Research output: Contribution to journal › Article › peer-review
Splitting of the 1s-13p resonance at the sulfur atom in planar sulfur gold complexes. / Pavlychev, A. A.; Szargan, R.; Hallmeier, K. H.; Hennig, C.; Franke, A.
In: Physica B: Physics of Condensed Matter, Vol. 208-209, No. C, 01.03.1995, p. 62-64.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Splitting of the 1s-13p resonance at the sulfur atom in planar sulfur gold complexes
AU - Pavlychev, A. A.
AU - Szargan, R.
AU - Hallmeier, K. H.
AU - Hennig, C.
AU - Franke, A.
PY - 1995/3/1
Y1 - 1995/3/1
N2 - Results of experimental and theoretical investigation of X-ray absorption S K near edge structure in gold complex compounds with isomaleonitrildithiolate and isomaleonitrilthioselenolate ligands are presented. In the framework of a quasi-atomic model the splitting of the 1s-13p resonance at the sulfur atom has been found to dominate the S K XANES. Approximating the surrounding effect by fragments which include all sulfur and gold atoms a threefold splitting of the resonance was obtained. The components may be attributed to particular σ and π antibonding electronic states of the complex molecule. Comparing the results for both complexes the strong influence of the local structure on the resonance splitting is elucidated.
AB - Results of experimental and theoretical investigation of X-ray absorption S K near edge structure in gold complex compounds with isomaleonitrildithiolate and isomaleonitrilthioselenolate ligands are presented. In the framework of a quasi-atomic model the splitting of the 1s-13p resonance at the sulfur atom has been found to dominate the S K XANES. Approximating the surrounding effect by fragments which include all sulfur and gold atoms a threefold splitting of the resonance was obtained. The components may be attributed to particular σ and π antibonding electronic states of the complex molecule. Comparing the results for both complexes the strong influence of the local structure on the resonance splitting is elucidated.
UR - http://www.scopus.com/inward/record.url?scp=25544477055&partnerID=8YFLogxK
U2 - 10.1016/0921-4526(94)00635-9
DO - 10.1016/0921-4526(94)00635-9
M3 - Article
AN - SCOPUS:25544477055
VL - 208-209
SP - 62
EP - 64
JO - Physica B: Condensed Matter
JF - Physica B: Condensed Matter
SN - 0921-4526
IS - C
ER -
ID: 43210340