Standard

Rearrangement of the Binuclear K4Mo2Cl8 Cluster Structure in the Process of Its Oxidation in HCl Solution. / Krapivin, M. A.; Ivanov, N. S.; Kondratiev, Yu. V.; Pestova, O. N.; Khripun, V. D.

In: Russian Journal of General Chemistry, Vol. 89, No. 4, 2019, p. 856-858.

Research output: Contribution to journal › Letter › peer-review

Harvard

Krapivin, MA, Ivanov, NS, Kondratiev, YV, Pestova, ON & Khripun, VD 2019, 'Rearrangement of the Binuclear K4Mo2Cl8 Cluster Structure in the Process of Its Oxidation in HCl Solution', Russian Journal of General Chemistry, vol. 89, no. 4, pp. 856-858. https://doi.org/10.1134/S1070363219040364

APA

Krapivin, M. A., Ivanov, N. S., Kondratiev, Y. V., Pestova, O. N., & Khripun, V. D. (2019). Rearrangement of the Binuclear K4Mo2Cl8 Cluster Structure in the Process of Its Oxidation in HCl Solution. Russian Journal of General Chemistry, 89(4), 856-858. https://doi.org/10.1134/S1070363219040364

Vancouver

Krapivin MA, Ivanov NS, Kondratiev YV, Pestova ON, Khripun VD. Rearrangement of the Binuclear K4Mo2Cl8 Cluster Structure in the Process of Its Oxidation in HCl Solution. Russian Journal of General Chemistry. 2019;89(4):856-858. https://doi.org/10.1134/S1070363219040364

Author

Krapivin, M. A. ; Ivanov, N. S. ; Kondratiev, Yu. V. ; Pestova, O. N. ; Khripun, V. D. / Rearrangement of the Binuclear K4Mo2Cl8 Cluster Structure in the Process of Its Oxidation in HCl Solution. In: Russian Journal of General Chemistry. 2019 ; Vol. 89, No. 4. pp. 856-858.

BibTeX

@article{b6af735ceb0a4a978b3f30743f2a9cc7,
title = "Rearrangement of the Binuclear K4Mo2Cl8 Cluster Structure in the Process of Its Oxidation in HCl Solution",
abstract = "Batch-type spectroscopic and continuous potentiometric titration of K4Mo2Cl8 with potassium dichromate in 1 M hydrochloric acid was carried out. Intermediate forms of molybdenum compounds in the oxidation process were determined. It was shown that the oxidation is accompanied by a rearrangement of the complex structure with the formation of trinuclear oxo- and hydroxohalide anions of molybdenum into trinuclear oxo- and hydroxohalide molybdenum anions. The standard reduction potential of the pair E298o(MoVI/Mo3IV=1.003+0.032V was determined.",
keywords = "cluster, electron spectroscopy, molybdenum, potentiometry",
author = "Krapivin, {M. A.} and Ivanov, {N. S.} and Kondratiev, {Yu. V.} and Pestova, {O. N.} and Khripun, {V. D.}",
note = "Krapivin, M.A., Ivanov, N.S., Kondratiev, Y.V. et al. Russ J Gen Chem (2019) 89: 856. https://doi.org/10.1134/S1070363219040364",
year = "2019",
doi = "10.1134/S1070363219040364",
language = "English",
volume = "89",
pages = "856--858",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Rearrangement of the Binuclear K4Mo2Cl8 Cluster Structure in the Process of Its Oxidation in HCl Solution

AU - Krapivin, M. A.

AU - Ivanov, N. S.

AU - Kondratiev, Yu. V.

AU - Pestova, O. N.

AU - Khripun, V. D.

N1 - Krapivin, M.A., Ivanov, N.S., Kondratiev, Y.V. et al. Russ J Gen Chem (2019) 89: 856. https://doi.org/10.1134/S1070363219040364

PY - 2019

Y1 - 2019

N2 - Batch-type spectroscopic and continuous potentiometric titration of K4Mo2Cl8 with potassium dichromate in 1 M hydrochloric acid was carried out. Intermediate forms of molybdenum compounds in the oxidation process were determined. It was shown that the oxidation is accompanied by a rearrangement of the complex structure with the formation of trinuclear oxo- and hydroxohalide anions of molybdenum into trinuclear oxo- and hydroxohalide molybdenum anions. The standard reduction potential of the pair E298o(MoVI/Mo3IV=1.003+0.032V was determined.

AB - Batch-type spectroscopic and continuous potentiometric titration of K4Mo2Cl8 with potassium dichromate in 1 M hydrochloric acid was carried out. Intermediate forms of molybdenum compounds in the oxidation process were determined. It was shown that the oxidation is accompanied by a rearrangement of the complex structure with the formation of trinuclear oxo- and hydroxohalide anions of molybdenum into trinuclear oxo- and hydroxohalide molybdenum anions. The standard reduction potential of the pair E298o(MoVI/Mo3IV=1.003+0.032V was determined.

KW - cluster

KW - electron spectroscopy

KW - molybdenum

KW - potentiometry

UR - http://www.scopus.com/inward/record.url?scp=85067645431&partnerID=8YFLogxK

U2 - 10.1134/S1070363219040364

DO - 10.1134/S1070363219040364

M3 - Letter

AN - SCOPUS:85067645431

VL - 89

SP - 856

EP - 858

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -

ID: 47948574