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Stabilization of β-Ga Structure in Nanostructured Ga–In Alloy. / Nefedov, D. Yu; Charnaya, E. V.; Uskov, A. V.; Antonenko, A. O.; Podorozhkin, D. Yu; Haase, J.; Kumzerov, Yu A.; Fokin, A. V.

In: Applied Magnetic Resonance, Vol. 52, No. 12, 12.2021, p. 1721–1727.

Research output: Contribution to journalArticlepeer-review

Harvard

Nefedov, DY, Charnaya, EV, Uskov, AV, Antonenko, AO, Podorozhkin, DY, Haase, J, Kumzerov, YA & Fokin, AV 2021, 'Stabilization of β-Ga Structure in Nanostructured Ga–In Alloy', Applied Magnetic Resonance, vol. 52, no. 12, pp. 1721–1727. https://doi.org/10.1007/s00723-021-01385-4

APA

Nefedov, D. Y., Charnaya, E. V., Uskov, A. V., Antonenko, A. O., Podorozhkin, D. Y., Haase, J., Kumzerov, Y. A., & Fokin, A. V. (2021). Stabilization of β-Ga Structure in Nanostructured Ga–In Alloy. Applied Magnetic Resonance, 52(12), 1721–1727. https://doi.org/10.1007/s00723-021-01385-4

Vancouver

Author

Nefedov, D. Yu ; Charnaya, E. V. ; Uskov, A. V. ; Antonenko, A. O. ; Podorozhkin, D. Yu ; Haase, J. ; Kumzerov, Yu A. ; Fokin, A. V. / Stabilization of β-Ga Structure in Nanostructured Ga–In Alloy. In: Applied Magnetic Resonance. 2021 ; Vol. 52, No. 12. pp. 1721–1727.

BibTeX

@article{92263fb0e95a44bb975d7e2b233c9e4b,
title = "Stabilization of β-Ga Structure in Nanostructured Ga–In Alloy",
abstract = "The gallium–indium eutectic alloy is in a focus of modern studies because of its great potential for microelectronics, wearable electronics, electronic skin, medical diagnosis, and soft robotics. Novel applications of the Ga–In alloy require better understanding of the effect of size reduction on its properties. Here we report the NMR studies of the nanostructured Ga–In alloy within pores of the opal matrix. We demonstrated the stabilization of the segregated gallium-rich crystalline phase with a structure of β-gallium, this phase being metastable in bulk. The temperature dependences of the NMR isotropic shift for gallium nuclei within a temperature range from 11 K up to confined alloy melting and of the quadrupole constants for two gallium isotopes were also obtained. The experimental results suggested that only the gallium-rich phase with a structure of β-Ga crystallized under opal nanoconfinement.",
keywords = "NUCLEAR-MAGNETIC-RESONANCE, GALLIUM",
author = "Nefedov, {D. Yu} and Charnaya, {E. V.} and Uskov, {A. V.} and Antonenko, {A. O.} and Podorozhkin, {D. Yu} and J. Haase and Kumzerov, {Yu A.} and Fokin, {A. V.}",
note = "Publisher Copyright: {\textcopyright} 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature.",
year = "2021",
month = dec,
doi = "10.1007/s00723-021-01385-4",
language = "English",
volume = "52",
pages = "1721–1727",
journal = "Applied Magnetic Resonance",
issn = "0937-9347",
publisher = "Springer Nature",
number = "12",

}

RIS

TY - JOUR

T1 - Stabilization of β-Ga Structure in Nanostructured Ga–In Alloy

AU - Nefedov, D. Yu

AU - Charnaya, E. V.

AU - Uskov, A. V.

AU - Antonenko, A. O.

AU - Podorozhkin, D. Yu

AU - Haase, J.

AU - Kumzerov, Yu A.

AU - Fokin, A. V.

N1 - Publisher Copyright: © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature.

PY - 2021/12

Y1 - 2021/12

N2 - The gallium–indium eutectic alloy is in a focus of modern studies because of its great potential for microelectronics, wearable electronics, electronic skin, medical diagnosis, and soft robotics. Novel applications of the Ga–In alloy require better understanding of the effect of size reduction on its properties. Here we report the NMR studies of the nanostructured Ga–In alloy within pores of the opal matrix. We demonstrated the stabilization of the segregated gallium-rich crystalline phase with a structure of β-gallium, this phase being metastable in bulk. The temperature dependences of the NMR isotropic shift for gallium nuclei within a temperature range from 11 K up to confined alloy melting and of the quadrupole constants for two gallium isotopes were also obtained. The experimental results suggested that only the gallium-rich phase with a structure of β-Ga crystallized under opal nanoconfinement.

AB - The gallium–indium eutectic alloy is in a focus of modern studies because of its great potential for microelectronics, wearable electronics, electronic skin, medical diagnosis, and soft robotics. Novel applications of the Ga–In alloy require better understanding of the effect of size reduction on its properties. Here we report the NMR studies of the nanostructured Ga–In alloy within pores of the opal matrix. We demonstrated the stabilization of the segregated gallium-rich crystalline phase with a structure of β-gallium, this phase being metastable in bulk. The temperature dependences of the NMR isotropic shift for gallium nuclei within a temperature range from 11 K up to confined alloy melting and of the quadrupole constants for two gallium isotopes were also obtained. The experimental results suggested that only the gallium-rich phase with a structure of β-Ga crystallized under opal nanoconfinement.

KW - NUCLEAR-MAGNETIC-RESONANCE

KW - GALLIUM

UR - http://www.scopus.com/inward/record.url?scp=85111000603&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/9011d8d8-25e0-35cb-87e9-ede5b22066a1/

U2 - 10.1007/s00723-021-01385-4

DO - 10.1007/s00723-021-01385-4

M3 - Article

AN - SCOPUS:85111000603

VL - 52

SP - 1721

EP - 1727

JO - Applied Magnetic Resonance

JF - Applied Magnetic Resonance

SN - 0937-9347

IS - 12

ER -

ID: 87861902