Reactivity of the pentelidene complexes [Cp*E{W(CO)5}2] (E = P, As) towards dichalcogenides and chalcogenols - synthesis of novel chalcogenopentelidene complexes

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Reactivity of the pentelidene complexes [Cp*E{W(CO)₅}₂] (E = P, As) towards dichalcogenides and chalcogenols - synthesis of novel chalcogenopentelidene complexes. / Rummel, Lena; Lassandro, Giuliano; Seidl, Michael; Timoshkin, Alexey Y.; Scheer, Manfred.

In: Dalton Transactions, Vol. 50, No. 36, 28.09.2021, p. 12648-12654.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{93b5dd730bb842488c0f58e851f6cef5,

title = "Reactivity of the pentelidene complexes [Cp*E{W(CO)5}2] (E = P, As) towards dichalcogenides and chalcogenols - synthesis of novel chalcogenopentelidene complexes",

abstract = "Pentelidene complexes of the type [Cp*E{W(CO)5}2] (Cp* = C5Me5;1a: E = P,1b: E = As) were reacted with the dichalcogenides R2Ch2(R = Ph, Mes, Tipp; Ch = S, Se, Te; Mes = 2,4,6-trimethylphenyl; Tipp = 2,4,6-triisopropylphenyl) and the chalcogenols PhChH (Ch = S, Se). It has been shown that the formation of new E-Ch bonds proceeds under elimination of the Cp* substituent. The resulting chalcogenopentelidene complexes, which have been isolated and fully characterised, represent a novel class of phosphinidene complexes which can be synthesised through this general synthetic route.",

keywords = "BOND COVALENT RADII, ARSINIDENE COMPLEXES, PHOSPHINIDENE, SUBSTITUTION, EXPANSION, SULFUR, SINGLE, RING",

author = "Lena Rummel and Giuliano Lassandro and Michael Seidl and Timoshkin, {Alexey Y.} and Manfred Scheer",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = sep,

day = "28",

doi = "10.1039/d1dt01866c",

language = "English",

volume = "50",

pages = "12648--12654",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "36",

}

RIS

TY - JOUR

T1 - Reactivity of the pentelidene complexes [Cp*E{W(CO)5}2] (E = P, As) towards dichalcogenides and chalcogenols - synthesis of novel chalcogenopentelidene complexes

AU - Rummel, Lena

AU - Lassandro, Giuliano

AU - Seidl, Michael

AU - Timoshkin, Alexey Y.

AU - Scheer, Manfred

N1 - Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/9/28

Y1 - 2021/9/28

N2 - Pentelidene complexes of the type [Cp*E{W(CO)5}2] (Cp* = C5Me5;1a: E = P,1b: E = As) were reacted with the dichalcogenides R2Ch2(R = Ph, Mes, Tipp; Ch = S, Se, Te; Mes = 2,4,6-trimethylphenyl; Tipp = 2,4,6-triisopropylphenyl) and the chalcogenols PhChH (Ch = S, Se). It has been shown that the formation of new E-Ch bonds proceeds under elimination of the Cp* substituent. The resulting chalcogenopentelidene complexes, which have been isolated and fully characterised, represent a novel class of phosphinidene complexes which can be synthesised through this general synthetic route.

AB - Pentelidene complexes of the type [Cp*E{W(CO)5}2] (Cp* = C5Me5;1a: E = P,1b: E = As) were reacted with the dichalcogenides R2Ch2(R = Ph, Mes, Tipp; Ch = S, Se, Te; Mes = 2,4,6-trimethylphenyl; Tipp = 2,4,6-triisopropylphenyl) and the chalcogenols PhChH (Ch = S, Se). It has been shown that the formation of new E-Ch bonds proceeds under elimination of the Cp* substituent. The resulting chalcogenopentelidene complexes, which have been isolated and fully characterised, represent a novel class of phosphinidene complexes which can be synthesised through this general synthetic route.

KW - BOND COVALENT RADII

KW - ARSINIDENE COMPLEXES

KW - PHOSPHINIDENE

KW - SUBSTITUTION

KW - EXPANSION

KW - SULFUR

KW - SINGLE

KW - RING

UR - http://www.scopus.com/inward/record.url?scp=85115617914&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/12d984c5-eba3-30cb-b4b8-cb04e83a7f89/

U2 - 10.1039/d1dt01866c

DO - 10.1039/d1dt01866c

M3 - Article

AN - SCOPUS:85115617914

VL - 50

SP - 12648

EP - 12654

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 36

ER -

ID: 86407424