Standard

Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid – ethanol – ethyl formate – water at 298.15 K and 308.15 K. / Trofimova, Maya; Sadaev, Alexey; Samarov, Artemiy; Toikka, Maria; Toikka, Alexander.

In: Fluid Phase Equilibria, Vol. 485, 15.04.2019, p. 111-119.

Research output: Contribution to journal › Article › peer-review

Harvard

Trofimova, M, Sadaev, A, Samarov, A, Toikka, M & Toikka, A 2019, 'Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid – ethanol – ethyl formate – water at 298.15 K and 308.15 K', Fluid Phase Equilibria, vol. 485, pp. 111-119. https://doi.org/10.1016/j.fluid.2018.12.024

APA

Trofimova, M., Sadaev, A., Samarov, A., Toikka, M., & Toikka, A. (2019). Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid – ethanol – ethyl formate – water at 298.15 K and 308.15 K. Fluid Phase Equilibria, 485, 111-119. https://doi.org/10.1016/j.fluid.2018.12.024

Vancouver

Trofimova M, Sadaev A, Samarov A, Toikka M, Toikka A. Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid – ethanol – ethyl formate – water at 298.15 K and 308.15 K. Fluid Phase Equilibria. 2019 Apr 15;485:111-119. https://doi.org/10.1016/j.fluid.2018.12.024

Author

Trofimova, Maya ; Sadaev, Alexey ; Samarov, Artemiy ; Toikka, Maria ; Toikka, Alexander. / Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid – ethanol – ethyl formate – water at 298.15 K and 308.15 K. In: Fluid Phase Equilibria. 2019 ; Vol. 485. pp. 111-119.

BibTeX

@article{1d7e48fb7de44433a5e08bada0321eb4,
title = "Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid – ethanol – ethyl formate – water at 298.15 K and 308.15 K",
abstract = "Solubility, critical states and liquid-liquid equilibrium (LLE) in the quaternary reacting system formic acid – ethanol – ethyl formate – water and in the ternary subsystems formic acid – ethyl formate – water and ethanol – ethyl formate – water were studied experimentally at 298.15 K and 308.15 K and atmospheric pressure. Binodal curves, binodal surfaces, tie-lines and critical manifolds were determined. In order to construct binodal surfaces and critical curves of the quaternary system, five cutting planes with several different ratios of concentration of formic acid to ethanol were studied. Experimental LLE data were compared with the data calculated by NRTL model, and it was found that experimental and calculated data are in a good agreement.",
keywords = "Critical states, Ethyl formate, Liquid-liquid equilibrium, Solubility, CHEMICAL-EQUILIBRIUM, ALCOHOL, BINARY-SYSTEMS, ACETATE-WATER, METHANOATE, ACETIC-ACID",
author = "Maya Trofimova and Alexey Sadaev and Artemiy Samarov and Maria Toikka and Alexander Toikka",
year = "2019",
month = apr,
day = "15",
doi = "10.1016/j.fluid.2018.12.024",
language = "English",
volume = "485",
pages = "111--119",
journal = "Fluid Phase Equilibria",
issn = "0378-3812",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid – ethanol – ethyl formate – water at 298.15 K and 308.15 K

AU - Trofimova, Maya

AU - Sadaev, Alexey

AU - Samarov, Artemiy

AU - Toikka, Maria

AU - Toikka, Alexander

PY - 2019/4/15

Y1 - 2019/4/15

N2 - Solubility, critical states and liquid-liquid equilibrium (LLE) in the quaternary reacting system formic acid – ethanol – ethyl formate – water and in the ternary subsystems formic acid – ethyl formate – water and ethanol – ethyl formate – water were studied experimentally at 298.15 K and 308.15 K and atmospheric pressure. Binodal curves, binodal surfaces, tie-lines and critical manifolds were determined. In order to construct binodal surfaces and critical curves of the quaternary system, five cutting planes with several different ratios of concentration of formic acid to ethanol were studied. Experimental LLE data were compared with the data calculated by NRTL model, and it was found that experimental and calculated data are in a good agreement.

AB - Solubility, critical states and liquid-liquid equilibrium (LLE) in the quaternary reacting system formic acid – ethanol – ethyl formate – water and in the ternary subsystems formic acid – ethyl formate – water and ethanol – ethyl formate – water were studied experimentally at 298.15 K and 308.15 K and atmospheric pressure. Binodal curves, binodal surfaces, tie-lines and critical manifolds were determined. In order to construct binodal surfaces and critical curves of the quaternary system, five cutting planes with several different ratios of concentration of formic acid to ethanol were studied. Experimental LLE data were compared with the data calculated by NRTL model, and it was found that experimental and calculated data are in a good agreement.

KW - Critical states

KW - Ethyl formate

KW - Liquid-liquid equilibrium

KW - Solubility

KW - CHEMICAL-EQUILIBRIUM

KW - ALCOHOL

KW - BINARY-SYSTEMS

KW - ACETATE-WATER

KW - METHANOATE

KW - ACETIC-ACID

UR - http://www.scopus.com/inward/record.url?scp=85058932220&partnerID=8YFLogxK

U2 - 10.1016/j.fluid.2018.12.024

DO - 10.1016/j.fluid.2018.12.024

M3 - Article

AN - SCOPUS:85058932220

VL - 485

SP - 111

EP - 119

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

SN - 0378-3812

ER -

ID: 37692699