TY - JOUR

T1 - Solubility of d-elements salts in organic and aqueous-organic solvents

T2 - III. Influence of intermolecular association on solubility of cadmium bromide and iodide

AU - Bogachev, N. A.

AU - Gorbunov, A. O.

AU - Nikolskii, A. B.

AU - Skripkin, M. Yu.

PY - 2016/7

Y1 - 2016/7

N2 - Solubility in the systems CdX2-H2O-Solv (X = Br, I; Solv = dimethyl sulfoxide, N,N-dimethyl acetamide, N,N-dimethyl formamide, and 1,4-dioxane) at 25A degrees C was measured by the isothermal saturation method. A relation between the shape of the solubility isotherm and the structure of the binary solvent depending on its composition was found. Positions of solubility maxima and isotherms inflection points in the most cases correlate with destruction of intermolecular associates formed by solvent components.

AB - Solubility in the systems CdX2-H2O-Solv (X = Br, I; Solv = dimethyl sulfoxide, N,N-dimethyl acetamide, N,N-dimethyl formamide, and 1,4-dioxane) at 25A degrees C was measured by the isothermal saturation method. A relation between the shape of the solubility isotherm and the structure of the binary solvent depending on its composition was found. Positions of solubility maxima and isotherms inflection points in the most cases correlate with destruction of intermolecular associates formed by solvent components.

KW - structure of liquid

KW - complex formation

KW - cadmium halides

KW - competing solvation

KW - THERMODYNAMIC PROPERTIES

KW - MIXTURES

KW - WATER

KW - SYSTEM

KW - COBALT

KW - DMSO

U2 - 10.1134/S107036321607001X

DO - 10.1134/S107036321607001X

M3 - статья

VL - 86

SP - 1539

EP - 1544

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 7

ER -