Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes

Standard

Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes. / Eliseeva, A. A.; Prudnikova, E. G.; Panikorovskii, T. L.; Skvortsov, N. K.

In: Russian Journal of General Chemistry, Vol. 87, No. 8, 01.08.2017, p. 1884-1886.

Research output: Contribution to journal › Letter › peer-review

Author

Eliseeva, A. A. ; Prudnikova, E. G. ; Panikorovskii, T. L. ; Skvortsov, N. K. / Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes. In: Russian Journal of General Chemistry. 2017 ; Vol. 87, No. 8. pp. 1884-1886.

BibTeX

@article{008229a6e1e8454b86b17609fd373278,

title = "Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes",

abstract = "Dehydrocondensation reactions of silicon hydrides catalyzed by the rhodium(III) complex [RhCl3(Me2SO)3] in the absence of the second substrate were studied. It was found that the complex [RhCl3(Me2SO)3] catalyzed the dehydrocondensation reaction with the formation of compounds containing siloxane bonds. Analysis of NMR spectra has shown that the reaction of [RhCl3(Me2SO)3] with silicon hydride includes sequential desoxygenation of sulfoxide ligands to sulfide ligands with the complex [RhCl3(Me2S)3] formation.",

keywords = "dehydrocondensation, desoxygenation of ligands, rhodium(III) complex, silicon hydride",

author = "Eliseeva, {A. A.} and Prudnikova, {E. G.} and Panikorovskii, {T. L.} and Skvortsov, {N. K.}",

year = "2017",

month = aug,

day = "1",

doi = "10.1134/S1070363217080400",

language = "English",

volume = "87",

pages = "1884--1886",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "8",

}

RIS

TY - JOUR

T1 - Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes

AU - Eliseeva, A. A.

AU - Prudnikova, E. G.

AU - Panikorovskii, T. L.

AU - Skvortsov, N. K.

PY - 2017/8/1

Y1 - 2017/8/1

N2 - Dehydrocondensation reactions of silicon hydrides catalyzed by the rhodium(III) complex [RhCl3(Me2SO)3] in the absence of the second substrate were studied. It was found that the complex [RhCl3(Me2SO)3] catalyzed the dehydrocondensation reaction with the formation of compounds containing siloxane bonds. Analysis of NMR spectra has shown that the reaction of [RhCl3(Me2SO)3] with silicon hydride includes sequential desoxygenation of sulfoxide ligands to sulfide ligands with the complex [RhCl3(Me2S)3] formation.

AB - Dehydrocondensation reactions of silicon hydrides catalyzed by the rhodium(III) complex [RhCl3(Me2SO)3] in the absence of the second substrate were studied. It was found that the complex [RhCl3(Me2SO)3] catalyzed the dehydrocondensation reaction with the formation of compounds containing siloxane bonds. Analysis of NMR spectra has shown that the reaction of [RhCl3(Me2SO)3] with silicon hydride includes sequential desoxygenation of sulfoxide ligands to sulfide ligands with the complex [RhCl3(Me2S)3] formation.

KW - dehydrocondensation

KW - desoxygenation of ligands

KW - rhodium(III) complex

KW - silicon hydride

UR - http://www.scopus.com/inward/record.url?scp=85029578352&partnerID=8YFLogxK

U2 - 10.1134/S1070363217080400

DO - 10.1134/S1070363217080400

M3 - Letter

AN - SCOPUS:85029578352

VL - 87

SP - 1884

EP - 1886

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 8

ER -

ID: 54306881