Research output: Contribution to journal › Article › peer-review
Ratiometric thermometry using single Er3+-doped CaWO4 phosphors. / Kolesnikov, Ilya E; Mamonova, Daria V; Kurochkin, Mikhail A; Medvedev, Vassily A; Bai, Gongxun; Kolesnikov, Evgenii Yu.
In: Nanotechnology, Vol. 34, No. 5, 15.11.2022, p. 055501.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Ratiometric thermometry using single Er3+-doped CaWO4 phosphors
AU - Kolesnikov, Ilya E
AU - Mamonova, Daria V
AU - Kurochkin, Mikhail A
AU - Medvedev, Vassily A
AU - Bai, Gongxun
AU - Kolesnikov, Evgenii Yu
PY - 2022/11/15
Y1 - 2022/11/15
N2 - Single doped CaWO4:Er3+ phosphors were synthesized and studied for application of optical thermal sensing within a wide range of 98–773 K. Ratiometric strategy utilizing two luminescence intensity ratios, one between host and Er3+ band (LIR1) and second between different Er3+ transitions (LIR2), results in self-referencing temperature readouts. The presence of two temperature-dependent parameters could improve thermometric characteristics and broaden the working temperature range compared to a usual single-parameter thermometer. Thermometric performances of prepared samples were evaluated in terms of thermal sensitivities, temperature resolution and repeatability. The highest sensitivity of 2.09% K−1@300 K was found for LIR1, whereas LIR2 provided more accurate thermal sensing with a temperature resolution of 0.06–0.1 K. Effect of Er3+ doping concentration on sensing properties were studied. The presented findings indicate that CaWO4:Er3+ phosphors are perspective in dual-mode thermal sensing with high sensitivity and sub-degree resolution.
AB - Single doped CaWO4:Er3+ phosphors were synthesized and studied for application of optical thermal sensing within a wide range of 98–773 K. Ratiometric strategy utilizing two luminescence intensity ratios, one between host and Er3+ band (LIR1) and second between different Er3+ transitions (LIR2), results in self-referencing temperature readouts. The presence of two temperature-dependent parameters could improve thermometric characteristics and broaden the working temperature range compared to a usual single-parameter thermometer. Thermometric performances of prepared samples were evaluated in terms of thermal sensitivities, temperature resolution and repeatability. The highest sensitivity of 2.09% K−1@300 K was found for LIR1, whereas LIR2 provided more accurate thermal sensing with a temperature resolution of 0.06–0.1 K. Effect of Er3+ doping concentration on sensing properties were studied. The presented findings indicate that CaWO4:Er3+ phosphors are perspective in dual-mode thermal sensing with high sensitivity and sub-degree resolution.
U2 - 10.1088/1361-6528/ac9a55
DO - 10.1088/1361-6528/ac9a55
M3 - Article
VL - 34
SP - 055501
JO - Nanotechnology
JF - Nanotechnology
SN - 0957-4484
IS - 5
ER -
ID: 102529992