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Shape-anisotropic cobalt-germanium-borate glass flakes as novel Li-ion battery anodes. / Esper, Julian D.; Zhuo, Ying; Barr, Maïssa K.S.; Yokosawa, Tadahiro; Spiecker, Erdmann; de Ligny, Dominique; Bachmann, Julien; Peukert, Wolfgang; Romeis, Stefan.

In: Powder Technology, Vol. 363, 01.03.2020, p. 218-231.

Research output: Contribution to journal › Article › peer-review

Harvard

Esper, JD, Zhuo, Y, Barr, MKS, Yokosawa, T, Spiecker, E, de Ligny, D, Bachmann, J, Peukert, W & Romeis, S 2020, 'Shape-anisotropic cobalt-germanium-borate glass flakes as novel Li-ion battery anodes', Powder Technology, vol. 363, pp. 218-231. https://doi.org/10.1016/j.powtec.2019.11.063

APA

Esper, J. D., Zhuo, Y., Barr, M. K. S., Yokosawa, T., Spiecker, E., de Ligny, D., Bachmann, J., Peukert, W., & Romeis, S. (2020). Shape-anisotropic cobalt-germanium-borate glass flakes as novel Li-ion battery anodes. Powder Technology, 363, 218-231. https://doi.org/10.1016/j.powtec.2019.11.063

Vancouver

Esper JD, Zhuo Y, Barr MKS, Yokosawa T, Spiecker E, de Ligny D et al. Shape-anisotropic cobalt-germanium-borate glass flakes as novel Li-ion battery anodes. Powder Technology. 2020 Mar 1;363:218-231. https://doi.org/10.1016/j.powtec.2019.11.063

Author

Esper, Julian D. ; Zhuo, Ying ; Barr, Maïssa K.S. ; Yokosawa, Tadahiro ; Spiecker, Erdmann ; de Ligny, Dominique ; Bachmann, Julien ; Peukert, Wolfgang ; Romeis, Stefan. / Shape-anisotropic cobalt-germanium-borate glass flakes as novel Li-ion battery anodes. In: Powder Technology. 2020 ; Vol. 363. pp. 218-231.

BibTeX

@article{f1f0d5add30949fa8ed003dbc3b64bd7,
title = "Shape-anisotropic cobalt-germanium-borate glass flakes as novel Li-ion battery anodes",
abstract = "Novel CoO-Li2O-B2O3 and CoO-GeO2-Li2O-B2O3 flake-like glass particles for battery applications are produced by an innovative technique: Glasses from melt quenching are processed into micron-sized glass flakes in a stirred media mill. Processing under well-controlled conditions yields flake-like particles with high aspect ratios which are suitable for anodes in Lithium-ion batteries. Electrochemical characterization by cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge/discharge cycles and rate capability measurements indicates that the flakes show superior electrochemical properties compared to the bulk glass counterparts with a stable specific capacity of 620 mAh g−1 after 100 cycles. The majority of charge is stored by Li+ ion diffusion inside the material and impedance spectroscopy shows enhanced lithium ion diffusion capabilities of the flakes. The proposed fabrication process is performed under ambient conditions and is simple, cost-efficient, fully scalable and can be easily transferred to other glass compositions with electrochemically active metal oxides.",
keywords = "Anode, Glasses, Lithium-ion battery, Particle design, Shape-anisotropy, STORAGE, OXIDE, CATHODES, PERFORMANCE, CARBON NANOTUBES, RECHARGEABLE LITHIUM, NANOPARTICLES, CO3O4, RATE CAPABILITY, HIGH-CAPACITY",
author = "Esper, {Julian D.} and Ying Zhuo and Barr, {Ma{\"i}ssa K.S.} and Tadahiro Yokosawa and Erdmann Spiecker and {de Ligny}, Dominique and Julien Bachmann and Wolfgang Peukert and Stefan Romeis",
note = "Funding Information: The authors thank Dr. Jochen Schmidt for performing the ICP OES measurements. Jakob Iser and Milena Stephan are acknowledged for assisting with lab work and sample preparation. SR acknowledges German Research Foundation (DFG) for providing funding through the starting grant of GRK1896 “In situ Microscopy with Electrons, X-rays and Scanning Probes”. Appendix A Publisher Copyright: {\textcopyright} 2019 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = mar,
day = "1",
doi = "10.1016/j.powtec.2019.11.063",
language = "English",
volume = "363",
pages = "218--231",
journal = "Powder Technology",
issn = "0032-5910",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Shape-anisotropic cobalt-germanium-borate glass flakes as novel Li-ion battery anodes

AU - Esper, Julian D.

AU - Zhuo, Ying

AU - Barr, Maïssa K.S.

AU - Yokosawa, Tadahiro

AU - Spiecker, Erdmann

AU - de Ligny, Dominique

AU - Bachmann, Julien

AU - Peukert, Wolfgang

AU - Romeis, Stefan

N1 - Funding Information: The authors thank Dr. Jochen Schmidt for performing the ICP OES measurements. Jakob Iser and Milena Stephan are acknowledged for assisting with lab work and sample preparation. SR acknowledges German Research Foundation (DFG) for providing funding through the starting grant of GRK1896 “In situ Microscopy with Electrons, X-rays and Scanning Probes”. Appendix A Publisher Copyright: © 2019 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/3/1

Y1 - 2020/3/1

N2 - Novel CoO-Li2O-B2O3 and CoO-GeO2-Li2O-B2O3 flake-like glass particles for battery applications are produced by an innovative technique: Glasses from melt quenching are processed into micron-sized glass flakes in a stirred media mill. Processing under well-controlled conditions yields flake-like particles with high aspect ratios which are suitable for anodes in Lithium-ion batteries. Electrochemical characterization by cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge/discharge cycles and rate capability measurements indicates that the flakes show superior electrochemical properties compared to the bulk glass counterparts with a stable specific capacity of 620 mAh g−1 after 100 cycles. The majority of charge is stored by Li+ ion diffusion inside the material and impedance spectroscopy shows enhanced lithium ion diffusion capabilities of the flakes. The proposed fabrication process is performed under ambient conditions and is simple, cost-efficient, fully scalable and can be easily transferred to other glass compositions with electrochemically active metal oxides.

AB - Novel CoO-Li2O-B2O3 and CoO-GeO2-Li2O-B2O3 flake-like glass particles for battery applications are produced by an innovative technique: Glasses from melt quenching are processed into micron-sized glass flakes in a stirred media mill. Processing under well-controlled conditions yields flake-like particles with high aspect ratios which are suitable for anodes in Lithium-ion batteries. Electrochemical characterization by cyclic voltammetry, electrochemical impedance spectroscopy, galvanostatic charge/discharge cycles and rate capability measurements indicates that the flakes show superior electrochemical properties compared to the bulk glass counterparts with a stable specific capacity of 620 mAh g−1 after 100 cycles. The majority of charge is stored by Li+ ion diffusion inside the material and impedance spectroscopy shows enhanced lithium ion diffusion capabilities of the flakes. The proposed fabrication process is performed under ambient conditions and is simple, cost-efficient, fully scalable and can be easily transferred to other glass compositions with electrochemically active metal oxides.

KW - Anode

KW - Glasses

KW - Lithium-ion battery

KW - Particle design

KW - Shape-anisotropy

KW - STORAGE

KW - OXIDE

KW - CATHODES

KW - PERFORMANCE

KW - CARBON NANOTUBES

KW - RECHARGEABLE LITHIUM

KW - NANOPARTICLES

KW - CO3O4

KW - RATE CAPABILITY

KW - HIGH-CAPACITY

UR - http://www.scopus.com/inward/record.url?scp=85077942458&partnerID=8YFLogxK

U2 - 10.1016/j.powtec.2019.11.063

DO - 10.1016/j.powtec.2019.11.063

M3 - Article

AN - SCOPUS:85077942458

VL - 363

SP - 218

EP - 231

JO - Powder Technology

JF - Powder Technology

SN - 0032-5910

ER -

ID: 70657800