Selective and reversible 1,3-dipolar cycloaddition of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones under microwave irradiation

Standard

Selective and reversible 1,3-dipolar cycloaddition of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones under microwave irradiation. / Molchanov, A.P.; Efremova, M.M.; Kryukova, M.A.; Kuznetsov, M.A.

In: Beilstein Journal of Organic Chemistry, Vol. 16, 30.10.2020, p. 2679-2686.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{12c5e48f73b44844889c7f4d139c64f5,

title = "Selective and reversible 1,3-dipolar cycloaddition of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones under microwave irradiation",

abstract = "The first example of the cycloaddition of in situ-generated azomethine imine under microwave conditions is described. The reaction of 6-aryl-1,5-diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones proceeds regio- and stereoselectively giving mostly good yields of the corresponding perhydropyrazolopyrazoles. The products of the reaction undergo cycloreversion under the reaction conditions.",

keywords = "azomethine imines; cycloaddition; diazabicyclohexanes; diaziridines; regioselectivity, Azomethine imines, cycloaddition, diazabicyclohexanes, diaziridines, Regioselectivity, regioselectivity, THERMOLYSIS, ANALOGS, azomethine imines, DIAZIRIDINE RING, METATHESIS, AZOMETHINE IMINES",

author = "A.P. Molchanov and M.M. Efremova and M.A. Kryukova and M.A. Kuznetsov",

note = "Copyright {\textcopyright} 2020, Molchanov et al.; licensee Beilstein-Institut.",

year = "2020",

month = oct,

day = "30",

doi = "10.3762/bjoc.16.218",

language = "English",

volume = "16",

pages = "2679--2686",

journal = "Beilstein Journal of Organic Chemistry",

issn = "2195-951X",

publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",

}

RIS

TY - JOUR

T1 - Selective and reversible 1,3-dipolar cycloaddition of 6-aryl-1,5- diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones under microwave irradiation

AU - Molchanov, A.P.

AU - Efremova, M.M.

AU - Kryukova, M.A.

AU - Kuznetsov, M.A.

PY - 2020/10/30

Y1 - 2020/10/30

N2 - The first example of the cycloaddition of in situ-generated azomethine imine under microwave conditions is described. The reaction of 6-aryl-1,5-diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones proceeds regio- and stereoselectively giving mostly good yields of the corresponding perhydropyrazolopyrazoles. The products of the reaction undergo cycloreversion under the reaction conditions.

AB - The first example of the cycloaddition of in situ-generated azomethine imine under microwave conditions is described. The reaction of 6-aryl-1,5-diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones proceeds regio- and stereoselectively giving mostly good yields of the corresponding perhydropyrazolopyrazoles. The products of the reaction undergo cycloreversion under the reaction conditions.

KW - azomethine imines; cycloaddition; diazabicyclohexanes; diaziridines; regioselectivity

KW - Azomethine imines

KW - cycloaddition

KW - diazabicyclohexanes

KW - diaziridines

KW - Regioselectivity

KW - regioselectivity

KW - THERMOLYSIS

KW - ANALOGS

KW - azomethine imines

KW - DIAZIRIDINE RING

KW - METATHESIS

KW - AZOMETHINE IMINES

UR - https://www.mendeley.com/catalogue/c100ebc6-ca7c-3bab-bdee-927b5f9c1573/

U2 - 10.3762/bjoc.16.218

DO - 10.3762/bjoc.16.218

M3 - Article

C2 - 33178358

VL - 16

SP - 2679

EP - 2686

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 2195-951X

ER -

ID: 70764836