Solubility of Copper(II) Chloride in Mixed Organic Oxygen-Containing Solvents

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Solubility of Copper(II) Chloride in Mixed Organic Oxygen-Containing Solvents. / Bogachev, N. A.; Lyubichev, D. A.; Starova, G. L.; Nikolskii, A. B.; Skripkin, M. Yu.

In: Russian Journal of General Chemistry, Vol. 88, No. 4, 01.04.2018, p. 617-621.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{03684e0a480e4b68adb4dd883924cf97,

title = "Solubility of Copper(II) Chloride in Mixed Organic Oxygen-Containing Solvents",

abstract = "Solubility of copper(II) chloride at 25°C in binary organic solvents consisting of dimethyl sulfoxide, N,N-dimethylacetamide, and 1,4-dioxane was determined by the isothermal saturation method. The shape of solubility isotherms for all ternary systems under study is connected with the structural type of formed copper chloride solvates, the composition of which is defined by the solvent donor number. Solvates crystallize predominantly, where the metal ion coordinates molecules of the solvent with a greater donor power. The temperature increase in the system CuCl2–dimethylacetamide–dioxane up to 50°C leads to the formation of the cluster compound [Cu4Cl6O(DMA)4]; its structure was determined by the X-ray structural analysis method.",

keywords = "1,4-dioxane, copper chloride, copper clusters, dimethyl sulfoxide, N,N-dimethylacetamide, phase equilibria",

author = "Bogachev, {N. A.} and Lyubichev, {D. A.} and Starova, {G. L.} and Nikolskii, {A. B.} and Skripkin, {M. Yu}",

year = "2018",

month = apr,

day = "1",

doi = "10.1134/S1070363218040011",

language = "English",

volume = "88",

pages = "617--621",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "4",

}

RIS

TY - JOUR

T1 - Solubility of Copper(II) Chloride in Mixed Organic Oxygen-Containing Solvents

AU - Bogachev, N. A.

AU - Lyubichev, D. A.

AU - Starova, G. L.

AU - Nikolskii, A. B.

AU - Skripkin, M. Yu

PY - 2018/4/1

Y1 - 2018/4/1

N2 - Solubility of copper(II) chloride at 25°C in binary organic solvents consisting of dimethyl sulfoxide, N,N-dimethylacetamide, and 1,4-dioxane was determined by the isothermal saturation method. The shape of solubility isotherms for all ternary systems under study is connected with the structural type of formed copper chloride solvates, the composition of which is defined by the solvent donor number. Solvates crystallize predominantly, where the metal ion coordinates molecules of the solvent with a greater donor power. The temperature increase in the system CuCl2–dimethylacetamide–dioxane up to 50°C leads to the formation of the cluster compound [Cu4Cl6O(DMA)4]; its structure was determined by the X-ray structural analysis method.

AB - Solubility of copper(II) chloride at 25°C in binary organic solvents consisting of dimethyl sulfoxide, N,N-dimethylacetamide, and 1,4-dioxane was determined by the isothermal saturation method. The shape of solubility isotherms for all ternary systems under study is connected with the structural type of formed copper chloride solvates, the composition of which is defined by the solvent donor number. Solvates crystallize predominantly, where the metal ion coordinates molecules of the solvent with a greater donor power. The temperature increase in the system CuCl2–dimethylacetamide–dioxane up to 50°C leads to the formation of the cluster compound [Cu4Cl6O(DMA)4]; its structure was determined by the X-ray structural analysis method.

KW - 1,4-dioxane

KW - copper chloride

KW - copper clusters

KW - dimethyl sulfoxide

KW - N,N-dimethylacetamide

KW - phase equilibria

UR - http://www.scopus.com/inward/record.url?scp=85048307534&partnerID=8YFLogxK

U2 - 10.1134/S1070363218040011

DO - 10.1134/S1070363218040011

M3 - Article

AN - SCOPUS:85048307534

VL - 88

SP - 617

EP - 621

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -

ID: 40042852