Research output: Contribution to journal › Article › peer-review
Prussian blue analogues based on 3d-metals as cathode materials for magnesium ion batteries. / Селютин, Артем Александрович; Арбенин, Андрей Юрьевич; Федорова, Анна Викторовна; Егоров, Семен Сергеевич; Приходько, Игорь Владимирович; Пенькова, Анастасия Владимировна.
In: Energies, Vol. 18, No. 3, 711, 04.02.2025.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Prussian blue analogues based on 3d-metals as cathode materials for magnesium ion batteries
AU - Селютин, Артем Александрович
AU - Арбенин, Андрей Юрьевич
AU - Федорова, Анна Викторовна
AU - Егоров, Семен Сергеевич
AU - Приходько, Игорь Владимирович
AU - Пенькова, Анастасия Владимировна
PY - 2025/2/4
Y1 - 2025/2/4
N2 - Prussian blue PB analogues (K;Mg)xM[Fe(CN)6] were obtained via the co-precipitation method. Manganese, iron, cobalt, nickel, copper and zinc were selected to obtain the metal hexacyanoferrates (MHCFs) of these metals and to systematically study their structural and electrochemical properties as cathode materials. The obtained substances were characterized via X-ray powder analysis, scanning electron microscopy, thermogravimetric analysis and elemental analysis. An electrochemical study of the obtained cathode materials relative to a platinum anode in an aqueous medium and a magnesium anode in a nonaqueous medium was carried out, and the cycling parameters were determined. The influence of 3d-metal nature on the composition–structure–properties of hexacyanoferrates was demonstrated. MHCFs are promising cathode materials for Mg2+ intercalation/deintercalation in aqueous electrolytes.
AB - Prussian blue PB analogues (K;Mg)xM[Fe(CN)6] were obtained via the co-precipitation method. Manganese, iron, cobalt, nickel, copper and zinc were selected to obtain the metal hexacyanoferrates (MHCFs) of these metals and to systematically study their structural and electrochemical properties as cathode materials. The obtained substances were characterized via X-ray powder analysis, scanning electron microscopy, thermogravimetric analysis and elemental analysis. An electrochemical study of the obtained cathode materials relative to a platinum anode in an aqueous medium and a magnesium anode in a nonaqueous medium was carried out, and the cycling parameters were determined. The influence of 3d-metal nature on the composition–structure–properties of hexacyanoferrates was demonstrated. MHCFs are promising cathode materials for Mg2+ intercalation/deintercalation in aqueous electrolytes.
KW - aqueous electrolytes batteries
KW - cathode materials
KW - hexacyanoferrates
KW - intercalation
UR - https://www.mendeley.com/catalogue/09b7a17b-22a1-37be-9ee4-c44ae90fd974/
U2 - 10.3390/en18030711
DO - 10.3390/en18030711
M3 - Article
VL - 18
JO - Energies
JF - Energies
SN - 1996-1073
IS - 3
M1 - 711
ER -
ID: 127322094