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Ring opening of azetidine cycle : First examples of 1-azetidinepropanamine molecules as a template in hybrid organic-inorganic compounds. / Gurzhiy, Vladislav V.; Tyumentseva, Olga S.; Britvin, Sergey N.; Krivovichev, Sergey V.; Tananaev, Ivan G.

In: Journal of Molecular Structure, Vol. 1151, 05.01.2018, p. 88-96.

Research output: Contribution to journal › Article › peer-review

Harvard

Gurzhiy, VV, Tyumentseva, OS, Britvin, SN, Krivovichev, SV & Tananaev, IG 2018, 'Ring opening of azetidine cycle: First examples of 1-azetidinepropanamine molecules as a template in hybrid organic-inorganic compounds', Journal of Molecular Structure, vol. 1151, pp. 88-96. https://doi.org/10.1016/j.molstruc.2017.09.042

APA

Gurzhiy, V. V., Tyumentseva, O. S., Britvin, S. N., Krivovichev, S. V., & Tananaev, I. G. (2018). Ring opening of azetidine cycle: First examples of 1-azetidinepropanamine molecules as a template in hybrid organic-inorganic compounds. Journal of Molecular Structure, 1151, 88-96. https://doi.org/10.1016/j.molstruc.2017.09.042

Vancouver

Gurzhiy VV, Tyumentseva OS, Britvin SN, Krivovichev SV, Tananaev IG. Ring opening of azetidine cycle: First examples of 1-azetidinepropanamine molecules as a template in hybrid organic-inorganic compounds. Journal of Molecular Structure. 2018 Jan 5;1151:88-96. https://doi.org/10.1016/j.molstruc.2017.09.042

Author

Gurzhiy, Vladislav V. ; Tyumentseva, Olga S. ; Britvin, Sergey N. ; Krivovichev, Sergey V. ; Tananaev, Ivan G. / Ring opening of azetidine cycle : First examples of 1-azetidinepropanamine molecules as a template in hybrid organic-inorganic compounds. In: Journal of Molecular Structure. 2018 ; Vol. 1151. pp. 88-96.

BibTeX

@article{74a685122bda481bb02393beaa334f62,
title = "Ring opening of azetidine cycle: First examples of 1-azetidinepropanamine molecules as a template in hybrid organic-inorganic compounds",
abstract = "Three novel uranyl selenate and sulfate oxysalts templated by protonated azetidine molecules, [AzH]+, and its ring-opened counterpart 1-azetidinepropanamine, [AzH(CH2)3NH3]2+, have been prepared and studied by X-ray structural analysis. Conformations of azetidinium cations were analysed by means of infrared vibrational assignments supported by the DFT calculations. Crystallization of [AzH]2 [(UO2)2(SeO4)3(H2O)] (I) from highly acidic solutions suggests that low pH does not necessarily result in the opening of azetidine ring. [AzH(CH2)3NH3][(UO2)2(SeO4)3(H2O)](H2O) (II) and [AzH(CH2)3NH3](H5O2)[(UO2)2(SO4)3(HSO4)] (III) are the first structurally characterized crystalline compounds bearing isolated ring-opened azetidine moiety.",
keywords = "Azetidine, Crystal structure, Ring opening, Selenate, Structural topology, Sulfate, Uranyl",
author = "Gurzhiy, {Vladislav V.} and Tyumentseva, {Olga S.} and Britvin, {Sergey N.} and Krivovichev, {Sergey V.} and Tananaev, {Ivan G.}",
year = "2018",
month = jan,
day = "5",
doi = "10.1016/j.molstruc.2017.09.042",
language = "English",
volume = "1151",
pages = "88--96",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Ring opening of azetidine cycle

T2 - First examples of 1-azetidinepropanamine molecules as a template in hybrid organic-inorganic compounds

AU - Gurzhiy, Vladislav V.

AU - Tyumentseva, Olga S.

AU - Britvin, Sergey N.

AU - Krivovichev, Sergey V.

AU - Tananaev, Ivan G.

PY - 2018/1/5

Y1 - 2018/1/5

N2 - Three novel uranyl selenate and sulfate oxysalts templated by protonated azetidine molecules, [AzH]+, and its ring-opened counterpart 1-azetidinepropanamine, [AzH(CH2)3NH3]2+, have been prepared and studied by X-ray structural analysis. Conformations of azetidinium cations were analysed by means of infrared vibrational assignments supported by the DFT calculations. Crystallization of [AzH]2 [(UO2)2(SeO4)3(H2O)] (I) from highly acidic solutions suggests that low pH does not necessarily result in the opening of azetidine ring. [AzH(CH2)3NH3][(UO2)2(SeO4)3(H2O)](H2O) (II) and [AzH(CH2)3NH3](H5O2)[(UO2)2(SO4)3(HSO4)] (III) are the first structurally characterized crystalline compounds bearing isolated ring-opened azetidine moiety.

AB - Three novel uranyl selenate and sulfate oxysalts templated by protonated azetidine molecules, [AzH]+, and its ring-opened counterpart 1-azetidinepropanamine, [AzH(CH2)3NH3]2+, have been prepared and studied by X-ray structural analysis. Conformations of azetidinium cations were analysed by means of infrared vibrational assignments supported by the DFT calculations. Crystallization of [AzH]2 [(UO2)2(SeO4)3(H2O)] (I) from highly acidic solutions suggests that low pH does not necessarily result in the opening of azetidine ring. [AzH(CH2)3NH3][(UO2)2(SeO4)3(H2O)](H2O) (II) and [AzH(CH2)3NH3](H5O2)[(UO2)2(SO4)3(HSO4)] (III) are the first structurally characterized crystalline compounds bearing isolated ring-opened azetidine moiety.

KW - Azetidine

KW - Crystal structure

KW - Ring opening

KW - Selenate

KW - Structural topology

KW - Sulfate

KW - Uranyl

UR - http://www.scopus.com/inward/record.url?scp=85029497968&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2017.09.042

DO - 10.1016/j.molstruc.2017.09.042

M3 - Article

AN - SCOPUS:85029497968

VL - 1151

SP - 88

EP - 96

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -

ID: 9151556