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@article{73f5b21264bf4391ace6d40784d50d35,
title = "Prussian blue analogues based on 3d-metals as cathode materials for magnesium ion batteries",
abstract = "Prussian blue PB analogues (K;Mg)xM[Fe(CN)6] were obtained via the co-precipitation method. Manganese, iron, cobalt, nickel, copper and zinc were selected to obtain the metal hexacyanoferrates (MHCFs) of these metals and to systematically study their structural and electrochemical properties as cathode materials. The obtained substances were characterized via X-ray powder analysis, scanning electron microscopy, thermogravimetric analysis and elemental analysis. An electrochemical study of the obtained cathode materials relative to a platinum anode in an aqueous medium and a magnesium anode in a nonaqueous medium was carried out, and the cycling parameters were determined. The influence of 3d-metal nature on the composition–structure–properties of hexacyanoferrates was demonstrated. MHCFs are promising cathode materials for Mg2+ intercalation/deintercalation in aqueous electrolytes.",
keywords = "aqueous electrolytes batteries, cathode materials, hexacyanoferrates, intercalation",
author = "Селютин, {Артем Александрович} and Арбенин, {Андрей Юрьевич} and Федорова, {Анна Викторовна} and Егоров, {Семен Сергеевич} and Приходько, {Игорь Владимирович} and Пенькова, {Анастасия Владимировна}",
year = "2025",
month = feb,
day = "4",
doi = "10.3390/en18030711",
language = "English",
volume = "18",
journal = "Energies",
issn = "1996-1073",
publisher = "MDPI AG",
number = "3",

}

RIS

TY - JOUR

T1 - Prussian blue analogues based on 3d-metals as cathode materials for magnesium ion batteries

AU - Селютин, Артем Александрович

AU - Арбенин, Андрей Юрьевич

AU - Федорова, Анна Викторовна

AU - Егоров, Семен Сергеевич

AU - Приходько, Игорь Владимирович

AU - Пенькова, Анастасия Владимировна

PY - 2025/2/4

Y1 - 2025/2/4

N2 - Prussian blue PB analogues (K;Mg)xM[Fe(CN)6] were obtained via the co-precipitation method. Manganese, iron, cobalt, nickel, copper and zinc were selected to obtain the metal hexacyanoferrates (MHCFs) of these metals and to systematically study their structural and electrochemical properties as cathode materials. The obtained substances were characterized via X-ray powder analysis, scanning electron microscopy, thermogravimetric analysis and elemental analysis. An electrochemical study of the obtained cathode materials relative to a platinum anode in an aqueous medium and a magnesium anode in a nonaqueous medium was carried out, and the cycling parameters were determined. The influence of 3d-metal nature on the composition–structure–properties of hexacyanoferrates was demonstrated. MHCFs are promising cathode materials for Mg2+ intercalation/deintercalation in aqueous electrolytes.

AB - Prussian blue PB analogues (K;Mg)xM[Fe(CN)6] were obtained via the co-precipitation method. Manganese, iron, cobalt, nickel, copper and zinc were selected to obtain the metal hexacyanoferrates (MHCFs) of these metals and to systematically study their structural and electrochemical properties as cathode materials. The obtained substances were characterized via X-ray powder analysis, scanning electron microscopy, thermogravimetric analysis and elemental analysis. An electrochemical study of the obtained cathode materials relative to a platinum anode in an aqueous medium and a magnesium anode in a nonaqueous medium was carried out, and the cycling parameters were determined. The influence of 3d-metal nature on the composition–structure–properties of hexacyanoferrates was demonstrated. MHCFs are promising cathode materials for Mg2+ intercalation/deintercalation in aqueous electrolytes.

KW - aqueous electrolytes batteries

KW - cathode materials

KW - hexacyanoferrates

KW - intercalation

UR - https://www.mendeley.com/catalogue/09b7a17b-22a1-37be-9ee4-c44ae90fd974/

U2 - 10.3390/en18030711

DO - 10.3390/en18030711

M3 - Article

VL - 18

JO - Energies

JF - Energies

SN - 1996-1073

IS - 3

M1 - 711

ER -

ID: 127322094