Ring Expansion Reactions through Intramolecular Transamidation

Standard

Ring Expansion Reactions through Intramolecular Transamidation. / Калинин, Станислав Алексеевич ; Сапегин, Александр Владимирович.

In: European Journal of Organic Chemistry, Vol. 26, No. 44, e202300754, 30.10.2023.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{3ef5e96be66142a9895d25a74a6f01fe,

title = "Ring Expansion Reactions through Intramolecular Transamidation",

abstract = "Synthetic methodologies based on cycle expansion reactions have proven to be highly effective in delivering valuable medium-sized cycles and macrocycles. A primary method of ring expansion relies on intramolecular transamidation reactions. These reactions typically employ N-aminoalkyl and N-aminoacyl derivatives of lactams and their analogues as starting materials, yielding a diverse spectrum of unique nitrogen-containing heterocycles. This Review aims to provide a comprehensive analysis of the research outcomes related to intramolecular transamidation reactions that lead to cycle expansion. This will offer the reader a perspective on the potential applications of such reactions in generating novel and intriguing types of heterocyclic systems.",

keywords = "aminoacyl inclusion, intramolecular transamidation, lactams, medium-sized cycles, ring expansion",

author = "Калинин, {Станислав Алексеевич} and Сапегин, {Александр Владимирович}",

year = "2023",

month = oct,

day = "30",

doi = "10.1002/ejoc.202300754",

language = "English",

volume = "26",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-Blackwell",

number = "44",

}

RIS

TY - JOUR

T1 - Ring Expansion Reactions through Intramolecular Transamidation

AU - Калинин, Станислав Алексеевич

AU - Сапегин, Александр Владимирович

PY - 2023/10/30

Y1 - 2023/10/30

N2 - Synthetic methodologies based on cycle expansion reactions have proven to be highly effective in delivering valuable medium-sized cycles and macrocycles. A primary method of ring expansion relies on intramolecular transamidation reactions. These reactions typically employ N-aminoalkyl and N-aminoacyl derivatives of lactams and their analogues as starting materials, yielding a diverse spectrum of unique nitrogen-containing heterocycles. This Review aims to provide a comprehensive analysis of the research outcomes related to intramolecular transamidation reactions that lead to cycle expansion. This will offer the reader a perspective on the potential applications of such reactions in generating novel and intriguing types of heterocyclic systems.

AB - Synthetic methodologies based on cycle expansion reactions have proven to be highly effective in delivering valuable medium-sized cycles and macrocycles. A primary method of ring expansion relies on intramolecular transamidation reactions. These reactions typically employ N-aminoalkyl and N-aminoacyl derivatives of lactams and their analogues as starting materials, yielding a diverse spectrum of unique nitrogen-containing heterocycles. This Review aims to provide a comprehensive analysis of the research outcomes related to intramolecular transamidation reactions that lead to cycle expansion. This will offer the reader a perspective on the potential applications of such reactions in generating novel and intriguing types of heterocyclic systems.

KW - aminoacyl inclusion

KW - intramolecular transamidation

KW - lactams

KW - medium-sized cycles

KW - ring expansion

UR - https://www.mendeley.com/catalogue/72837662-2c35-3d98-af3f-c2044e64f15e/

U2 - 10.1002/ejoc.202300754

DO - 10.1002/ejoc.202300754

M3 - Article

VL - 26

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 44

M1 - e202300754

ER -

ID: 114715925