"Solvent-in-salt’’ systems for design of new materials in chemistry, biology and energy research

Standard

"Solvent-in-salt’’ systems for design of new materials in chemistry, biology and energy research. / Анаников, Валентин Павлович.

In: Chemical Society Reviews, Vol. 47, No. 4, 21.02.2018, p. 1250-1284.

Research output: Contribution to journal › Review article › peer-review

Author

Анаников, Валентин Павлович. / "Solvent-in-salt’’ systems for design of new materials in chemistry, biology and energy research. In: Chemical Society Reviews. 2018 ; Vol. 47, No. 4. pp. 1250-1284.

BibTeX

@article{68f5b364190e4af6adcd4f6c0a970074,

title = "{"}Solvent-in-salt{\textquoteright}{\textquoteright} systems for design of new materials in chemistry, biology and energy research",

abstract = "Inorganic and organic {"}solvent-in-salt{"} (SIS) systems have been known for decades but have attracted significant attention only recently. Molten salt hydrates/solvates have been successfully employed as non-flammable, benign electrolytes in rechargeable lithium-ion batteries leading to a revolution in battery development and design. SIS with organic components (for example, ionic liquids containing small amounts of water) demonstrate remarkable thermal stability and tunability, and present a class of admittedly safer electrolytes, in comparison with traditional organic solvents. Water molecules tend to form nano- and microstructures (droplets and channel networks) in ionic media impacting their heterogeneity. Such microscale domains can be employed as microreactors for chemical and enzymatic synthesis. In this review, we address known SIS systems and discuss their composition, structure, properties and dynamics. Special attention is paid to the current and potential applications of inorganic and organic SIS systems in energy research, chemistry and biochemistry. A separate section of this review is dedicated to experimental methods of SIS investigation, which is crucial for the development of this field.",

author = "Анаников, {Валентин Павлович}",

note = "Funding Information: Valentine Ananikov received his MSc degree in 1996 (biochemistry), PhD degree in 1999 (organic chemistry and catalysis), Habilitation in 2003, and in 2005 he was appointed Professor and Laboratory Head of the Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences. In 2008 he was elected as a Member of the Russian Academy of Sciences. In 2012 he became Professor of the Chemistry Department of Moscow State University. He was a recipient of the Russian State Prize for Outstanding Achievements in Science and Technology (2004), an Award of the Science Support Foundation (2005), a Medal of the Russian Academy of Sciences (2000), Liebig Lecturer by German Chemical Society (2010), and the Balandin Prize for outstanding achievements in the field of catalysis (2010), Organometallics Distinguished Author Award Lectureship by American Chemical Society (2016), Hitachi High-Technologies Award In Appreciation for Novel Approach and Outstanding Contribution to Setting New Standards for Electron Microscopy Applications in Chemistry (2016). His research interests are focused on mechanistic studies, catalysis, ionic liquids and molecular complexity. Funding Information: This research was supported by the Russian Science Foundation (grant 14-50-00126).",

year = "2018",

month = feb,

day = "21",

doi = "10.1039/c7cs00547d",

language = "English",

volume = "47",

pages = "1250--1284",

journal = "Chemical Society Reviews",

issn = "0306-0012",

publisher = "Royal Society of Chemistry",

number = "4",

}

RIS

TY - JOUR

T1 - "Solvent-in-salt’’ systems for design of new materials in chemistry, biology and energy research

AU - Анаников, Валентин Павлович

N1 - Funding Information: Valentine Ananikov received his MSc degree in 1996 (biochemistry), PhD degree in 1999 (organic chemistry and catalysis), Habilitation in 2003, and in 2005 he was appointed Professor and Laboratory Head of the Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences. In 2008 he was elected as a Member of the Russian Academy of Sciences. In 2012 he became Professor of the Chemistry Department of Moscow State University. He was a recipient of the Russian State Prize for Outstanding Achievements in Science and Technology (2004), an Award of the Science Support Foundation (2005), a Medal of the Russian Academy of Sciences (2000), Liebig Lecturer by German Chemical Society (2010), and the Balandin Prize for outstanding achievements in the field of catalysis (2010), Organometallics Distinguished Author Award Lectureship by American Chemical Society (2016), Hitachi High-Technologies Award In Appreciation for Novel Approach and Outstanding Contribution to Setting New Standards for Electron Microscopy Applications in Chemistry (2016). His research interests are focused on mechanistic studies, catalysis, ionic liquids and molecular complexity. Funding Information: This research was supported by the Russian Science Foundation (grant 14-50-00126).

PY - 2018/2/21

Y1 - 2018/2/21

N2 - Inorganic and organic "solvent-in-salt" (SIS) systems have been known for decades but have attracted significant attention only recently. Molten salt hydrates/solvates have been successfully employed as non-flammable, benign electrolytes in rechargeable lithium-ion batteries leading to a revolution in battery development and design. SIS with organic components (for example, ionic liquids containing small amounts of water) demonstrate remarkable thermal stability and tunability, and present a class of admittedly safer electrolytes, in comparison with traditional organic solvents. Water molecules tend to form nano- and microstructures (droplets and channel networks) in ionic media impacting their heterogeneity. Such microscale domains can be employed as microreactors for chemical and enzymatic synthesis. In this review, we address known SIS systems and discuss their composition, structure, properties and dynamics. Special attention is paid to the current and potential applications of inorganic and organic SIS systems in energy research, chemistry and biochemistry. A separate section of this review is dedicated to experimental methods of SIS investigation, which is crucial for the development of this field.

AB - Inorganic and organic "solvent-in-salt" (SIS) systems have been known for decades but have attracted significant attention only recently. Molten salt hydrates/solvates have been successfully employed as non-flammable, benign electrolytes in rechargeable lithium-ion batteries leading to a revolution in battery development and design. SIS with organic components (for example, ionic liquids containing small amounts of water) demonstrate remarkable thermal stability and tunability, and present a class of admittedly safer electrolytes, in comparison with traditional organic solvents. Water molecules tend to form nano- and microstructures (droplets and channel networks) in ionic media impacting their heterogeneity. Such microscale domains can be employed as microreactors for chemical and enzymatic synthesis. In this review, we address known SIS systems and discuss their composition, structure, properties and dynamics. Special attention is paid to the current and potential applications of inorganic and organic SIS systems in energy research, chemistry and biochemistry. A separate section of this review is dedicated to experimental methods of SIS investigation, which is crucial for the development of this field.

UR - http://www.scopus.com/inward/record.url?scp=85042313709&partnerID=8YFLogxK

U2 - 10.1039/c7cs00547d

DO - 10.1039/c7cs00547d

M3 - Review article

VL - 47

SP - 1250

EP - 1284

JO - Chemical Society Reviews

JF - Chemical Society Reviews

SN - 0306-0012

IS - 4

ER -

ID: 36192927