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Selenium(IV) Polybromide Complexes : Structural Diversity Driven by Halogen and Chalcogen Bonding. / Korobeynikov, Nikita A.; Usoltsev, Andrey N.; Novikov, Alexander S.; Abramov, Pavel A.; Sokolov, Maxim N.; Adonin, Sergey A.

In: Molecules, Vol. 27, No. 16, 5355, 22.08.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Korobeynikov, NA, Usoltsev, AN, Novikov, AS, Abramov, PA, Sokolov, MN & Adonin, SA 2022, 'Selenium(IV) Polybromide Complexes: Structural Diversity Driven by Halogen and Chalcogen Bonding', Molecules, vol. 27, no. 16, 5355. https://doi.org/10.3390/molecules27165355

APA

Korobeynikov, N. A., Usoltsev, A. N., Novikov, A. S., Abramov, P. A., Sokolov, M. N., & Adonin, S. A. (2022). Selenium(IV) Polybromide Complexes: Structural Diversity Driven by Halogen and Chalcogen Bonding. Molecules, 27(16), [5355]. https://doi.org/10.3390/molecules27165355

Vancouver

Korobeynikov NA, Usoltsev AN, Novikov AS, Abramov PA, Sokolov MN, Adonin SA. Selenium(IV) Polybromide Complexes: Structural Diversity Driven by Halogen and Chalcogen Bonding. Molecules. 2022 Aug 22;27(16). 5355. https://doi.org/10.3390/molecules27165355

Author

Korobeynikov, Nikita A. ; Usoltsev, Andrey N. ; Novikov, Alexander S. ; Abramov, Pavel A. ; Sokolov, Maxim N. ; Adonin, Sergey A. / Selenium(IV) Polybromide Complexes : Structural Diversity Driven by Halogen and Chalcogen Bonding. In: Molecules. 2022 ; Vol. 27, No. 16.

BibTeX

@article{f6914d58935e40aaaf0352c8c8aacb4e,
title = "Selenium(IV) Polybromide Complexes: Structural Diversity Driven by Halogen and Chalcogen Bonding",
abstract = "Reactions between bromoselenate(IV)-containing solutions, dibromine and salts of pyridinium-family organic cations resulted in structurally diverse, bromine-rich polybromine-bromoselenates(IV): (4-MePyH)5[Se2Br9][SeBr6](Br3)2 (1), (2-MePyH)2{[SeBr6](Br2)} (2), (PyH)2{[SeBr5]Br(Br2)2} (3), (1-MePy)2{[SeBr6](Br2)} (4). The compounds feature halogen and (in the case of 3) chalcogen bonding in solid state, resulting in formation of supramolecular architectures of different dimensionality. DFT calculations allowed estimation of the energies of non-covalent interactions in 1–4; additionally, characterization by Raman spectroscopy was performed.",
keywords = "chalcogen bonding, halogen bonding, non-covalent interactions, polyhalogens, selenium",
author = "Korobeynikov, {Nikita A.} and Usoltsev, {Andrey N.} and Novikov, {Alexander S.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",
note = "Korobeynikov, N.A.; Usoltsev, A.N.; Novikov, A.S.; Abramov, P.A.; Sokolov, M.N.; Adonin, S.A. Selenium(IV) Polybromide Complexes: Structural Diversity Driven by Halogen and Chalcogen Bonding. Molecules 2022, 27, 5355. https://doi.org/10.3390/molecules27165355",
year = "2022",
month = aug,
day = "22",
doi = "10.3390/molecules27165355",
language = "English",
volume = "27",
journal = "Molecules",
issn = "1420-3049",
publisher = "MDPI AG",
number = "16",

}

RIS

TY - JOUR

T1 - Selenium(IV) Polybromide Complexes

T2 - Structural Diversity Driven by Halogen and Chalcogen Bonding

AU - Korobeynikov, Nikita A.

AU - Usoltsev, Andrey N.

AU - Novikov, Alexander S.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

N1 - Korobeynikov, N.A.; Usoltsev, A.N.; Novikov, A.S.; Abramov, P.A.; Sokolov, M.N.; Adonin, S.A. Selenium(IV) Polybromide Complexes: Structural Diversity Driven by Halogen and Chalcogen Bonding. Molecules 2022, 27, 5355. https://doi.org/10.3390/molecules27165355

PY - 2022/8/22

Y1 - 2022/8/22

N2 - Reactions between bromoselenate(IV)-containing solutions, dibromine and salts of pyridinium-family organic cations resulted in structurally diverse, bromine-rich polybromine-bromoselenates(IV): (4-MePyH)5[Se2Br9][SeBr6](Br3)2 (1), (2-MePyH)2{[SeBr6](Br2)} (2), (PyH)2{[SeBr5]Br(Br2)2} (3), (1-MePy)2{[SeBr6](Br2)} (4). The compounds feature halogen and (in the case of 3) chalcogen bonding in solid state, resulting in formation of supramolecular architectures of different dimensionality. DFT calculations allowed estimation of the energies of non-covalent interactions in 1–4; additionally, characterization by Raman spectroscopy was performed.

AB - Reactions between bromoselenate(IV)-containing solutions, dibromine and salts of pyridinium-family organic cations resulted in structurally diverse, bromine-rich polybromine-bromoselenates(IV): (4-MePyH)5[Se2Br9][SeBr6](Br3)2 (1), (2-MePyH)2{[SeBr6](Br2)} (2), (PyH)2{[SeBr5]Br(Br2)2} (3), (1-MePy)2{[SeBr6](Br2)} (4). The compounds feature halogen and (in the case of 3) chalcogen bonding in solid state, resulting in formation of supramolecular architectures of different dimensionality. DFT calculations allowed estimation of the energies of non-covalent interactions in 1–4; additionally, characterization by Raman spectroscopy was performed.

KW - chalcogen bonding

KW - halogen bonding

KW - non-covalent interactions

KW - polyhalogens

KW - selenium

UR - http://www.scopus.com/inward/record.url?scp=85136845421&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/0347392b-2266-3330-a96e-434791856203/

U2 - 10.3390/molecules27165355

DO - 10.3390/molecules27165355

M3 - Article

C2 - 36014592

AN - SCOPUS:85136845421

VL - 27

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 16

M1 - 5355

ER -

ID: 98879480