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Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures. / Tumkin, Ilya I.; Khairullina, Evgeniia M.; Myund, Liubov A.; Logunov, Lev S.; Gordeychuk, Dmitrii I.; Panov, Maxim S.; Kochemirovsky, Vladimir A.

In: Optical and Quantum Electronics, Vol. 51, No. 3, 89, 01.03.2019.

Research output: Contribution to journal › Article › peer-review

Harvard

Tumkin, II, Khairullina, EM, Myund, LA, Logunov, LS, Gordeychuk, DI, Panov, MS & Kochemirovsky, VA 2019, 'Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures', Optical and Quantum Electronics, vol. 51, no. 3, 89. https://doi.org/10.1007/s11082-019-1800-5

APA

Tumkin, I. I., Khairullina, E. M., Myund, L. A., Logunov, L. S., Gordeychuk, D. I., Panov, M. S., & Kochemirovsky, V. A. (2019). Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures. Optical and Quantum Electronics, 51(3), [89]. https://doi.org/10.1007/s11082-019-1800-5

Vancouver

Tumkin II, Khairullina EM, Myund LA, Logunov LS, Gordeychuk DI, Panov MS et al. Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures. Optical and Quantum Electronics. 2019 Mar 1;51(3). 89. https://doi.org/10.1007/s11082-019-1800-5

Author

Tumkin, Ilya I. ; Khairullina, Evgeniia M. ; Myund, Liubov A. ; Logunov, Lev S. ; Gordeychuk, Dmitrii I. ; Panov, Maxim S. ; Kochemirovsky, Vladimir A. / Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures. In: Optical and Quantum Electronics. 2019 ; Vol. 51, No. 3.

BibTeX

@article{3d6793540de14738929a2b06debc156a,
title = "Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures",
abstract = "In this work we study the influence of l-(+)-?NaC(4)H(4)O(6)x4H(2)O (KNaT) and l-H2C4H4O6 (H2T) on the complexation processes occurring during in situ laser-induced catalytic destruction of the organic components of the aqueous solutions with formation of the unsaturated hydrocarbons. For that purpose, ATR-FTIR, Raman, IR, and NIR spectroscopy as well as quantum chemical calculations were implemented. It was observed that hydration of T2- anion via carboxylate groups is stronger than that via hydroxyl groups. We also established the changes in the spectral characteristics of the absorption bands corresponding to vibrations of T2-, HT-, and H2T, at solid state-liquid and acid-salt transitions, depending on concentration of the solution components and the [OH-]/[H2T] ratio. Finally, it was shown that ethylene is a main product of the catalytic destruction of the copper tartrate complexes.",
keywords = "ATR-FTIR, Catalysis, DFT calculations, IR, Laser-induced copper deposition, NIR, Raman spectroscopy, Sodium potassium tartrate tetrahydrate, Tartaric acid, TARTRATE, GLYCEROL, RAMAN, GROWTH, LIGAND",
author = "Tumkin, {Ilya I.} and Khairullina, {Evgeniia M.} and Myund, {Liubov A.} and Logunov, {Lev S.} and Gordeychuk, {Dmitrii I.} and Panov, {Maxim S.} and Kochemirovsky, {Vladimir A.}",
year = "2019",
month = mar,
day = "1",
doi = "10.1007/s11082-019-1800-5",
language = "English",
volume = "51",
journal = "Optical and Quantum Electronics",
issn = "0306-8919",
publisher = "Springer Nature",
number = "3",

}

RIS

TY - JOUR

T1 - Spectroscopic and theoretical studies of potassium sodium l-(+)-tartrate tetrahydrate and l-tartaric acid used as precursors for in situ laser-induced deposition of the catalytically active copper microstructures

AU - Tumkin, Ilya I.

AU - Khairullina, Evgeniia M.

AU - Myund, Liubov A.

AU - Logunov, Lev S.

AU - Gordeychuk, Dmitrii I.

AU - Panov, Maxim S.

AU - Kochemirovsky, Vladimir A.

PY - 2019/3/1

Y1 - 2019/3/1

N2 - In this work we study the influence of l-(+)-?NaC(4)H(4)O(6)x4H(2)O (KNaT) and l-H2C4H4O6 (H2T) on the complexation processes occurring during in situ laser-induced catalytic destruction of the organic components of the aqueous solutions with formation of the unsaturated hydrocarbons. For that purpose, ATR-FTIR, Raman, IR, and NIR spectroscopy as well as quantum chemical calculations were implemented. It was observed that hydration of T2- anion via carboxylate groups is stronger than that via hydroxyl groups. We also established the changes in the spectral characteristics of the absorption bands corresponding to vibrations of T2-, HT-, and H2T, at solid state-liquid and acid-salt transitions, depending on concentration of the solution components and the [OH-]/[H2T] ratio. Finally, it was shown that ethylene is a main product of the catalytic destruction of the copper tartrate complexes.

AB - In this work we study the influence of l-(+)-?NaC(4)H(4)O(6)x4H(2)O (KNaT) and l-H2C4H4O6 (H2T) on the complexation processes occurring during in situ laser-induced catalytic destruction of the organic components of the aqueous solutions with formation of the unsaturated hydrocarbons. For that purpose, ATR-FTIR, Raman, IR, and NIR spectroscopy as well as quantum chemical calculations were implemented. It was observed that hydration of T2- anion via carboxylate groups is stronger than that via hydroxyl groups. We also established the changes in the spectral characteristics of the absorption bands corresponding to vibrations of T2-, HT-, and H2T, at solid state-liquid and acid-salt transitions, depending on concentration of the solution components and the [OH-]/[H2T] ratio. Finally, it was shown that ethylene is a main product of the catalytic destruction of the copper tartrate complexes.

KW - ATR-FTIR

KW - Catalysis

KW - DFT calculations

KW - IR

KW - Laser-induced copper deposition

KW - NIR

KW - Raman spectroscopy

KW - Sodium potassium tartrate tetrahydrate

KW - Tartaric acid

KW - TARTRATE

KW - GLYCEROL

KW - RAMAN

KW - GROWTH

KW - LIGAND

UR - http://www.scopus.com/inward/record.url?scp=85063025904&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/spectroscopic-theoretical-studies-potassium-sodium-ltartrate-tetrahydrate-ltartaric-acid-used-precur

U2 - 10.1007/s11082-019-1800-5

DO - 10.1007/s11082-019-1800-5

M3 - Article

AN - SCOPUS:85063025904

VL - 51

JO - Optical and Quantum Electronics

JF - Optical and Quantum Electronics

SN - 0306-8919

IS - 3

M1 - 89

ER -

ID: 40045472