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Solubility of n-Hexane and Setchenov’s Constants in Aqueous Solutions of KCl, NaCl, NaBr, and NaNO3. / Koroleva, Sofia; Korchak, Petr; Enders, Sabine; Dobryakov, Yuri; Victorov, Alexey.

In: Journal of Chemical & Engineering Data, Vol. 64, No. 10, 10.2019, p. 4314-4318.

Research output: Contribution to journal › Article › peer-review

Harvard

Koroleva, S, Korchak, P, Enders, S, Dobryakov, Y & Victorov, A 2019, 'Solubility of n-Hexane and Setchenov’s Constants in Aqueous Solutions of KCl, NaCl, NaBr, and NaNO3', Journal of Chemical & Engineering Data, vol. 64, no. 10, pp. 4314-4318. https://doi.org/10.1021/acs.jced.9b00384

APA

Koroleva, S., Korchak, P., Enders, S., Dobryakov, Y., & Victorov, A. (2019). Solubility of n-Hexane and Setchenov’s Constants in Aqueous Solutions of KCl, NaCl, NaBr, and NaNO3. Journal of Chemical & Engineering Data, 64(10), 4314-4318. https://doi.org/10.1021/acs.jced.9b00384

Vancouver

Koroleva S, Korchak P, Enders S, Dobryakov Y, Victorov A. Solubility of n-Hexane and Setchenov’s Constants in Aqueous Solutions of KCl, NaCl, NaBr, and NaNO3. Journal of Chemical & Engineering Data. 2019 Oct;64(10):4314-4318. https://doi.org/10.1021/acs.jced.9b00384

Author

Koroleva, Sofia ; Korchak, Petr ; Enders, Sabine ; Dobryakov, Yuri ; Victorov, Alexey. / Solubility of n-Hexane and Setchenov’s Constants in Aqueous Solutions of KCl, NaCl, NaBr, and NaNO3. In: Journal of Chemical & Engineering Data. 2019 ; Vol. 64, No. 10. pp. 4314-4318.

BibTeX

@article{4bbbe9098dd2419b9493f696a203f62c,
title = "Solubility of n-Hexane and Setchenov{\textquoteright}s Constants in Aqueous Solutions of KCl, NaCl, NaBr, and NaNO3",
abstract = "Specific chemistry of added salt has a strong effect on the solubility of chemicals. In this work we measure the effect of several inorganic 1:1 salts on the aqueous solubility of n-hexane. For KCl, NaCl, and NaBr, our data agree with previous measurements. The effect of NaNO3 is measured for the first time. Based on our data, we report the Setchenov salting-out constants and discuss the specific effect of added salt on the solubility of n-hexane. We apply the ePC-SAFT equation of the state to correlate our data and report parameters of this equation. Calculated results reproduce the experimental data quite well.",
keywords = "ALKANES, ELECTROLYTE SOLUTIONS, HYDROCARBONS, MUTUAL SOLUBILITIES, SALTING-OUT, THERMODYNAMIC ANALYSIS, WATER",
author = "Sofia Koroleva and Petr Korchak and Sabine Enders and Yuri Dobryakov and Alexey Victorov",
note = "Funding Information: The authors are grateful to Prof. Sadowski and Dr. Held for sharing their PC-SAFT software. Financial support of the Russian Foundation for Basic Research (project no. 18-03-00698a) is acknowledged. S.V.K. thanks the German–Russian Interdisciplinary Science Center (project no. C-2010b-2).",
year = "2019",
month = oct,
doi = "10.1021/acs.jced.9b00384",
language = "English",
volume = "64",
pages = "4314--4318",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "10",

}

RIS

TY - JOUR

T1 - Solubility of n-Hexane and Setchenov’s Constants in Aqueous Solutions of KCl, NaCl, NaBr, and NaNO3

AU - Koroleva, Sofia

AU - Korchak, Petr

AU - Enders, Sabine

AU - Dobryakov, Yuri

AU - Victorov, Alexey

N1 - Funding Information: The authors are grateful to Prof. Sadowski and Dr. Held for sharing their PC-SAFT software. Financial support of the Russian Foundation for Basic Research (project no. 18-03-00698a) is acknowledged. S.V.K. thanks the German–Russian Interdisciplinary Science Center (project no. C-2010b-2).

PY - 2019/10

Y1 - 2019/10

N2 - Specific chemistry of added salt has a strong effect on the solubility of chemicals. In this work we measure the effect of several inorganic 1:1 salts on the aqueous solubility of n-hexane. For KCl, NaCl, and NaBr, our data agree with previous measurements. The effect of NaNO3 is measured for the first time. Based on our data, we report the Setchenov salting-out constants and discuss the specific effect of added salt on the solubility of n-hexane. We apply the ePC-SAFT equation of the state to correlate our data and report parameters of this equation. Calculated results reproduce the experimental data quite well.

AB - Specific chemistry of added salt has a strong effect on the solubility of chemicals. In this work we measure the effect of several inorganic 1:1 salts on the aqueous solubility of n-hexane. For KCl, NaCl, and NaBr, our data agree with previous measurements. The effect of NaNO3 is measured for the first time. Based on our data, we report the Setchenov salting-out constants and discuss the specific effect of added salt on the solubility of n-hexane. We apply the ePC-SAFT equation of the state to correlate our data and report parameters of this equation. Calculated results reproduce the experimental data quite well.

KW - ALKANES

KW - ELECTROLYTE SOLUTIONS

KW - HYDROCARBONS

KW - MUTUAL SOLUBILITIES

KW - SALTING-OUT

KW - THERMODYNAMIC ANALYSIS

KW - WATER

UR - http://www.scopus.com/inward/record.url?scp=85074228381&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/solubility-nhexane-setchenovs-constants-aqueous-solutions-kcl-nacl-nabr-nano3

U2 - 10.1021/acs.jced.9b00384

DO - 10.1021/acs.jced.9b00384

M3 - Article

VL - 64

SP - 4314

EP - 4318

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

SN - 0021-9568

IS - 10

ER -

ID: 46646165