Research output: Contribution to journal › Article › peer-review
Separation of Boron Isotopes in Extraction Systems Tetrafluoroboric Acid–Organophosphorus Compounds. / Мальцева, Таисия Валерьевна; Бабитова, Екатерина Сергеевна; Смирнов, Игорь Валентинович.
In: Radiochemistry, Vol. 65, No. 2, 01.04.2023, p. 245-248.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Separation of Boron Isotopes in Extraction Systems Tetrafluoroboric Acid–Organophosphorus Compounds
AU - Мальцева, Таисия Валерьевна
AU - Бабитова, Екатерина Сергеевна
AU - Смирнов, Игорь Валентинович
PY - 2023/4/1
Y1 - 2023/4/1
N2 - Abstract: Extraction systems based on extraction of tetrafluoroboric acid (HBF4) with tributyl phosphate (TBP) and triamylphosphine oxide (TAPO) for boron isotope separation were studied. Tetrafluoroboric acid was studied in comparison with boric acid (H3BO3). The extraction isotherms at 20°C for four systems (boric and tetrafluoroboric acids extracted with TBP and TAPO in o-xylene) were obtained, and single-stage isotope separation factors for these four systems were determined. The lighter boron isotope (10B) is concentrated in the aqueous phase in the systems containing tetrafluoroboric acid, whereas in the systems with boric acid it is concentrated in the organic phase.
AB - Abstract: Extraction systems based on extraction of tetrafluoroboric acid (HBF4) with tributyl phosphate (TBP) and triamylphosphine oxide (TAPO) for boron isotope separation were studied. Tetrafluoroboric acid was studied in comparison with boric acid (H3BO3). The extraction isotherms at 20°C for four systems (boric and tetrafluoroboric acids extracted with TBP and TAPO in o-xylene) were obtained, and single-stage isotope separation factors for these four systems were determined. The lighter boron isotope (10B) is concentrated in the aqueous phase in the systems containing tetrafluoroboric acid, whereas in the systems with boric acid it is concentrated in the organic phase.
KW - boron isotope separation
KW - extraction
KW - tetrafluoroboric acid boric acid
KW - triamylphosphine oxide
KW - tributyl phosphate
UR - https://www.mendeley.com/catalogue/9109dac0-1aec-3823-b4b0-e4ea70e76ef3/
U2 - 10.1134/S1066362223020157
DO - 10.1134/S1066362223020157
M3 - Article
VL - 65
SP - 245
EP - 248
JO - Radiochemistry
JF - Radiochemistry
SN - 1066-3622
IS - 2
ER -
ID: 108300722