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Solubility of d-element salts in organic and aqueous-organic solvents : II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride. / Gorbunov, A. O.; Tsyrul'nikov, N. A.; Tikhomirova, A. A.; Bogachev, N. A.; Skripkin, M. Yu.; Nikolskii, A. B.; Pestova, O. N.

In: Russian Journal of General Chemistry, Vol. 86, No. 4, 04.2016, p. 771-777.

Research output: Contribution to journal › Article › peer-review

Harvard

Gorbunov, AO, Tsyrul'nikov, NA, Tikhomirova, AA, Bogachev, NA, Skripkin, MY, Nikolskii, AB & Pestova, ON 2016, 'Solubility of d-element salts in organic and aqueous-organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride', Russian Journal of General Chemistry, vol. 86, no. 4, pp. 771-777. https://doi.org/10.1134/S1070363216040022

APA

Gorbunov, A. O., Tsyrul'nikov, N. A., Tikhomirova, A. A., Bogachev, N. A., Skripkin, M. Y., Nikolskii, A. B., & Pestova, O. N. (2016). Solubility of d-element salts in organic and aqueous-organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride. Russian Journal of General Chemistry, 86(4), 771-777. https://doi.org/10.1134/S1070363216040022

Vancouver

Gorbunov AO, Tsyrul'nikov NA, Tikhomirova AA, Bogachev NA, Skripkin MY, Nikolskii AB et al. Solubility of d-element salts in organic and aqueous-organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride. Russian Journal of General Chemistry. 2016 Apr;86(4):771-777. https://doi.org/10.1134/S1070363216040022

Author

Gorbunov, A. O. ; Tsyrul'nikov, N. A. ; Tikhomirova, A. A. ; Bogachev, N. A. ; Skripkin, M. Yu. ; Nikolskii, A. B. ; Pestova, O. N. / Solubility of d-element salts in organic and aqueous-organic solvents : II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride. In: Russian Journal of General Chemistry. 2016 ; Vol. 86, No. 4. pp. 771-777.

BibTeX

@article{87b3cbc29d804a299436335d78713e3c,
title = "Solubility of d-element salts in organic and aqueous-organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride",
abstract = "Solubility of salts in the systems MCl2-H2O-Solv (M = Co, Ni) and CoBr2-H2O-Solv (Solv = dimethyl sulfoxide, dimethyl formamide, and dimethyl acetamide) at 25A degrees C was measured experimentally. Dominating species of cobalt and nickel halides existing in various concentration regions were identified by analysis of electron absorption spectra. It was shown that the major factor defining solubility is the interaction of halocomplexes of metal ions with solvent molecules.",
keywords = "solubility, ternary systems, aqueous-organic solvents, halocomplex formation, cobalt halide complexes, nickel halide complexes, SOLVATION, COMPLEXES, WATER, IONS, N,N-DIMETHYLFORMAMIDE, N,N-DIMETHYLACETAMIDE, DIMETHYLSULFOXIDE, MANGANESE(II), SOFTNESS",
author = "Gorbunov, {A. O.} and Tsyrul'nikov, {N. A.} and Tikhomirova, {A. A.} and Bogachev, {N. A.} and Skripkin, {M. Yu.} and Nikolskii, {A. B.} and Pestova, {O. N.}",
year = "2016",
month = apr,
doi = "10.1134/S1070363216040022",
language = "Английский",
volume = "86",
pages = "771--777",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Solubility of d-element salts in organic and aqueous-organic solvents

T2 - II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride

AU - Gorbunov, A. O.

AU - Tsyrul'nikov, N. A.

AU - Tikhomirova, A. A.

AU - Bogachev, N. A.

AU - Skripkin, M. Yu.

AU - Nikolskii, A. B.

AU - Pestova, O. N.

PY - 2016/4

Y1 - 2016/4

N2 - Solubility of salts in the systems MCl2-H2O-Solv (M = Co, Ni) and CoBr2-H2O-Solv (Solv = dimethyl sulfoxide, dimethyl formamide, and dimethyl acetamide) at 25A degrees C was measured experimentally. Dominating species of cobalt and nickel halides existing in various concentration regions were identified by analysis of electron absorption spectra. It was shown that the major factor defining solubility is the interaction of halocomplexes of metal ions with solvent molecules.

AB - Solubility of salts in the systems MCl2-H2O-Solv (M = Co, Ni) and CoBr2-H2O-Solv (Solv = dimethyl sulfoxide, dimethyl formamide, and dimethyl acetamide) at 25A degrees C was measured experimentally. Dominating species of cobalt and nickel halides existing in various concentration regions were identified by analysis of electron absorption spectra. It was shown that the major factor defining solubility is the interaction of halocomplexes of metal ions with solvent molecules.

KW - solubility

KW - ternary systems

KW - aqueous-organic solvents

KW - halocomplex formation

KW - cobalt halide complexes

KW - nickel halide complexes

KW - SOLVATION

KW - COMPLEXES

KW - WATER

KW - IONS

KW - N,N-DIMETHYLFORMAMIDE

KW - N,N-DIMETHYLACETAMIDE

KW - DIMETHYLSULFOXIDE

KW - MANGANESE(II)

KW - SOFTNESS

U2 - 10.1134/S1070363216040022

DO - 10.1134/S1070363216040022

M3 - статья

VL - 86

SP - 771

EP - 777

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -

ID: 9140032