Research output: Contribution to journal › Article › peer-review
Solubility of d-elements salts in organic and aqueous-organic solvents : III. Influence of intermolecular association on solubility of cadmium bromide and iodide. / Bogachev, N. A.; Gorbunov, A. O.; Nikolskii, A. B.; Skripkin, M. Yu.
In: Russian Journal of General Chemistry, Vol. 86, No. 7, 07.2016, p. 1539-1544.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Solubility of d-elements salts in organic and aqueous-organic solvents
T2 - III. Influence of intermolecular association on solubility of cadmium bromide and iodide
AU - Bogachev, N. A.
AU - Gorbunov, A. O.
AU - Nikolskii, A. B.
AU - Skripkin, M. Yu.
PY - 2016/7
Y1 - 2016/7
N2 - Solubility in the systems CdX2-H2O-Solv (X = Br, I; Solv = dimethyl sulfoxide, N,N-dimethyl acetamide, N,N-dimethyl formamide, and 1,4-dioxane) at 25A degrees C was measured by the isothermal saturation method. A relation between the shape of the solubility isotherm and the structure of the binary solvent depending on its composition was found. Positions of solubility maxima and isotherms inflection points in the most cases correlate with destruction of intermolecular associates formed by solvent components.
AB - Solubility in the systems CdX2-H2O-Solv (X = Br, I; Solv = dimethyl sulfoxide, N,N-dimethyl acetamide, N,N-dimethyl formamide, and 1,4-dioxane) at 25A degrees C was measured by the isothermal saturation method. A relation between the shape of the solubility isotherm and the structure of the binary solvent depending on its composition was found. Positions of solubility maxima and isotherms inflection points in the most cases correlate with destruction of intermolecular associates formed by solvent components.
KW - structure of liquid
KW - complex formation
KW - cadmium halides
KW - competing solvation
KW - THERMODYNAMIC PROPERTIES
KW - MIXTURES
KW - WATER
KW - SYSTEM
KW - COBALT
KW - DMSO
U2 - 10.1134/S107036321607001X
DO - 10.1134/S107036321607001X
M3 - статья
VL - 86
SP - 1539
EP - 1544
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 7
ER -
ID: 9139777