Research output: Contribution to journal › Article › peer-review
Redox-conducting polymers based on metal-salen complexes for energy storage applications. / Chepurnaya, Irina A.; Karushev, Mikhail P.; Lukyanov, Daniil A.; Levin, Oleg V.; Алексеева, Елена Валерьевна.
In: Pure and Applied Chemistry, Vol. 92, No. 8, 01.08.2020, p. 1239-1258.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Redox-conducting polymers based on metal-salen complexes for energy storage applications
AU - Chepurnaya, Irina A.
AU - Karushev, Mikhail P.
AU - Lukyanov, Daniil A.
AU - Levin, Oleg V.
AU - Алексеева, Елена Валерьевна
N1 - Publisher Copyright: © 2020 IUPAC & De Gruyter 2020.
PY - 2020/8/1
Y1 - 2020/8/1
N2 - Metal-salen polymers are electrochemically active metallopolymers functionalized with multiple redox centers, with a potential for high performance in various fields such as heterogeneous catalysis, chemical sensors, energy conversion, saving, and storage. In light of the growing world demand for the development of superior energy storage systems, the prospects of employing these polymers for advancing the performance of supercapacitors and lithium-ion batteries are particularly interesting. This article provides a general overview of the results of investigating key structure-property relationships of metal-salen polymers and using them to design polymer-modified electrodes with improved energy storage characteristics. The results of independent and collaborative studies conducted by the members of two research groups currently affiliated to the Saint-Petersburg State University and the Ioffe Institute, respectively, along with the related data from other studies are presented in this review.
AB - Metal-salen polymers are electrochemically active metallopolymers functionalized with multiple redox centers, with a potential for high performance in various fields such as heterogeneous catalysis, chemical sensors, energy conversion, saving, and storage. In light of the growing world demand for the development of superior energy storage systems, the prospects of employing these polymers for advancing the performance of supercapacitors and lithium-ion batteries are particularly interesting. This article provides a general overview of the results of investigating key structure-property relationships of metal-salen polymers and using them to design polymer-modified electrodes with improved energy storage characteristics. The results of independent and collaborative studies conducted by the members of two research groups currently affiliated to the Saint-Petersburg State University and the Ioffe Institute, respectively, along with the related data from other studies are presented in this review.
KW - Charge diffusion coefficient
KW - conductivity
KW - electrochemical stability
KW - lithium-ion battery
KW - Mendeleev-21
KW - metal-salen complex; metal-salen polymer
KW - polymer-modified electrode
KW - redox conducting metallopolymer
KW - Schiff base
KW - specific capacitance
KW - supercapacitor
KW - Lithium-ion battery
KW - Polymer-modified electrode
KW - Metal-salen complex; metal-salen polymer
KW - Conductivity
KW - Specific capacitance
KW - Redox conducting metallopolymer
KW - Electrochemical stability
KW - Supercapacitor
KW - ELECTROCATALYTIC REDUCTION
KW - metal-salen polymer
KW - SUPERCAPACITOR ELECTRODES
KW - SCHIFF-BASES
KW - SPECTROELECTROCHEMICAL CHARACTERIZATION
KW - HYDROGEN-PEROXIDE
KW - NICKEL-COMPLEXES
KW - CATALYTIC-REDUCTION
KW - EQUILIBRIUM VOLTAMMETRIC CURVES
KW - metal-salen complex
KW - ELECTROCHEMICAL-BEHAVIOR
KW - SPECTROSCOPIC CHARACTERIZATION
UR - http://www.scopus.com/inward/record.url?scp=85088957099&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/b3180171-c680-3525-901e-887b0c65795e/
U2 - 10.1515/pac-2019-1218
DO - 10.1515/pac-2019-1218
M3 - Article
AN - SCOPUS:85088957099
VL - 92
SP - 1239
EP - 1258
JO - Pure and Applied Chemistry
JF - Pure and Applied Chemistry
SN - 0033-4545
IS - 8
ER -
ID: 61200636