Standard

Solid-Contact Ion-Selective Electrodes with Copper Hexacyanoferrate in the Transducer Layer. / Тимофеев, Василий Владимирович; Левин, Михаил Борисович; Старикова, Анна Александровна; Трофимов, Михаил Алексеевич; Корнеев, Сергей Михайлович; Михельсон, Константин Николаевич.

In: Russian Journal of Electrochemistry, Vol. 54, No. 4, 01.04.2018, p. 400-408.

Research output: Contribution to journal › Article › peer-review

Harvard

Тимофеев, ВВ, Левин, МБ, Старикова, АА, Трофимов, МА, Корнеев, СМ & Михельсон, КН 2018, 'Solid-Contact Ion-Selective Electrodes with Copper Hexacyanoferrate in the Transducer Layer', Russian Journal of Electrochemistry, vol. 54, no. 4, pp. 400-408. https://doi.org/10.1134/S1023193518040080

APA

Тимофеев, В. В., Левин, М. Б., Старикова, А. А., Трофимов, М. А., Корнеев, С. М., & Михельсон, К. Н. (2018). Solid-Contact Ion-Selective Electrodes with Copper Hexacyanoferrate in the Transducer Layer. Russian Journal of Electrochemistry, 54(4), 400-408. https://doi.org/10.1134/S1023193518040080

Vancouver

Тимофеев ВВ, Левин МБ, Старикова АА, Трофимов МА, Корнеев СМ, Михельсон КН. Solid-Contact Ion-Selective Electrodes with Copper Hexacyanoferrate in the Transducer Layer. Russian Journal of Electrochemistry. 2018 Apr 1;54(4):400-408. https://doi.org/10.1134/S1023193518040080

Author

Тимофеев, Василий Владимирович ; Левин, Михаил Борисович ; Старикова, Анна Александровна ; Трофимов, Михаил Алексеевич ; Корнеев, Сергей Михайлович ; Михельсон, Константин Николаевич. / Solid-Contact Ion-Selective Electrodes with Copper Hexacyanoferrate in the Transducer Layer. In: Russian Journal of Electrochemistry. 2018 ; Vol. 54, No. 4. pp. 400-408.

BibTeX

@article{2fdf30eca20e425bbfabba61c5cfd6ce,
title = "Solid-Contact Ion-Selective Electrodes with Copper Hexacyanoferrate in the Transducer Layer",
abstract = "The possibility of using mixed Fe 2+/Fe 3+ copper hexacyanoferrate (CuHCF) as the material for the transducer layer of solid-contact ion-selective electrodes (SC-ISEs) with plasticized polyvinylchloride membranes is studied. The study is performed for K +-SC-ISEs and water-hardness SC-ISEs. It is shown that CuHCF combines the ion-exchange and redox properties and, hence, in principle, should be suitable for SC-ISEs. However, the reproducibility of SC-ISE potentials from one electrode to another and their stability in time are far below those of conventional ISEs with internal aqueous solution. The potentials of individual SC-ISEs can be brought closer to one another by their polarization using a potentiostat or by their short-circuiting to a saturated silver-chloride reference electrode. ",
keywords = "copper hexacyanoferrate, potassium ions, solid-contact ion-selective electrodes, water hardness",
author = "Тимофеев, {Василий Владимирович} and Левин, {Михаил Борисович} and Старикова, {Анна Александровна} and Трофимов, {Михаил Алексеевич} and Корнеев, {Сергей Михайлович} and Михельсон, {Константин Николаевич}",
note = "Funding Information: ACKNOWLEDGEMENTS This work was supported by St.Petersburg University, grant 12.38.235.2014.",
year = "2018",
month = apr,
day = "1",
doi = "10.1134/S1023193518040080",
language = "English",
volume = "54",
pages = "400--408",
journal = "Russian Journal of Electrochemistry",
issn = "1023-1935",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Solid-Contact Ion-Selective Electrodes with Copper Hexacyanoferrate in the Transducer Layer

AU - Тимофеев, Василий Владимирович

AU - Левин, Михаил Борисович

AU - Старикова, Анна Александровна

AU - Трофимов, Михаил Алексеевич

AU - Корнеев, Сергей Михайлович

AU - Михельсон, Константин Николаевич

N1 - Funding Information: ACKNOWLEDGEMENTS This work was supported by St.Petersburg University, grant 12.38.235.2014.

PY - 2018/4/1

Y1 - 2018/4/1

N2 - The possibility of using mixed Fe 2+/Fe 3+ copper hexacyanoferrate (CuHCF) as the material for the transducer layer of solid-contact ion-selective electrodes (SC-ISEs) with plasticized polyvinylchloride membranes is studied. The study is performed for K +-SC-ISEs and water-hardness SC-ISEs. It is shown that CuHCF combines the ion-exchange and redox properties and, hence, in principle, should be suitable for SC-ISEs. However, the reproducibility of SC-ISE potentials from one electrode to another and their stability in time are far below those of conventional ISEs with internal aqueous solution. The potentials of individual SC-ISEs can be brought closer to one another by their polarization using a potentiostat or by their short-circuiting to a saturated silver-chloride reference electrode.

AB - The possibility of using mixed Fe 2+/Fe 3+ copper hexacyanoferrate (CuHCF) as the material for the transducer layer of solid-contact ion-selective electrodes (SC-ISEs) with plasticized polyvinylchloride membranes is studied. The study is performed for K +-SC-ISEs and water-hardness SC-ISEs. It is shown that CuHCF combines the ion-exchange and redox properties and, hence, in principle, should be suitable for SC-ISEs. However, the reproducibility of SC-ISE potentials from one electrode to another and their stability in time are far below those of conventional ISEs with internal aqueous solution. The potentials of individual SC-ISEs can be brought closer to one another by their polarization using a potentiostat or by their short-circuiting to a saturated silver-chloride reference electrode.

KW - copper hexacyanoferrate

KW - potassium ions

KW - solid-contact ion-selective electrodes

KW - water hardness

UR - http://www.scopus.com/inward/record.url?scp=85046692006&partnerID=8YFLogxK

U2 - 10.1134/S1023193518040080

DO - 10.1134/S1023193518040080

M3 - Article

VL - 54

SP - 400

EP - 408

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 4

ER -

ID: 24072821