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Square-planar aminonitronate transition metal complexes (M = CuII, NiII, PdII, and PtII). / Il'in, Mikhail V.; Bolotin, Dmitrii S.; Novikov, Alexander S.; Suslonov, Vitalii V.; Chezhina, Natalia V.; Bubnov, Michael P.; Cherkasov, Vladimir K.; Venter, Gertruida J.S.; Roodt, Andreas.

In: Inorganica Chimica Acta, Vol. 467, 01.10.2017, p. 372-378.

Research output: Contribution to journal › Article › peer-review

Harvard

Il'in, MV, Bolotin, DS, Novikov, AS, Suslonov, VV, Chezhina, NV, Bubnov, MP, Cherkasov, VK, Venter, GJS & Roodt, A 2017, 'Square-planar aminonitronate transition metal complexes (M = CuII, NiII, PdII, and PtII)', Inorganica Chimica Acta, vol. 467, pp. 372-378. https://doi.org/10.1016/j.ica.2017.08.034

APA

Il'in, M. V., Bolotin, D. S., Novikov, A. S., Suslonov, V. V., Chezhina, N. V., Bubnov, M. P., Cherkasov, V. K., Venter, G. J. S., & Roodt, A. (2017). Square-planar aminonitronate transition metal complexes (M = CuII, NiII, PdII, and PtII). Inorganica Chimica Acta, 467, 372-378. https://doi.org/10.1016/j.ica.2017.08.034

Vancouver

Il'in MV, Bolotin DS, Novikov AS, Suslonov VV, Chezhina NV, Bubnov MP et al. Square-planar aminonitronate transition metal complexes (M = CuII, NiII, PdII, and PtII). Inorganica Chimica Acta. 2017 Oct 1;467:372-378. https://doi.org/10.1016/j.ica.2017.08.034

Author

Il'in, Mikhail V. ; Bolotin, Dmitrii S. ; Novikov, Alexander S. ; Suslonov, Vitalii V. ; Chezhina, Natalia V. ; Bubnov, Michael P. ; Cherkasov, Vladimir K. ; Venter, Gertruida J.S. ; Roodt, Andreas. / Square-planar aminonitronate transition metal complexes (M = CuII, NiII, PdII, and PtII). In: Inorganica Chimica Acta. 2017 ; Vol. 467. pp. 372-378.

BibTeX

@article{4cf49de1e1174077b7b2226f80d38893,
title = "Square-planar aminonitronate transition metal complexes (M = CuII, NiII, PdII, and PtII)",
abstract = "Treatment of the aromatic aminonitrones p-RC6H4C(NH2)[dbnd]N+(Me)O− (R = NMe2, Cl) with CuCl2·2H2O, NiCl2·2H2O, β-PdCl2, or cis-[PtCl2(Me2SO)2] in the presence of a base leads to the [M{p-RC6H4C(NH)[dbnd]N+(Me)O−}2] (M = Cu, Ni, Pd) (72–95%) or [Pt{p-RC6H4C(NH)[dbnd]N+(Me)O–}Cl(Me2SO)] (ca. 80%) complexes, respectively. These compounds were characterized by elemental analyses (C, H, N), HRESI+-MS, FTIR, 1H and 13C{1H} NMR, and for the CuII and NiII complexes EPR and magnetic susceptibility. In addition, eight species were studied by single-crystal X-ray diffraction. In the X-ray structures of 2a–d, the hydrogen bonds are responsible for the formation of 1D polymeric chains. These bonds were evaluated by DFT calculations (M06/DZP-DKH level of theory) and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method). Estimated strengths of these non-covalent interactions are 2.7–4.4 kcal/mol.",
keywords = "Amidoxime, Aminonitrone, Metal complexes, Nitrone, Transition metals",
author = "Il'in, {Mikhail V.} and Bolotin, {Dmitrii S.} and Novikov, {Alexander S.} and Suslonov, {Vitalii V.} and Chezhina, {Natalia V.} and Bubnov, {Michael P.} and Cherkasov, {Vladimir K.} and Venter, {Gertruida J.S.} and Andreas Roodt",
year = "2017",
month = oct,
day = "1",
doi = "10.1016/j.ica.2017.08.034",
language = "English",
volume = "467",
pages = "372--378",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Square-planar aminonitronate transition metal complexes (M = CuII, NiII, PdII, and PtII)

AU - Il'in, Mikhail V.

AU - Bolotin, Dmitrii S.

AU - Novikov, Alexander S.

AU - Suslonov, Vitalii V.

AU - Chezhina, Natalia V.

AU - Bubnov, Michael P.

AU - Cherkasov, Vladimir K.

AU - Venter, Gertruida J.S.

AU - Roodt, Andreas

PY - 2017/10/1

Y1 - 2017/10/1

N2 - Treatment of the aromatic aminonitrones p-RC6H4C(NH2)[dbnd]N+(Me)O− (R = NMe2, Cl) with CuCl2·2H2O, NiCl2·2H2O, β-PdCl2, or cis-[PtCl2(Me2SO)2] in the presence of a base leads to the [M{p-RC6H4C(NH)[dbnd]N+(Me)O−}2] (M = Cu, Ni, Pd) (72–95%) or [Pt{p-RC6H4C(NH)[dbnd]N+(Me)O–}Cl(Me2SO)] (ca. 80%) complexes, respectively. These compounds were characterized by elemental analyses (C, H, N), HRESI+-MS, FTIR, 1H and 13C{1H} NMR, and for the CuII and NiII complexes EPR and magnetic susceptibility. In addition, eight species were studied by single-crystal X-ray diffraction. In the X-ray structures of 2a–d, the hydrogen bonds are responsible for the formation of 1D polymeric chains. These bonds were evaluated by DFT calculations (M06/DZP-DKH level of theory) and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method). Estimated strengths of these non-covalent interactions are 2.7–4.4 kcal/mol.

AB - Treatment of the aromatic aminonitrones p-RC6H4C(NH2)[dbnd]N+(Me)O− (R = NMe2, Cl) with CuCl2·2H2O, NiCl2·2H2O, β-PdCl2, or cis-[PtCl2(Me2SO)2] in the presence of a base leads to the [M{p-RC6H4C(NH)[dbnd]N+(Me)O−}2] (M = Cu, Ni, Pd) (72–95%) or [Pt{p-RC6H4C(NH)[dbnd]N+(Me)O–}Cl(Me2SO)] (ca. 80%) complexes, respectively. These compounds were characterized by elemental analyses (C, H, N), HRESI+-MS, FTIR, 1H and 13C{1H} NMR, and for the CuII and NiII complexes EPR and magnetic susceptibility. In addition, eight species were studied by single-crystal X-ray diffraction. In the X-ray structures of 2a–d, the hydrogen bonds are responsible for the formation of 1D polymeric chains. These bonds were evaluated by DFT calculations (M06/DZP-DKH level of theory) and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method). Estimated strengths of these non-covalent interactions are 2.7–4.4 kcal/mol.

KW - Amidoxime

KW - Aminonitrone

KW - Metal complexes

KW - Nitrone

KW - Transition metals

UR - http://www.scopus.com/inward/record.url?scp=85028706612&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2017.08.034

DO - 10.1016/j.ica.2017.08.034

M3 - Article

AN - SCOPUS:85028706612

VL - 467

SP - 372

EP - 378

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -

ID: 9169931