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Reformulation of the thermodynamic theory of nucleation on charged particles. / Rusanov, A. I.; Kuni, F. M.

In: Journal of Colloid and Interface Science, Vol. 100, No. 1, 07.1984, p. 264-277.

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Harvard

Rusanov, AI & Kuni, FM 1984, 'Reformulation of the thermodynamic theory of nucleation on charged particles', Journal of Colloid and Interface Science, vol. 100, no. 1, pp. 264-277. https://doi.org/10.1016/0021-9797(84)90434-X

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Vancouver

Author

Rusanov, A. I. ; Kuni, F. M. / Reformulation of the thermodynamic theory of nucleation on charged particles. In: Journal of Colloid and Interface Science. 1984 ; Vol. 100, No. 1. pp. 264-277.

BibTeX

@article{69db94697efa494dbdec2b6a42e1a3d5,
title = "Reformulation of the thermodynamic theory of nucleation on charged particles",
abstract = "A complete set of thermodynamic fundamental equations for heterogeneous systems with curved interfaces in an external electric field has been derived recognizing the difference between the mechanical surface tension, γ, and the thermodynamic surface tension, a. Equations have been obtained for the dependence of γ, σ, the phase transition temperature, chemical potentials, and pressure on the surface curvature and an electric field. Extensions of Kelvin's and J. J. Thomson's equations have been given. Calculation of the work of nucleation on charged particles and the phase transition activation energy has been carried out. When applied to water condensation, the result obtained shows that negative condensation centers are more active than positive ones.",
author = "Rusanov, {A. I.} and Kuni, {F. M.}",
year = "1984",
month = jul,
doi = "10.1016/0021-9797(84)90434-X",
language = "English",
volume = "100",
pages = "264--277",
journal = "Journal of Colloid and Interface Science",
issn = "0021-9797",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - Reformulation of the thermodynamic theory of nucleation on charged particles

AU - Rusanov, A. I.

AU - Kuni, F. M.

PY - 1984/7

Y1 - 1984/7

N2 - A complete set of thermodynamic fundamental equations for heterogeneous systems with curved interfaces in an external electric field has been derived recognizing the difference between the mechanical surface tension, γ, and the thermodynamic surface tension, a. Equations have been obtained for the dependence of γ, σ, the phase transition temperature, chemical potentials, and pressure on the surface curvature and an electric field. Extensions of Kelvin's and J. J. Thomson's equations have been given. Calculation of the work of nucleation on charged particles and the phase transition activation energy has been carried out. When applied to water condensation, the result obtained shows that negative condensation centers are more active than positive ones.

AB - A complete set of thermodynamic fundamental equations for heterogeneous systems with curved interfaces in an external electric field has been derived recognizing the difference between the mechanical surface tension, γ, and the thermodynamic surface tension, a. Equations have been obtained for the dependence of γ, σ, the phase transition temperature, chemical potentials, and pressure on the surface curvature and an electric field. Extensions of Kelvin's and J. J. Thomson's equations have been given. Calculation of the work of nucleation on charged particles and the phase transition activation energy has been carried out. When applied to water condensation, the result obtained shows that negative condensation centers are more active than positive ones.

UR - http://www.scopus.com/inward/record.url?scp=0021460250&partnerID=8YFLogxK

U2 - 10.1016/0021-9797(84)90434-X

DO - 10.1016/0021-9797(84)90434-X

M3 - Article

AN - SCOPUS:0021460250

VL - 100

SP - 264

EP - 277

JO - Journal of Colloid and Interface Science

JF - Journal of Colloid and Interface Science

SN - 0021-9797

IS - 1

ER -

ID: 95726401