Standard

Spectroscopic and thermodynamic characterization of strontium carbonyls formed upon carbon monoxide adsorption on the zeolite Sr-Y. / Garrone, E.; Bonelli, B.; Tsyganenko, A. A.; Delgado, M. Rodríguez; Palomino, G. Turnes; Manoilova, O. V.; Areán, C. Otero.

In: Journal of Physical Chemistry B, Vol. 107, No. 11, 20.03.2003, p. 2537-2542.

Research output: Contribution to journal › Article › peer-review

Harvard

Garrone, E, Bonelli, B, Tsyganenko, AA, Delgado, MR, Palomino, GT, Manoilova, OV & Areán, CO 2003, 'Spectroscopic and thermodynamic characterization of strontium carbonyls formed upon carbon monoxide adsorption on the zeolite Sr-Y', Journal of Physical Chemistry B, vol. 107, no. 11, pp. 2537-2542. https://doi.org/10.1021/jp0217841

APA

Garrone, E., Bonelli, B., Tsyganenko, A. A., Delgado, M. R., Palomino, G. T., Manoilova, O. V., & Areán, C. O. (2003). Spectroscopic and thermodynamic characterization of strontium carbonyls formed upon carbon monoxide adsorption on the zeolite Sr-Y. Journal of Physical Chemistry B, 107(11), 2537-2542. https://doi.org/10.1021/jp0217841

Vancouver

Garrone E, Bonelli B, Tsyganenko AA, Delgado MR, Palomino GT, Manoilova OV et al. Spectroscopic and thermodynamic characterization of strontium carbonyls formed upon carbon monoxide adsorption on the zeolite Sr-Y. Journal of Physical Chemistry B. 2003 Mar 20;107(11):2537-2542. https://doi.org/10.1021/jp0217841

Author

Garrone, E. ; Bonelli, B. ; Tsyganenko, A. A. ; Delgado, M. Rodríguez ; Palomino, G. Turnes ; Manoilova, O. V. ; Areán, C. Otero. / Spectroscopic and thermodynamic characterization of strontium carbonyls formed upon carbon monoxide adsorption on the zeolite Sr-Y. In: Journal of Physical Chemistry B. 2003 ; Vol. 107, No. 11. pp. 2537-2542.

BibTeX

@article{eae8f7625f44413ab79d3ff092ab551b,
title = "Spectroscopic and thermodynamic characterization of strontium carbonyls formed upon carbon monoxide adsorption on the zeolite Sr-Y",
abstract = "The adsorption of CO on the faujasite-type zeolite Sr-Y generates four types of carbonyls: The Sr(CO)2+ species, which has a characteristic IR adsorption band at 2191 cm-1; the Sr(OC)2+ species at 2095 cm-1; Sr(CO)22+, which has a single mode at 2187 cm-1; and Sr(CO, OC)2+, which has a mode at 2098 cm-1. The use of a variable-temperature IR cell allowing the simultaneous measurements of temperature, pressure, and coverages (intensities) of CO species to be made has allowed the determination of the standard enthalpy and entropy of formation of each species, so obtaining a fairly thorough thermodynamic characterization of the CO/Sr-Y system. C- and O-bonded carbonyl species were found to be in a temperature-dependent isomerization equilibrium, which was also studied by means of variable-temperature IR spectroscopy.",
author = "E. Garrone and B. Bonelli and Tsyganenko, {A. A.} and Delgado, {M. Rodr{\'i}guez} and Palomino, {G. Turnes} and Manoilova, {O. V.} and Are{\'a}n, {C. Otero}",
year = "2003",
month = mar,
day = "20",
doi = "10.1021/jp0217841",
language = "English",
volume = "107",
pages = "2537--2542",
journal = "Journal of Physical Chemistry B",
issn = "1520-6106",
publisher = "American Chemical Society",
number = "11",

}

RIS

TY - JOUR

T1 - Spectroscopic and thermodynamic characterization of strontium carbonyls formed upon carbon monoxide adsorption on the zeolite Sr-Y

AU - Garrone, E.

AU - Bonelli, B.

AU - Tsyganenko, A. A.

AU - Delgado, M. Rodríguez

AU - Palomino, G. Turnes

AU - Manoilova, O. V.

AU - Areán, C. Otero

PY - 2003/3/20

Y1 - 2003/3/20

N2 - The adsorption of CO on the faujasite-type zeolite Sr-Y generates four types of carbonyls: The Sr(CO)2+ species, which has a characteristic IR adsorption band at 2191 cm-1; the Sr(OC)2+ species at 2095 cm-1; Sr(CO)22+, which has a single mode at 2187 cm-1; and Sr(CO, OC)2+, which has a mode at 2098 cm-1. The use of a variable-temperature IR cell allowing the simultaneous measurements of temperature, pressure, and coverages (intensities) of CO species to be made has allowed the determination of the standard enthalpy and entropy of formation of each species, so obtaining a fairly thorough thermodynamic characterization of the CO/Sr-Y system. C- and O-bonded carbonyl species were found to be in a temperature-dependent isomerization equilibrium, which was also studied by means of variable-temperature IR spectroscopy.

AB - The adsorption of CO on the faujasite-type zeolite Sr-Y generates four types of carbonyls: The Sr(CO)2+ species, which has a characteristic IR adsorption band at 2191 cm-1; the Sr(OC)2+ species at 2095 cm-1; Sr(CO)22+, which has a single mode at 2187 cm-1; and Sr(CO, OC)2+, which has a mode at 2098 cm-1. The use of a variable-temperature IR cell allowing the simultaneous measurements of temperature, pressure, and coverages (intensities) of CO species to be made has allowed the determination of the standard enthalpy and entropy of formation of each species, so obtaining a fairly thorough thermodynamic characterization of the CO/Sr-Y system. C- and O-bonded carbonyl species were found to be in a temperature-dependent isomerization equilibrium, which was also studied by means of variable-temperature IR spectroscopy.

UR - http://www.scopus.com/inward/record.url?scp=0037650205&partnerID=8YFLogxK

U2 - 10.1021/jp0217841

DO - 10.1021/jp0217841

M3 - Article

AN - SCOPUS:0037650205

VL - 107

SP - 2537

EP - 2542

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

SN - 1520-6106

IS - 11

ER -

ID: 41680183