Abstract—The paper provides complete measurement results of the effective longitudinal magnetic field B_e and the radial velocity $${{V}_{R}}$$ for 107 targets that are mainly Main-Sequence chemically peculiar stars and standard stars. The spectropolarmetric data were obtained in 2013 with the Main Stellar Spectrograph (MSS) at the 6-m BTA telescope of SAO RAS. Seven new magnetic stars were discovered during the year: HD 16545, HD 34736, HD 36997, HD 37633, HD 128220, HD 220846, and BD +37°431. During 11 observation nights, 296 circularly polarized spectra were obtained. Radial velocities were measured for all the objects, for sixty-four of them—for the first time. Observations of standard magnetic and non-magnetic stars confirm the absence of any significant systematic errors capable of distorting the B_e measurement results. The paper presents comments for measurement results for all the observed stars.