Research output: Contribution to journal › Article › peer-review
Reaction of fluoro(phenyl)carbene with Schiff bases : Synthesis of 2-fluoro-2-phenylaziridines. / Kusei, E. Yu; Novikov, M. S.; Khlebnikov, A. F.
In: Russian Journal of General Chemistry, Vol. 75, No. 10, 01.10.2005, p. 1643-1647.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Reaction of fluoro(phenyl)carbene with Schiff bases
T2 - Synthesis of 2-fluoro-2-phenylaziridines
AU - Kusei, E. Yu
AU - Novikov, M. S.
AU - Khlebnikov, A. F.
PY - 2005/10/1
Y1 - 2005/10/1
N2 - Fluoro(phenyl)carbene generated by reaction of α-bromo-α- fluorotoluene with potassium tert-butoxide reacts with Schiff bases to afford the corresponding 2-fluoro-2-phenylaziridines. The latter were isolated in low yields due to their instability under the carbene generation conditions. Although the reaction of α,α-dibromo-α-fluorotoluene with zinc and lead involves formation of fluoro(phenyl)carbene, this procedure is not suitable for the synthesis of 2-fluoro-2-phenylaziridines.
AB - Fluoro(phenyl)carbene generated by reaction of α-bromo-α- fluorotoluene with potassium tert-butoxide reacts with Schiff bases to afford the corresponding 2-fluoro-2-phenylaziridines. The latter were isolated in low yields due to their instability under the carbene generation conditions. Although the reaction of α,α-dibromo-α-fluorotoluene with zinc and lead involves formation of fluoro(phenyl)carbene, this procedure is not suitable for the synthesis of 2-fluoro-2-phenylaziridines.
UR - http://www.scopus.com/inward/record.url?scp=33747822845&partnerID=8YFLogxK
U2 - 10.1007/s11176-005-0480-y
DO - 10.1007/s11176-005-0480-y
M3 - Article
AN - SCOPUS:33747822845
VL - 75
SP - 1643
EP - 1647
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 10
ER -
ID: 28249939