It is shown that the semiconductor-metal transition (SMT) in chalcogenide glass-forming liquids takes place over a range of temperatures and is accompanied by an endothermic effect and structural transformation. Therefore, it should be referred to as a smeared first-order phase transition with the micro-regions of co-operative structural transformations involving 102 or more atoms. Apparently, this mechanism of the SMT is determined by the structure of glass-forming liquids and glasses in which there are structurally self-consistent regions, i.e., by medium-range order.

Original languageEnglish
Pages (from-to)78-82
Number of pages5
JournalJournal of Non-Crystalline Solids
Volume256
DOIs
StatePublished - 2 Oct 1999
EventProceedings of the 1998 11th International Symposium on Non-Oxide and New Optical Glasses - Sheffield, UK
Duration: 6 Sep 199810 Sep 1998

    Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

ID: 43156350