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[Re(CO)3(bipy)(ClO4)] : Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure. / Miroslavov, A. E.; Sidorenko, G. V.; Tyupina, M. Yu; Gurzhiy, V. V.

In: Russian Journal of General Chemistry, Vol. 90, No. 12, 25.12.2020, p. 2333-2337.

Research output: Contribution to journal › Article › peer-review

Harvard

Miroslavov, AE, Sidorenko, GV, Tyupina, MY & Gurzhiy, VV 2020, '[Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure', Russian Journal of General Chemistry, vol. 90, no. 12, pp. 2333-2337. https://doi.org/10.1134/S1070363220120178

APA

Miroslavov, A. E., Sidorenko, G. V., Tyupina, M. Y., & Gurzhiy, V. V. (2020). [Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure. Russian Journal of General Chemistry, 90(12), 2333-2337. https://doi.org/10.1134/S1070363220120178

Vancouver

Miroslavov AE, Sidorenko GV, Tyupina MY, Gurzhiy VV. [Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure. Russian Journal of General Chemistry. 2020 Dec 25;90(12):2333-2337. https://doi.org/10.1134/S1070363220120178

Author

Miroslavov, A. E. ; Sidorenko, G. V. ; Tyupina, M. Yu ; Gurzhiy, V. V. / [Re(CO)3(bipy)(ClO4)] : Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure. In: Russian Journal of General Chemistry. 2020 ; Vol. 90, No. 12. pp. 2333-2337.

BibTeX

@article{d194819950a6447d8bc1f49af37e70a0,
title = "[Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure",
abstract = "Abstract: The complex [Re(CO)3(bipy)(ClO4)] (bipy = 2,2ʹ-bipyridine) was prepared by the reaction of [Re(CO)3(H2O,EtOH)3](ClO4) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffraction analysis. The complex has a molecular octahedral structure with bidentate coordination of bipy and inner-sphere monodentate coordination of perchlorate ion in the fac-position to bipy. The complex was also characterized by IR and UV-visible absorption spectroscopy.",
keywords = "bipyridine complexes, perchlorate complexes, rhenium tricarbonyl complexes, single crystal X-ray diffraction analysis",
author = "Miroslavov, {A. E.} and Sidorenko, {G. V.} and Tyupina, {M. Yu} and Gurzhiy, {V. V.}",
note = "Funding Information: The study was performed with financial support of Russian Foundation for Basic Research (project no. 19-33-90040\19). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2020",
month = dec,
day = "25",
doi = "10.1134/S1070363220120178",
language = "English",
volume = "90",
pages = "2333--2337",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "12",

}

RIS

TY - JOUR

T1 - [Re(CO)3(bipy)(ClO4)]

T2 - Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure

AU - Miroslavov, A. E.

AU - Sidorenko, G. V.

AU - Tyupina, M. Yu

AU - Gurzhiy, V. V.

N1 - Funding Information: The study was performed with financial support of Russian Foundation for Basic Research (project no. 19-33-90040\19). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2020/12/25

Y1 - 2020/12/25

N2 - Abstract: The complex [Re(CO)3(bipy)(ClO4)] (bipy = 2,2ʹ-bipyridine) was prepared by the reaction of [Re(CO)3(H2O,EtOH)3](ClO4) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffraction analysis. The complex has a molecular octahedral structure with bidentate coordination of bipy and inner-sphere monodentate coordination of perchlorate ion in the fac-position to bipy. The complex was also characterized by IR and UV-visible absorption spectroscopy.

AB - Abstract: The complex [Re(CO)3(bipy)(ClO4)] (bipy = 2,2ʹ-bipyridine) was prepared by the reaction of [Re(CO)3(H2O,EtOH)3](ClO4) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffraction analysis. The complex has a molecular octahedral structure with bidentate coordination of bipy and inner-sphere monodentate coordination of perchlorate ion in the fac-position to bipy. The complex was also characterized by IR and UV-visible absorption spectroscopy.

KW - bipyridine complexes

KW - perchlorate complexes

KW - rhenium tricarbonyl complexes

KW - single crystal X-ray diffraction analysis

UR - http://www.scopus.com/inward/record.url?scp=85100596981&partnerID=8YFLogxK

U2 - 10.1134/S1070363220120178

DO - 10.1134/S1070363220120178

M3 - Article

AN - SCOPUS:85100596981

VL - 90

SP - 2333

EP - 2337

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 12

ER -

ID: 74670471