Vibrational relaxation of a single-component carbon dioxide in adiabatic thermal bath is studied in multi-temperature approaches using several models for the vibrational relaxation time. The energy production terms in two- A nd three-temperature vibrational energy relaxation equations are written in the frame of the common Landau-Teller model as well using corrections based on introducing multi-temperature relaxation times for various vibrational energy exchanges within and between CO2 modes. For the relaxation time evaluation, two theoretical models for the transition probabilities are implemented: The first-order perturbation theory and the forced harmonic oscillator model; several experimental data sets are also assessed. It is shown that the forced harmonic oscillator model provides satisfactory agreement with experimental relaxation times in a wide temperature range. Solutions obtained using the two theoretical models for the transition probabilities show essentially different trends, incubation time and relaxation rate.

Original languageEnglish
Article number012030
Number of pages8
JournalJournal of Physics: Conference Series
Volume1959
Issue number1
DOIs
StatePublished - 14 Jul 2021
EventМеждународная научная конференция по механике «IX Поляховские чтения» - СПбГУ, Санкт-Петербург, Russian Federation
Duration: 9 Mar 202112 Mar 2021
Conference number: IX
https://events.spbu.ru/events/polyakhov-2021

    Scopus subject areas

  • Physics and Astronomy(all)

ID: 78890045