Standard

Reactive polymers : 61. Reaction of macroporous poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol. / Horák, D.; Straka, J.; Štokr, J.; Schneider, B.; Tennikova, T. B.; Švec, F.

In: Polymer, Vol. 32, No. 6, 1991, p. 1135-1139.

Research output: Contribution to journal › Article › peer-review

Harvard

Horák, D, Straka, J, Štokr, J, Schneider, B, Tennikova, TB & Švec, F 1991, 'Reactive polymers: 61. Reaction of macroporous poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol', Polymer, vol. 32, no. 6, pp. 1135-1139. https://doi.org/10.1016/0032-3861(91)90604-H

APA

Horák, D., Straka, J., Štokr, J., Schneider, B., Tennikova, T. B., & Švec, F. (1991). Reactive polymers: 61. Reaction of macroporous poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol. Polymer, 32(6), 1135-1139. https://doi.org/10.1016/0032-3861(91)90604-H

Vancouver

Horák D, Straka J, Štokr J, Schneider B, Tennikova TB, Švec F. Reactive polymers: 61. Reaction of macroporous poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol. Polymer. 1991;32(6):1135-1139. https://doi.org/10.1016/0032-3861(91)90604-H

Author

Horák, D. ; Straka, J. ; Štokr, J. ; Schneider, B. ; Tennikova, T. B. ; Švec, F. / Reactive polymers : 61. Reaction of macroporous poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol. In: Polymer. 1991 ; Vol. 32, No. 6. pp. 1135-1139.

BibTeX

@article{1f6aca6da95a40f48ee31edbc098fad3,
title = "Reactive polymers: 61. Reaction of macroporous poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol",
abstract = "A series of sorbents differing substantially in the content of phenyl groups were prepared by a base-catalysed reaction of poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol. Methods are described for quantitative determination of the degree of substitution of epoxide groups by phenol, based on 13C nuclear magnetic resonance and infra-red spectroscopy and on elemental analysis (C, H); the last method was found to be inappropriate, however, owing to the large error involved. Infra-red spectroscopy is the method of choice for determining the degree of substitution. By studying the local properties of the regression surface, a polynomial equation was derived for the dependence of the degree of substitution of epoxide groups by phenol on the mole ratios phenol/epoxide and sodium hydroxide/phenol. The time dependence of the extent of reaction was also studied. The maximum degree of substitution attained was 0.65.",
keywords = "C nuclear magnetic resonance spectroscopy, ethylene dimethacrylate, glycidyl methacrylate, infra-red spectroscopy",
author = "D. Hor{\'a}k and J. Straka and J. {\v S}tokr and B. Schneider and Tennikova, {T. B.} and F. {\v S}vec",
year = "1991",
doi = "10.1016/0032-3861(91)90604-H",
language = "English",
volume = "32",
pages = "1135--1139",
journal = "Polymer",
issn = "0032-3861",
publisher = "Elsevier",
number = "6",

}

RIS

TY - JOUR

T1 - Reactive polymers

T2 - 61. Reaction of macroporous poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol

AU - Horák, D.

AU - Straka, J.

AU - Štokr, J.

AU - Schneider, B.

AU - Tennikova, T. B.

AU - Švec, F.

PY - 1991

Y1 - 1991

N2 - A series of sorbents differing substantially in the content of phenyl groups were prepared by a base-catalysed reaction of poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol. Methods are described for quantitative determination of the degree of substitution of epoxide groups by phenol, based on 13C nuclear magnetic resonance and infra-red spectroscopy and on elemental analysis (C, H); the last method was found to be inappropriate, however, owing to the large error involved. Infra-red spectroscopy is the method of choice for determining the degree of substitution. By studying the local properties of the regression surface, a polynomial equation was derived for the dependence of the degree of substitution of epoxide groups by phenol on the mole ratios phenol/epoxide and sodium hydroxide/phenol. The time dependence of the extent of reaction was also studied. The maximum degree of substitution attained was 0.65.

AB - A series of sorbents differing substantially in the content of phenyl groups were prepared by a base-catalysed reaction of poly(glycidyl methacrylate-co-ethylene dimethacrylate) with phenol. Methods are described for quantitative determination of the degree of substitution of epoxide groups by phenol, based on 13C nuclear magnetic resonance and infra-red spectroscopy and on elemental analysis (C, H); the last method was found to be inappropriate, however, owing to the large error involved. Infra-red spectroscopy is the method of choice for determining the degree of substitution. By studying the local properties of the regression surface, a polynomial equation was derived for the dependence of the degree of substitution of epoxide groups by phenol on the mole ratios phenol/epoxide and sodium hydroxide/phenol. The time dependence of the extent of reaction was also studied. The maximum degree of substitution attained was 0.65.

KW - C nuclear magnetic resonance spectroscopy

KW - ethylene dimethacrylate

KW - glycidyl methacrylate

KW - infra-red spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=0025843889&partnerID=8YFLogxK

U2 - 10.1016/0032-3861(91)90604-H

DO - 10.1016/0032-3861(91)90604-H

M3 - Article

AN - SCOPUS:0025843889

VL - 32

SP - 1135

EP - 1139

JO - Polymer

JF - Polymer

SN - 0032-3861

IS - 6

ER -

ID: 87866917