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Vibrational relaxation of a single-component carbon dioxide in adiabatic thermal bath is studied in multi-temperature approaches using several models for the vibrational relaxation time. The energy production terms in two- A nd three-temperature vibrational energy relaxation equations are written in the frame of the common Landau-Teller model as well using corrections based on introducing multi-temperature relaxation times for various vibrational energy exchanges within and between CO2 modes. For the relaxation time evaluation, two theoretical models for the transition probabilities are implemented: The first-order perturbation theory and the forced harmonic oscillator model; several experimental data sets are also assessed. It is shown that the forced harmonic oscillator model provides satisfactory agreement with experimental relaxation times in a wide temperature range. Solutions obtained using the two theoretical models for the transition probabilities show essentially different trends, incubation time and relaxation rate.
Original language | English |
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Article number | 012030 |
Number of pages | 8 |
Journal | Journal of Physics: Conference Series |
Volume | 1959 |
Issue number | 1 |
DOIs | |
State | Published - 14 Jul 2021 |
Event | Международная научная конференция по механике «IX Поляховские чтения» - СПбГУ, Санкт-Петербург, Russian Federation Duration: 9 Mar 2021 → 12 Mar 2021 Conference number: IX https://events.spbu.ru/events/polyakhov-2021 |
ID: 78890045