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Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure. / Toikka, Maria; Vernadskaya, Victoria; Samarov, Artemiy.

In: Fluid Phase Equilibria, Vol. 471, 15.09.2018, p. 68-73.

Research output: Contribution to journal › Article › peer-review

Harvard

Toikka, M, Vernadskaya, V & Samarov, A 2018, 'Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure', Fluid Phase Equilibria, vol. 471, pp. 68-73. https://doi.org/10.1016/j.fluid.2018.05.009

APA

Toikka, M., Vernadskaya, V., & Samarov, A. (2018). Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure. Fluid Phase Equilibria, 471, 68-73. https://doi.org/10.1016/j.fluid.2018.05.009

Vancouver

Toikka M, Vernadskaya V, Samarov A. Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure. Fluid Phase Equilibria. 2018 Sep 15;471:68-73. https://doi.org/10.1016/j.fluid.2018.05.009

Author

Toikka, Maria ; Vernadskaya, Victoria ; Samarov, Artemiy. / Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure. In: Fluid Phase Equilibria. 2018 ; Vol. 471. pp. 68-73.

BibTeX

@article{22b4e4a1bcbb4fb684dc37b808fa829c,
title = "Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure",
abstract = "The object of this study is multicomponent heterogeneous liquid-liquid system with n-amyl acetate synthesis reaction. New experimental data on solubility, liquid-liquid equilibrium (LLE) and critical compositions for acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure are presented. Solubility and critical states were investigated by “cloud-point technique” and pale opalescence blue methods accordingly. LLE compositions were determined by gas chromatography and correlated by NRTL model. Results calculated using NRTL modeling are in sufficient agreement with experimental data. Standard deviations for binary, ternary subsystems do not exceed 0.45% and for quaternary system investigated – 0.53%.",
keywords = "Cloud-point technique, Critical states, Liquid-liquid equilibrium, Multicomponent heterogeneous systems, n-Amyl acetate, Solubility",
author = "Maria Toikka and Victoria Vernadskaya and Artemiy Samarov",
year = "2018",
month = sep,
day = "15",
doi = "10.1016/j.fluid.2018.05.009",
language = "English",
volume = "471",
pages = "68--73",
journal = "Fluid Phase Equilibria",
issn = "0378-3812",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure

AU - Toikka, Maria

AU - Vernadskaya, Victoria

AU - Samarov, Artemiy

PY - 2018/9/15

Y1 - 2018/9/15

N2 - The object of this study is multicomponent heterogeneous liquid-liquid system with n-amyl acetate synthesis reaction. New experimental data on solubility, liquid-liquid equilibrium (LLE) and critical compositions for acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure are presented. Solubility and critical states were investigated by “cloud-point technique” and pale opalescence blue methods accordingly. LLE compositions were determined by gas chromatography and correlated by NRTL model. Results calculated using NRTL modeling are in sufficient agreement with experimental data. Standard deviations for binary, ternary subsystems do not exceed 0.45% and for quaternary system investigated – 0.53%.

AB - The object of this study is multicomponent heterogeneous liquid-liquid system with n-amyl acetate synthesis reaction. New experimental data on solubility, liquid-liquid equilibrium (LLE) and critical compositions for acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure are presented. Solubility and critical states were investigated by “cloud-point technique” and pale opalescence blue methods accordingly. LLE compositions were determined by gas chromatography and correlated by NRTL model. Results calculated using NRTL modeling are in sufficient agreement with experimental data. Standard deviations for binary, ternary subsystems do not exceed 0.45% and for quaternary system investigated – 0.53%.

KW - Cloud-point technique

KW - Critical states

KW - Liquid-liquid equilibrium

KW - Multicomponent heterogeneous systems

KW - n-Amyl acetate

KW - Solubility

UR - http://www.scopus.com/inward/record.url?scp=85046762016&partnerID=8YFLogxK

U2 - 10.1016/j.fluid.2018.05.009

DO - 10.1016/j.fluid.2018.05.009

M3 - Article

AN - SCOPUS:85046762016

VL - 471

SP - 68

EP - 73

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

SN - 0378-3812

ER -

ID: 46154326