Research output: Contribution to journal › Article › peer-review
Reaction of chiral pyrrolylphosphine with polynuclear carbonyl complexes of osmium and rhodium. / Ponomarenko, V. I.; Gracheva, E. V.; Koshevoi, I. O.; Gindin, V. A.; Tunik, S. P.; Pursiainen, I.; Haukka, M.
In: Russian Journal of General Chemistry, Vol. 80, No. 3, 01.03.2010, p. 408-413.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Reaction of chiral pyrrolylphosphine with polynuclear carbonyl complexes of osmium and rhodium
AU - Ponomarenko, V. I.
AU - Gracheva, E. V.
AU - Koshevoi, I. O.
AU - Gindin, V. A.
AU - Tunik, S. P.
AU - Pursiainen, I.
AU - Haukka, M.
PY - 2010/3/1
Y1 - 2010/3/1
N2 - Reactions of labile Os3(CO)10(NCMe)2 and Rh6(CO)15(NCMe) clusters and dinuclear Rh 2(CO)4Cl2 complex with chiral (S)-[2-(4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]di(1H-pyrrol-1-yl) phosphine were studied. The reaction of Os3(CO)10(NCMe) 2 with the chiral phosphine was diastereoselective, and it afforded only one diastereoisomer with ee 100%. All isolated compounds were completely characterized by NMR and mass spectra and X-ray diffraction data.
AB - Reactions of labile Os3(CO)10(NCMe)2 and Rh6(CO)15(NCMe) clusters and dinuclear Rh 2(CO)4Cl2 complex with chiral (S)-[2-(4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]di(1H-pyrrol-1-yl) phosphine were studied. The reaction of Os3(CO)10(NCMe) 2 with the chiral phosphine was diastereoselective, and it afforded only one diastereoisomer with ee 100%. All isolated compounds were completely characterized by NMR and mass spectra and X-ray diffraction data.
UR - http://www.scopus.com/inward/record.url?scp=77952530205&partnerID=8YFLogxK
U2 - 10.1134/S1070363210030060
DO - 10.1134/S1070363210030060
M3 - Article
AN - SCOPUS:77952530205
VL - 80
SP - 408
EP - 413
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 3
ER -
ID: 36015992