Research output: Contribution to journal › Article
Self-assembly of Supramolecular Luminescent Gold(I)-Copper(I) Complexes: “Wrapping” the Au6Cu6 Cluster with [Au3(diphosphine)3]3+ “Belt”. / Koshevoy, I.O.; Koskinen, L.; Haukka, M.; Tunik, S.P.; Serdobintsev, P.Yu.; Melnikov, A.S.; Pakkanen, T.A.
In: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Vol. 47, No. 21, 2008, p. 3942-3945.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Self-assembly of Supramolecular Luminescent Gold(I)-Copper(I) Complexes: “Wrapping” the Au6Cu6 Cluster with [Au3(diphosphine)3]3+ “Belt”
AU - Koshevoy, I.O.
AU - Koskinen, L.
AU - Haukka, M.
AU - Tunik, S.P.
AU - Serdobintsev, P.Yu.
AU - Melnikov, A.S.
AU - Pakkanen, T.A.
PY - 2008
Y1 - 2008
N2 - (Chemical Equation Presented) Belt and suspenders: A supramolecular gold-copper cluster has been synthesized by Cu+-assisted self-assembly of [Au-(C2Ph)2] rods and a gold-diphosphine belt, which is suspended from the Au6Cu6 core by Au-Au bonds (see picture). The cluster displays strong orange luminescence on excitation at 308 nm which is more intense than that of either of its structural fragments, which were isolated and studied independently. P-P = Ph 2PC6H4C6H4PPh 2. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
AB - (Chemical Equation Presented) Belt and suspenders: A supramolecular gold-copper cluster has been synthesized by Cu+-assisted self-assembly of [Au-(C2Ph)2] rods and a gold-diphosphine belt, which is suspended from the Au6Cu6 core by Au-Au bonds (see picture). The cluster displays strong orange luminescence on excitation at 308 nm which is more intense than that of either of its structural fragments, which were isolated and studied independently. P-P = Ph 2PC6H4C6H4PPh 2. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
U2 - DOI: 10.1002/anie.200800452
DO - DOI: 10.1002/anie.200800452
M3 - Article
VL - 47
SP - 3942
EP - 3945
JO - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
JF - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
SN - 1433-7851
IS - 21
ER -
ID: 5026165