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Separation Performance of BioRenewable Deep Eutectic Solvents. / Verevkin, S.P.; Sazonova, A.Y.; Frolkova, A.K.; Zaitsau, D.H.; Prikhodko, I.V.; Held, C.

In: Industrial and Engineering Chemistry Research, Vol. 54, No. 13, 2015, p. 3498-3504.

Research output: Contribution to journal › Article

Harvard

Verevkin, SP, Sazonova, AY, Frolkova, AK, Zaitsau, DH, Prikhodko, IV & Held, C 2015, 'Separation Performance of BioRenewable Deep Eutectic Solvents', Industrial and Engineering Chemistry Research, vol. 54, no. 13, pp. 3498-3504. https://doi.org/10.1021/acs.iecr.5b00357

APA

Verevkin, S. P., Sazonova, A. Y., Frolkova, A. K., Zaitsau, D. H., Prikhodko, I. V., & Held, C. (2015). Separation Performance of BioRenewable Deep Eutectic Solvents. Industrial and Engineering Chemistry Research, 54(13), 3498-3504. https://doi.org/10.1021/acs.iecr.5b00357

Vancouver

Verevkin SP, Sazonova AY, Frolkova AK, Zaitsau DH, Prikhodko IV, Held C. Separation Performance of BioRenewable Deep Eutectic Solvents. Industrial and Engineering Chemistry Research. 2015;54(13):3498-3504. https://doi.org/10.1021/acs.iecr.5b00357

Author

Verevkin, S.P. ; Sazonova, A.Y. ; Frolkova, A.K. ; Zaitsau, D.H. ; Prikhodko, I.V. ; Held, C. / Separation Performance of BioRenewable Deep Eutectic Solvents. In: Industrial and Engineering Chemistry Research. 2015 ; Vol. 54, No. 13. pp. 3498-3504.

BibTeX

@article{903a8bbd1904457eadb388eeda7d92da,
title = "Separation Performance of BioRenewable Deep Eutectic Solvents",
abstract = "ABSTRACT: Deep eutectic solvents (DESs) have been regarded as promising cost-effective and environmentally benign alternatives to conventional volatile organic solvents. The screening and selection of the suitable solvent for separation is an important part of the process design. Limiting activity coefficients provide a useful tool for the optimal choice of the selective solvent. For the first time, activity coefficients at infinite dilution have been measured in DESs as a solvent for 23 solutes(aliphatic and aromatic hydrocarbons, alcohols, ketones, ethers, and esters). The DESs were constituted from choline chloride and glycerol in molar ratios of 1:1 and 1:2. The measurements were carried out with the help of gas−liquid chromatography in the temperature range 298−358 K. Using experimental results, selectivity of different separation cases was assessed. To verify the separation performance of DESs the perturbed-chain statistical associating fluid theory (PC-SAFT) was employed for the first time. This method",
keywords = "deep eutectic solvents, activity coefficient at infinite dilution, separation, PC SAFT",
author = "S.P. Verevkin and A.Y. Sazonova and A.K. Frolkova and D.H. Zaitsau and I.V. Prikhodko and C. Held",
year = "2015",
doi = "10.1021/acs.iecr.5b00357",
language = "English",
volume = "54",
pages = "3498--3504",
journal = "Industrial and Engineering Chemistry Process Design and Development",
issn = "0888-5885",
publisher = "American Chemical Society",
number = "13",

}

RIS

TY - JOUR

T1 - Separation Performance of BioRenewable Deep Eutectic Solvents

AU - Verevkin, S.P.

AU - Sazonova, A.Y.

AU - Frolkova, A.K.

AU - Zaitsau, D.H.

AU - Prikhodko, I.V.

AU - Held, C.

PY - 2015

Y1 - 2015

N2 - ABSTRACT: Deep eutectic solvents (DESs) have been regarded as promising cost-effective and environmentally benign alternatives to conventional volatile organic solvents. The screening and selection of the suitable solvent for separation is an important part of the process design. Limiting activity coefficients provide a useful tool for the optimal choice of the selective solvent. For the first time, activity coefficients at infinite dilution have been measured in DESs as a solvent for 23 solutes(aliphatic and aromatic hydrocarbons, alcohols, ketones, ethers, and esters). The DESs were constituted from choline chloride and glycerol in molar ratios of 1:1 and 1:2. The measurements were carried out with the help of gas−liquid chromatography in the temperature range 298−358 K. Using experimental results, selectivity of different separation cases was assessed. To verify the separation performance of DESs the perturbed-chain statistical associating fluid theory (PC-SAFT) was employed for the first time. This method

AB - ABSTRACT: Deep eutectic solvents (DESs) have been regarded as promising cost-effective and environmentally benign alternatives to conventional volatile organic solvents. The screening and selection of the suitable solvent for separation is an important part of the process design. Limiting activity coefficients provide a useful tool for the optimal choice of the selective solvent. For the first time, activity coefficients at infinite dilution have been measured in DESs as a solvent for 23 solutes(aliphatic and aromatic hydrocarbons, alcohols, ketones, ethers, and esters). The DESs were constituted from choline chloride and glycerol in molar ratios of 1:1 and 1:2. The measurements were carried out with the help of gas−liquid chromatography in the temperature range 298−358 K. Using experimental results, selectivity of different separation cases was assessed. To verify the separation performance of DESs the perturbed-chain statistical associating fluid theory (PC-SAFT) was employed for the first time. This method

KW - deep eutectic solvents

KW - activity coefficient at infinite dilution

KW - separation

KW - PC SAFT

U2 - 10.1021/acs.iecr.5b00357

DO - 10.1021/acs.iecr.5b00357

M3 - Article

VL - 54

SP - 3498

EP - 3504

JO - Industrial and Engineering Chemistry Process Design and Development

JF - Industrial and Engineering Chemistry Process Design and Development

SN - 0888-5885

IS - 13

ER -

ID: 3929183