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Solvent effects on the ultraviolet absorption spectrum of mercury atom. / Buturlimova, M. V.; Zelikina, G. Ya; Kiseleva, M. B.

In: Journal of Molecular Structure, Vol. 880, No. 1-3, 27.05.2008, p. 59-63.

Research output: Contribution to journal › Article › peer-review

Harvard

Buturlimova, MV, Zelikina, GY & Kiseleva, MB 2008, 'Solvent effects on the ultraviolet absorption spectrum of mercury atom', Journal of Molecular Structure, vol. 880, no. 1-3, pp. 59-63. https://doi.org/10.1016/j.molstruc.2008.01.034

APA

Buturlimova, M. V., Zelikina, G. Y., & Kiseleva, M. B. (2008). Solvent effects on the ultraviolet absorption spectrum of mercury atom. Journal of Molecular Structure, 880(1-3), 59-63. https://doi.org/10.1016/j.molstruc.2008.01.034

Vancouver

Buturlimova MV, Zelikina GY, Kiseleva MB. Solvent effects on the ultraviolet absorption spectrum of mercury atom. Journal of Molecular Structure. 2008 May 27;880(1-3):59-63. https://doi.org/10.1016/j.molstruc.2008.01.034

Author

Buturlimova, M. V. ; Zelikina, G. Ya ; Kiseleva, M. B. / Solvent effects on the ultraviolet absorption spectrum of mercury atom. In: Journal of Molecular Structure. 2008 ; Vol. 880, No. 1-3. pp. 59-63.

BibTeX

@article{2f5a9173d3db41cfaf86cbece937388e,
title = "Solvent effects on the ultraviolet absorption spectrum of mercury atom",
abstract = "Absorption spectrum of mercury dissolved in hexane and heptane in the region 280-180 nm was found to consist of three bands. These bands were assigned to the 1S0 → 1P1 transition (A band, λ = 254 nm), to the 1S0 → 3P2 transition (B band, λ = 226 nm) and to the 1S0 → 1P1 transition (C band, λ = 190 nm) of a mercury atom placed into a liquid cell. The B and C absorption bands of mercury in liquid solutions were observed for the first time. It was found that the A band and the C band have, respectively, distinct doublet and triplet structure, while the doublet structure of the B band is only slightly seen. The oscillator strengths of all three bands of mercury in solutions were estimated. The structure of the C, A and B bands of mercury in solutions most probably results from the removal of the degeneracy of the excited states 1P1, 3P1 and 3P2 of a mercury atom, placed into a cell of low symmetry.",
keywords = "Intermolecular interactions, Mercury organic solution, VUV-UV absorption spectra",
author = "Buturlimova, {M. V.} and Zelikina, {G. Ya} and Kiseleva, {M. B.}",
year = "2008",
month = may,
day = "27",
doi = "10.1016/j.molstruc.2008.01.034",
language = "English",
volume = "880",
pages = "59--63",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",
number = "1-3",

}

RIS

TY - JOUR

T1 - Solvent effects on the ultraviolet absorption spectrum of mercury atom

AU - Buturlimova, M. V.

AU - Zelikina, G. Ya

AU - Kiseleva, M. B.

PY - 2008/5/27

Y1 - 2008/5/27

N2 - Absorption spectrum of mercury dissolved in hexane and heptane in the region 280-180 nm was found to consist of three bands. These bands were assigned to the 1S0 → 1P1 transition (A band, λ = 254 nm), to the 1S0 → 3P2 transition (B band, λ = 226 nm) and to the 1S0 → 1P1 transition (C band, λ = 190 nm) of a mercury atom placed into a liquid cell. The B and C absorption bands of mercury in liquid solutions were observed for the first time. It was found that the A band and the C band have, respectively, distinct doublet and triplet structure, while the doublet structure of the B band is only slightly seen. The oscillator strengths of all three bands of mercury in solutions were estimated. The structure of the C, A and B bands of mercury in solutions most probably results from the removal of the degeneracy of the excited states 1P1, 3P1 and 3P2 of a mercury atom, placed into a cell of low symmetry.

AB - Absorption spectrum of mercury dissolved in hexane and heptane in the region 280-180 nm was found to consist of three bands. These bands were assigned to the 1S0 → 1P1 transition (A band, λ = 254 nm), to the 1S0 → 3P2 transition (B band, λ = 226 nm) and to the 1S0 → 1P1 transition (C band, λ = 190 nm) of a mercury atom placed into a liquid cell. The B and C absorption bands of mercury in liquid solutions were observed for the first time. It was found that the A band and the C band have, respectively, distinct doublet and triplet structure, while the doublet structure of the B band is only slightly seen. The oscillator strengths of all three bands of mercury in solutions were estimated. The structure of the C, A and B bands of mercury in solutions most probably results from the removal of the degeneracy of the excited states 1P1, 3P1 and 3P2 of a mercury atom, placed into a cell of low symmetry.

KW - Intermolecular interactions

KW - Mercury organic solution

KW - VUV-UV absorption spectra

UR - http://www.scopus.com/inward/record.url?scp=43249099013&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2008.01.034

DO - 10.1016/j.molstruc.2008.01.034

M3 - Article

AN - SCOPUS:43249099013

VL - 880

SP - 59

EP - 63

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

IS - 1-3

ER -

ID: 28359877