Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′- tetraisobutyl-2,6-dipicolinamide

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Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′- tetraisobutyl-2,6-dipicolinamide. / Makrlík, E.; Vaňura, P.; Selucký, P.; Babain, V. A.; Smirnov, I. V.

In: Journal of Radioanalytical and Nuclear Chemistry, Vol. 288, No. 1, 01.04.2011, p. 233-238.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{2cde9189de424babb104b22b93ac8a6f,

title = "Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′- tetraisobutyl-2,6-dipicolinamide",

abstract = "Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N,N,N{\^a},N{\^a}-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL+, HL2 +, CaL2 2+, SrL2 2+ and SrL3 2+ are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined.",

keywords = "Calcium, Extraction, Hydrogen dicarbollylcobaltate, N,N,N{\^a},N{\^a}- tetraisobutyl-2,6-dipicolinamide, Nitrobenzene, Stability constants, Strontium",

author = "E. Makrl{\'i}k and P. Va{\v n}ura and P. Seluck{\'y} and Babain, {V. A.} and Smirnov, {I. V.}",

year = "2011",

month = apr,

day = "1",

doi = "10.1007/s10967-010-0902-0",

language = "English",

volume = "288",

pages = "233--238",

journal = "Journal of Radioanalytical and Nuclear Chemistry",

issn = "0236-5731",

publisher = "Springer Nature",

number = "1",

}

RIS

TY - JOUR

T1 - Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′- tetraisobutyl-2,6-dipicolinamide

AU - Makrlík, E.

AU - Vaňura, P.

AU - Selucký, P.

AU - Babain, V. A.

AU - Smirnov, I. V.

PY - 2011/4/1

Y1 - 2011/4/1

N2 - Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N,N,Nâ,Nâ-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL+, HL2 +, CaL2 2+, SrL2 2+ and SrL3 2+ are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined.

AB - Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of N,N,Nâ,Nâ-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL+, HL2 +, CaL2 2+, SrL2 2+ and SrL3 2+ are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined.

KW - Calcium

KW - Extraction

KW - Hydrogen dicarbollylcobaltate

KW - N,N,Nâ,Nâ- tetraisobutyl-2,6-dipicolinamide

KW - Nitrobenzene

KW - Stability constants

KW - Strontium

UR - http://www.scopus.com/inward/record.url?scp=79955061106&partnerID=8YFLogxK

U2 - 10.1007/s10967-010-0902-0

DO - 10.1007/s10967-010-0902-0

M3 - Article

AN - SCOPUS:79955061106

VL - 288

SP - 233

EP - 238

JO - Journal of Radioanalytical and Nuclear Chemistry

JF - Journal of Radioanalytical and Nuclear Chemistry

SN - 0236-5731

IS - 1

ER -

ID: 42867433