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Resonance Electron Attachment to Tetracyanoquinodimethane. / Pshenichnyuk, S.A.; Modelli, A.; Lazneva, E.F.; Komolov, A.S.

In: Journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory, Vol. 118, No. 34, 2014, p. 6810-6818.

Research output: Contribution to journal › Article

Harvard

Pshenichnyuk, SA, Modelli, A, Lazneva, EF & Komolov, AS 2014, 'Resonance Electron Attachment to Tetracyanoquinodimethane', Journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory, vol. 118, no. 34, pp. 6810-6818. https://doi.org/10.1021/jp505841c

APA

Pshenichnyuk, S. A., Modelli, A., Lazneva, E. F., & Komolov, A. S. (2014). Resonance Electron Attachment to Tetracyanoquinodimethane. Journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory, 118(34), 6810-6818. https://doi.org/10.1021/jp505841c

Vancouver

Pshenichnyuk SA, Modelli A, Lazneva EF, Komolov AS. Resonance Electron Attachment to Tetracyanoquinodimethane. Journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. 2014;118(34):6810-6818. https://doi.org/10.1021/jp505841c

Author

Pshenichnyuk, S.A. ; Modelli, A. ; Lazneva, E.F. ; Komolov, A.S. / Resonance Electron Attachment to Tetracyanoquinodimethane. In: Journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory. 2014 ; Vol. 118, No. 34. pp. 6810-6818.

BibTeX

@article{c17f3343d6984d9d8bfa74d7d1819b73,
title = "Resonance Electron Attachment to Tetracyanoquinodimethane",
abstract = "Resonance interaction of low energy (0-14 eV) electrons with gas-phase 7,7,8,8-tetracyanoquinodimethane (TCNQ) was investigated using dissociative electron attachment (DEA) spectroscopy. Spectral features associated with formation of long-lived TCNQ molecular negative ions are detected at incident electron energies of 0.3, 1.3, and 3.0 eV. A variety of negative fragments is observed around 4 eV, and slow (microseconds) dissociative decay channels are detected at about 3 eV, in competition with simple re-emission of the captured electron. The average electron detachment time from the TCNQ(-) negative ions formed at 3 eV was evaluated to be 250 mu s. The experimental findings are interpreted with the support of density functional theory (DFT) calculations of the empty orbital energies, scaled with an empirical equation, and by comparison with earlier electron transmission spectroscopy (ETS) data. A possible mechanism for the unusual formation of long-lived molecular anions above zero energy (up to 3 eV) is b",
author = "S.A. Pshenichnyuk and A. Modelli and E.F. Lazneva and A.S. Komolov",
year = "2014",
doi = "10.1021/jp505841c",
language = "English",
volume = "118",
pages = "6810--6818",
journal = "Journal of Physical Chemistry B",
issn = "1520-6106",
publisher = "American Chemical Society",
number = "34",

}

RIS

TY - JOUR

T1 - Resonance Electron Attachment to Tetracyanoquinodimethane

AU - Pshenichnyuk, S.A.

AU - Modelli, A.

AU - Lazneva, E.F.

AU - Komolov, A.S.

PY - 2014

Y1 - 2014

N2 - Resonance interaction of low energy (0-14 eV) electrons with gas-phase 7,7,8,8-tetracyanoquinodimethane (TCNQ) was investigated using dissociative electron attachment (DEA) spectroscopy. Spectral features associated with formation of long-lived TCNQ molecular negative ions are detected at incident electron energies of 0.3, 1.3, and 3.0 eV. A variety of negative fragments is observed around 4 eV, and slow (microseconds) dissociative decay channels are detected at about 3 eV, in competition with simple re-emission of the captured electron. The average electron detachment time from the TCNQ(-) negative ions formed at 3 eV was evaluated to be 250 mu s. The experimental findings are interpreted with the support of density functional theory (DFT) calculations of the empty orbital energies, scaled with an empirical equation, and by comparison with earlier electron transmission spectroscopy (ETS) data. A possible mechanism for the unusual formation of long-lived molecular anions above zero energy (up to 3 eV) is b

AB - Resonance interaction of low energy (0-14 eV) electrons with gas-phase 7,7,8,8-tetracyanoquinodimethane (TCNQ) was investigated using dissociative electron attachment (DEA) spectroscopy. Spectral features associated with formation of long-lived TCNQ molecular negative ions are detected at incident electron energies of 0.3, 1.3, and 3.0 eV. A variety of negative fragments is observed around 4 eV, and slow (microseconds) dissociative decay channels are detected at about 3 eV, in competition with simple re-emission of the captured electron. The average electron detachment time from the TCNQ(-) negative ions formed at 3 eV was evaluated to be 250 mu s. The experimental findings are interpreted with the support of density functional theory (DFT) calculations of the empty orbital energies, scaled with an empirical equation, and by comparison with earlier electron transmission spectroscopy (ETS) data. A possible mechanism for the unusual formation of long-lived molecular anions above zero energy (up to 3 eV) is b

U2 - 10.1021/jp505841c

DO - 10.1021/jp505841c

M3 - Article

VL - 118

SP - 6810

EP - 6818

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

SN - 1520-6106

IS - 34

ER -

ID: 7018985