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Sorption properties and transport parameters of membranes based on polybenzoxazinoneimide and its prepolymer. / Pulyalina, A. Yu; Polotskaya, G. A.; Rostovtseva, V. A.; Goikhman, M. Ya; Podeshvo, I. V.; Shugurov, S. M.; Zubakina, E. A.; Toikka, A. M.

In: Petroleum Chemistry, Vol. 57, No. 4, 01.01.2017, p. 318-326.

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@article{f75c8f0ca29a40a2a1f329dbecd89be2,
title = "Sorption properties and transport parameters of membranes based on polybenzoxazinoneimide and its prepolymer",
abstract = "A comparative study of physicochemical parameters and transport properties of the heteroaromatic polymer polybenzoxazinoneimide (PBOI) and its hydrolytically stable prepolymer, imide-containing polyamic acid (PI-PAA), has been performed. The process of thermal conversion of PI-PAA into PBOI has been studied using thermogravimetric analysis, differential scanning calorimetry, and mass spectrometry. The conversion of PI-PAA into PBOI increases the glass transition temperature and the density of the polymer, resulting in a reduction of fractional free volume. Both of the test polymers have been examined as membrane materials in pervaporation dehydration of aqueous isopropyl alcohol. It has been shown that PBOI is more effective in this process compared with the prepolymer. The transport properties of the PBOI membrane have been compared with published data on other polymers used in the pervaporative separation of the water–isopropanol azeotrope.",
keywords = "imide-containing polyamic acid, pervaporation, polybenzoxazinoneimide, water–isopropyl alcohol mixture",
author = "Pulyalina, {A. Yu} and Polotskaya, {G. A.} and Rostovtseva, {V. A.} and Goikhman, {M. Ya} and Podeshvo, {I. V.} and Shugurov, {S. M.} and Zubakina, {E. A.} and Toikka, {A. M.}",
year = "2017",
month = jan,
day = "1",
doi = "10.1134/S0965544117040053",
language = "English",
volume = "57",
pages = "318--326",
journal = "Petroleum Chemistry",
issn = "0965-5441",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Sorption properties and transport parameters of membranes based on polybenzoxazinoneimide and its prepolymer

AU - Pulyalina, A. Yu

AU - Polotskaya, G. A.

AU - Rostovtseva, V. A.

AU - Goikhman, M. Ya

AU - Podeshvo, I. V.

AU - Shugurov, S. M.

AU - Zubakina, E. A.

AU - Toikka, A. M.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - A comparative study of physicochemical parameters and transport properties of the heteroaromatic polymer polybenzoxazinoneimide (PBOI) and its hydrolytically stable prepolymer, imide-containing polyamic acid (PI-PAA), has been performed. The process of thermal conversion of PI-PAA into PBOI has been studied using thermogravimetric analysis, differential scanning calorimetry, and mass spectrometry. The conversion of PI-PAA into PBOI increases the glass transition temperature and the density of the polymer, resulting in a reduction of fractional free volume. Both of the test polymers have been examined as membrane materials in pervaporation dehydration of aqueous isopropyl alcohol. It has been shown that PBOI is more effective in this process compared with the prepolymer. The transport properties of the PBOI membrane have been compared with published data on other polymers used in the pervaporative separation of the water–isopropanol azeotrope.

AB - A comparative study of physicochemical parameters and transport properties of the heteroaromatic polymer polybenzoxazinoneimide (PBOI) and its hydrolytically stable prepolymer, imide-containing polyamic acid (PI-PAA), has been performed. The process of thermal conversion of PI-PAA into PBOI has been studied using thermogravimetric analysis, differential scanning calorimetry, and mass spectrometry. The conversion of PI-PAA into PBOI increases the glass transition temperature and the density of the polymer, resulting in a reduction of fractional free volume. Both of the test polymers have been examined as membrane materials in pervaporation dehydration of aqueous isopropyl alcohol. It has been shown that PBOI is more effective in this process compared with the prepolymer. The transport properties of the PBOI membrane have been compared with published data on other polymers used in the pervaporative separation of the water–isopropanol azeotrope.

KW - imide-containing polyamic acid

KW - pervaporation

KW - polybenzoxazinoneimide

KW - water–isopropyl alcohol mixture

UR - http://www.scopus.com/inward/record.url?scp=85018775870&partnerID=8YFLogxK

U2 - 10.1134/S0965544117040053

DO - 10.1134/S0965544117040053

M3 - Article

VL - 57

SP - 318

EP - 326

JO - Petroleum Chemistry

JF - Petroleum Chemistry

SN - 0965-5441

IS - 4

ER -

ID: 7749669