Solid–Vapor Equilibria under Desolvation of Solid Solutions. Topological Isomorphism with Phase Diagrams of Polymorphic Solid Solutions

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Solid–Vapor Equilibria under Desolvation of Solid Solutions. Topological Isomorphism with Phase Diagrams of Polymorphic Solid Solutions. / Charykov, N.A.; Kuznetsov, V.V.; Rumyantsev, A.V.; Keskinov, V.A.; Kulenova, N.A.; Semenov, K.N.; Charykova, M.V.; German, V.P.

In: Russian Journal of Inorganic Chemistry, 29.10.2024.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{246c9d41c1f54d5297c67d80653b09e9,

title = "Solid–Vapor Equilibria under Desolvation of Solid Solutions. Topological Isomorphism with Phase Diagrams of Polymorphic Solid Solutions",

abstract = "Abstract: This paper provides a proof for the operation of analogues of the three Gibbs–Konovalov laws (Gibbs–Roozeboom rules) in solid–vapor phase diagrams of ternary systems under the conditions of solid solutions desolvation in the absence of liquid phases. The diagrams under consideration are shown to feature topological isomorphism to phase diagrams of polymorphic transformations of solid solutions in binary systems, for which analogues of the Gibbs–Konovalov laws are also formulated. The proof is based on the application of generalized van der Waals differential equations to the phase equilibrium shift, written in the metrics of the incomplete and complete Gibbs potentials of solid phases of variable composition. The applicability of the laws (rules) analogues is shown for a number of model systems. A method is proposed for the separation and purification of salt components of solid solutions based on the laws recognized for the phase diagrams of solid solutions desolvation. {\textcopyright} Pleiades Publishing, Ltd. 2024. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2024. Pleiades Publishing, Ltd., 2024.",

keywords = "solid solutions desolvation, topological isomorphism, Desalination, Phase equilibria, Condition, Desolvation, Liquid phasis, Solid solution desolvation, Solid-vapor, Solid-vapour equilibrium, Topological isomorphism, Vapor Phase, Vapor phasis, Vapour-phase, Van der Waals forces",

author = "N.A. Charykov and V.V. Kuznetsov and A.V. Rumyantsev and V.A. Keskinov and N.A. Kulenova and K.N. Semenov and M.V. Charykova and V.P. German",

note = "Export Date: 10 November 2024 CODEN: RJICA",

year = "2024",

month = oct,

day = "29",

doi = "10.1134/s0036023624602319",

language = "Английский",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

}

RIS

TY - JOUR

T1 - Solid–Vapor Equilibria under Desolvation of Solid Solutions. Topological Isomorphism with Phase Diagrams of Polymorphic Solid Solutions

AU - Charykov, N.A.

AU - Kuznetsov, V.V.

AU - Rumyantsev, A.V.

AU - Keskinov, V.A.

AU - Kulenova, N.A.

AU - Semenov, K.N.

AU - Charykova, M.V.

AU - German, V.P.

N1 - Export Date: 10 November 2024 CODEN: RJICA

PY - 2024/10/29

Y1 - 2024/10/29

N2 - Abstract: This paper provides a proof for the operation of analogues of the three Gibbs–Konovalov laws (Gibbs–Roozeboom rules) in solid–vapor phase diagrams of ternary systems under the conditions of solid solutions desolvation in the absence of liquid phases. The diagrams under consideration are shown to feature topological isomorphism to phase diagrams of polymorphic transformations of solid solutions in binary systems, for which analogues of the Gibbs–Konovalov laws are also formulated. The proof is based on the application of generalized van der Waals differential equations to the phase equilibrium shift, written in the metrics of the incomplete and complete Gibbs potentials of solid phases of variable composition. The applicability of the laws (rules) analogues is shown for a number of model systems. A method is proposed for the separation and purification of salt components of solid solutions based on the laws recognized for the phase diagrams of solid solutions desolvation. © Pleiades Publishing, Ltd. 2024. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2024. Pleiades Publishing, Ltd., 2024.

AB - Abstract: This paper provides a proof for the operation of analogues of the three Gibbs–Konovalov laws (Gibbs–Roozeboom rules) in solid–vapor phase diagrams of ternary systems under the conditions of solid solutions desolvation in the absence of liquid phases. The diagrams under consideration are shown to feature topological isomorphism to phase diagrams of polymorphic transformations of solid solutions in binary systems, for which analogues of the Gibbs–Konovalov laws are also formulated. The proof is based on the application of generalized van der Waals differential equations to the phase equilibrium shift, written in the metrics of the incomplete and complete Gibbs potentials of solid phases of variable composition. The applicability of the laws (rules) analogues is shown for a number of model systems. A method is proposed for the separation and purification of salt components of solid solutions based on the laws recognized for the phase diagrams of solid solutions desolvation. © Pleiades Publishing, Ltd. 2024. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2024. Pleiades Publishing, Ltd., 2024.

KW - solid solutions desolvation

KW - topological isomorphism

KW - Desalination

KW - Phase equilibria

KW - Condition

KW - Desolvation

KW - Liquid phasis

KW - Solid solution desolvation

KW - Solid-vapor

KW - Solid-vapour equilibrium

KW - Topological isomorphism

KW - Vapor Phase

KW - Vapor phasis

KW - Vapour-phase

KW - Van der Waals forces

UR - https://www.mendeley.com/catalogue/f7bbd775-a612-399d-baa0-d2ac690d6aa7/

U2 - 10.1134/s0036023624602319

DO - 10.1134/s0036023624602319

M3 - статья

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

ER -

ID: 127213983