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Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates. / Nelyubin, Alexey V.; Neumolotov, Nikolay K.; Selivanov, Nikita A.; Bykov, Alexander Yu.; Klyukin, Ilya N.; Novikov, Alexander S.; Kubasov, Alexey S.; Zhdanov, Andrey P.; Zhizhin, Konstantin Yu.; Kuznetsov, Nikolay T.

In: Inorganics, Vol. 12, No. 1, 2, 2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Nelyubin, AV, Neumolotov, NK, Selivanov, NA, Bykov, AY, Klyukin, IN, Novikov, AS, Kubasov, AS, Zhdanov, AP, Zhizhin, KY & Kuznetsov, NT 2024, 'Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates', Inorganics, vol. 12, no. 1, 2. https://doi.org/10.3390/inorganics12010002

APA

Nelyubin, A. V., Neumolotov, N. K., Selivanov, N. A., Bykov, A. Y., Klyukin, I. N., Novikov, A. S., Kubasov, A. S., Zhdanov, A. P., Zhizhin, K. Y., & Kuznetsov, N. T. (2024). Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates. Inorganics, 12(1), [2]. https://doi.org/10.3390/inorganics12010002

Vancouver

Nelyubin AV, Neumolotov NK, Selivanov NA, Bykov AY, Klyukin IN, Novikov AS et al. Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates. Inorganics. 2024;12(1). 2. https://doi.org/10.3390/inorganics12010002

Author

Nelyubin, Alexey V. ; Neumolotov, Nikolay K. ; Selivanov, Nikita A. ; Bykov, Alexander Yu. ; Klyukin, Ilya N. ; Novikov, Alexander S. ; Kubasov, Alexey S. ; Zhdanov, Andrey P. ; Zhizhin, Konstantin Yu. ; Kuznetsov, Nikolay T. / Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates. In: Inorganics. 2024 ; Vol. 12, No. 1.

BibTeX

@article{3818ca124d5f4f869dd247fb618bf320,
title = "Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates",
abstract = "By reacting nitrilium derivative of the closo-dodecaborate anion, Bu4N[B12H11N≡CR] (where R = Me, Et, nPr, iPr, p-tolyl), with lithium aluminum hydride (LiAlH4), N-alkylammonium derivatives of the closo-dodecaborate anion, and Bu4N[B12H11NH2CH2R], were obtained. The reduction reaction procedure was optimized, achieving yields close to quantitative (90–95%). The structure of the compound Bu4N[B12H11NH2CH2CH3] was determined using X-ray structural analysis. It was found that substituting lithium aluminum hydride (LiAlH4) with sodium borohydride (NaBH4) leads to the same products but only upon heating, while the reaction with LiAlH4 proceeds at room temperature.",
author = "Nelyubin, {Alexey V.} and Neumolotov, {Nikolay K.} and Selivanov, {Nikita A.} and Bykov, {Alexander Yu.} and Klyukin, {Ilya N.} and Novikov, {Alexander S.} and Kubasov, {Alexey S.} and Zhdanov, {Andrey P.} and Zhizhin, {Konstantin Yu.} and Kuznetsov, {Nikolay T.}",
year = "2024",
doi = "10.3390/inorganics12010002",
language = "English",
volume = "12",
journal = "Inorganics",
issn = "2304-6740",
publisher = "MDPI AG",
number = "1",

}

RIS

TY - JOUR

T1 - Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates

AU - Nelyubin, Alexey V.

AU - Neumolotov, Nikolay K.

AU - Selivanov, Nikita A.

AU - Bykov, Alexander Yu.

AU - Klyukin, Ilya N.

AU - Novikov, Alexander S.

AU - Kubasov, Alexey S.

AU - Zhdanov, Andrey P.

AU - Zhizhin, Konstantin Yu.

AU - Kuznetsov, Nikolay T.

PY - 2024

Y1 - 2024

N2 - By reacting nitrilium derivative of the closo-dodecaborate anion, Bu4N[B12H11N≡CR] (where R = Me, Et, nPr, iPr, p-tolyl), with lithium aluminum hydride (LiAlH4), N-alkylammonium derivatives of the closo-dodecaborate anion, and Bu4N[B12H11NH2CH2R], were obtained. The reduction reaction procedure was optimized, achieving yields close to quantitative (90–95%). The structure of the compound Bu4N[B12H11NH2CH2CH3] was determined using X-ray structural analysis. It was found that substituting lithium aluminum hydride (LiAlH4) with sodium borohydride (NaBH4) leads to the same products but only upon heating, while the reaction with LiAlH4 proceeds at room temperature.

AB - By reacting nitrilium derivative of the closo-dodecaborate anion, Bu4N[B12H11N≡CR] (where R = Me, Et, nPr, iPr, p-tolyl), with lithium aluminum hydride (LiAlH4), N-alkylammonium derivatives of the closo-dodecaborate anion, and Bu4N[B12H11NH2CH2R], were obtained. The reduction reaction procedure was optimized, achieving yields close to quantitative (90–95%). The structure of the compound Bu4N[B12H11NH2CH2CH3] was determined using X-ray structural analysis. It was found that substituting lithium aluminum hydride (LiAlH4) with sodium borohydride (NaBH4) leads to the same products but only upon heating, while the reaction with LiAlH4 proceeds at room temperature.

UR - https://www.mendeley.com/catalogue/33c5c31a-bd99-3451-8c5b-84a49bcd6722/

U2 - 10.3390/inorganics12010002

DO - 10.3390/inorganics12010002

M3 - Article

VL - 12

JO - Inorganics

JF - Inorganics

SN - 2304-6740

IS - 1

M1 - 2

ER -

ID: 115119634