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Reactions of diphenylpyridylphosphine with H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and isolation of the oxidative addition products. / Ponomarenko, Vadim I.; Pilyugina, Tatiana S.; Khripun, Vassily D.; Grachova, Elena V.; Tunik, Sergey P.; Haukka, Matti; Pakkanen, Tapani A.

In: Journal of Organometallic Chemistry, Vol. 691, No. 1-2, 01.01.2006, p. 111-121.

Research output: Contribution to journal › Article › peer-review

Harvard

Ponomarenko, VI, Pilyugina, TS, Khripun, VD, Grachova, EV, Tunik, SP, Haukka, M & Pakkanen, TA 2006, 'Reactions of diphenylpyridylphosphine with H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and isolation of the oxidative addition products', Journal of Organometallic Chemistry, vol. 691, no. 1-2, pp. 111-121. https://doi.org/10.1016/j.jorganchem.2005.08.007

APA

Ponomarenko, V. I., Pilyugina, T. S., Khripun, V. D., Grachova, E. V., Tunik, S. P., Haukka, M., & Pakkanen, T. A. (2006). Reactions of diphenylpyridylphosphine with H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and isolation of the oxidative addition products. Journal of Organometallic Chemistry, 691(1-2), 111-121. https://doi.org/10.1016/j.jorganchem.2005.08.007

Vancouver

Ponomarenko VI, Pilyugina TS, Khripun VD, Grachova EV, Tunik SP, Haukka M et al. Reactions of diphenylpyridylphosphine with H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and isolation of the oxidative addition products. Journal of Organometallic Chemistry. 2006 Jan 1;691(1-2):111-121. https://doi.org/10.1016/j.jorganchem.2005.08.007

Author

Ponomarenko, Vadim I. ; Pilyugina, Tatiana S. ; Khripun, Vassily D. ; Grachova, Elena V. ; Tunik, Sergey P. ; Haukka, Matti ; Pakkanen, Tapani A. / Reactions of diphenylpyridylphosphine with H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and isolation of the oxidative addition products. In: Journal of Organometallic Chemistry. 2006 ; Vol. 691, No. 1-2. pp. 111-121.

BibTeX

@article{ae24b5198c3f4b30903fd2b14d1bee0f,
title = "Reactions of diphenylpyridylphosphine with H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and isolation of the oxidative addition products",
abstract = "The reactions of diphenylpyridylphosphine ligand with H2Os 3(CO)10 and H4Ru4(CO)12 were studied. It was found that the thermodynamic products of these reactions, (μ-H)Os3(CO)9(μ3,κ2- PhP(2-C5H4N)) (2) and H3Ru4(CO) 10(μ3,κ2-PhP(2-C5H 4N)) (4), are formed through the oxidative addition of a P-Ph bond in the coordinated ligand and subsequent reductive elimination of benzene. In the case of triosmium cluster an unusually stable intermediate compound, (μ-H)2Os3(CO)8(μ3, κ2-PhP(2-C5H4N))(Ph) (1), containing cis hydride and σ-bonded phenyl was isolated and fully characterized. This cluster eliminates benzene to give (2) only under heating above 50 °C. Reaction of H4Ru4(CO)12 with diphenylpyridylphosphine gives first the H4Ru4(CO) 10(μ,κ2-Ph2P(2-C5H 4N)) cluster (3) with a bridging (P,N) coordination of the starting ligand, which easily converts into the phosphide cluster (4) at room temperature. The structures of the clusters (1)-(4) were established using 1H and 31P NMR spectroscopy and X-ray crystallography. Variable temperature 1H NMR study of (3) and (4) showed that the hydride environment in (3) is stereochemically nonrigid and complete exchange of all hydrides was observed at room temperature. The cluster (4) exists in solution as an equilibrium mixture of two isomers with different disposition of hydrides relative to the bridging pyridylphosphide moiety.",
keywords = "Cluster compounds, Osmium, P Ligands, Ruthenium, X-ray diffraction",
author = "Ponomarenko, {Vadim I.} and Pilyugina, {Tatiana S.} and Khripun, {Vassily D.} and Grachova, {Elena V.} and Tunik, {Sergey P.} and Matti Haukka and Pakkanen, {Tapani A.}",
year = "2006",
month = jan,
day = "1",
doi = "10.1016/j.jorganchem.2005.08.007",
language = "English",
volume = "691",
pages = "111--121",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - Reactions of diphenylpyridylphosphine with H2Os 3(CO)10 and H4Ru4(CO)12, P-C bond splitting in the coordinated ligand and isolation of the oxidative addition products

AU - Ponomarenko, Vadim I.

AU - Pilyugina, Tatiana S.

AU - Khripun, Vassily D.

AU - Grachova, Elena V.

AU - Tunik, Sergey P.

AU - Haukka, Matti

AU - Pakkanen, Tapani A.

PY - 2006/1/1

Y1 - 2006/1/1

N2 - The reactions of diphenylpyridylphosphine ligand with H2Os 3(CO)10 and H4Ru4(CO)12 were studied. It was found that the thermodynamic products of these reactions, (μ-H)Os3(CO)9(μ3,κ2- PhP(2-C5H4N)) (2) and H3Ru4(CO) 10(μ3,κ2-PhP(2-C5H 4N)) (4), are formed through the oxidative addition of a P-Ph bond in the coordinated ligand and subsequent reductive elimination of benzene. In the case of triosmium cluster an unusually stable intermediate compound, (μ-H)2Os3(CO)8(μ3, κ2-PhP(2-C5H4N))(Ph) (1), containing cis hydride and σ-bonded phenyl was isolated and fully characterized. This cluster eliminates benzene to give (2) only under heating above 50 °C. Reaction of H4Ru4(CO)12 with diphenylpyridylphosphine gives first the H4Ru4(CO) 10(μ,κ2-Ph2P(2-C5H 4N)) cluster (3) with a bridging (P,N) coordination of the starting ligand, which easily converts into the phosphide cluster (4) at room temperature. The structures of the clusters (1)-(4) were established using 1H and 31P NMR spectroscopy and X-ray crystallography. Variable temperature 1H NMR study of (3) and (4) showed that the hydride environment in (3) is stereochemically nonrigid and complete exchange of all hydrides was observed at room temperature. The cluster (4) exists in solution as an equilibrium mixture of two isomers with different disposition of hydrides relative to the bridging pyridylphosphide moiety.

AB - The reactions of diphenylpyridylphosphine ligand with H2Os 3(CO)10 and H4Ru4(CO)12 were studied. It was found that the thermodynamic products of these reactions, (μ-H)Os3(CO)9(μ3,κ2- PhP(2-C5H4N)) (2) and H3Ru4(CO) 10(μ3,κ2-PhP(2-C5H 4N)) (4), are formed through the oxidative addition of a P-Ph bond in the coordinated ligand and subsequent reductive elimination of benzene. In the case of triosmium cluster an unusually stable intermediate compound, (μ-H)2Os3(CO)8(μ3, κ2-PhP(2-C5H4N))(Ph) (1), containing cis hydride and σ-bonded phenyl was isolated and fully characterized. This cluster eliminates benzene to give (2) only under heating above 50 °C. Reaction of H4Ru4(CO)12 with diphenylpyridylphosphine gives first the H4Ru4(CO) 10(μ,κ2-Ph2P(2-C5H 4N)) cluster (3) with a bridging (P,N) coordination of the starting ligand, which easily converts into the phosphide cluster (4) at room temperature. The structures of the clusters (1)-(4) were established using 1H and 31P NMR spectroscopy and X-ray crystallography. Variable temperature 1H NMR study of (3) and (4) showed that the hydride environment in (3) is stereochemically nonrigid and complete exchange of all hydrides was observed at room temperature. The cluster (4) exists in solution as an equilibrium mixture of two isomers with different disposition of hydrides relative to the bridging pyridylphosphide moiety.

KW - Cluster compounds

KW - Osmium

KW - P Ligands

KW - Ruthenium

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=28844449358&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2005.08.007

DO - 10.1016/j.jorganchem.2005.08.007

M3 - Article

AN - SCOPUS:28844449358

VL - 691

SP - 111

EP - 121

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1-2

ER -

ID: 36017140