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Proton relaxation and hydrogen mobility in Ti–V–Cr alloys: Improved exchange model. / Chizhik, V.I.; Rykov, I.A.; Shelyapina, M.G.; Fruchart, D.

In: International Journal of Hydrogen Energy, Vol. 39, No. 30, 2014, p. 17416-17421.

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Chizhik, VI, Rykov, IA, Shelyapina, MG & Fruchart, D 2014, 'Proton relaxation and hydrogen mobility in Ti–V–Cr alloys: Improved exchange model', International Journal of Hydrogen Energy, vol. 39, no. 30, pp. 17416-17421. https://doi.org/10.1016/j.ijhydene.2014.08.095

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Vancouver

Author

Chizhik, V.I. ; Rykov, I.A. ; Shelyapina, M.G. ; Fruchart, D. / Proton relaxation and hydrogen mobility in Ti–V–Cr alloys: Improved exchange model. In: International Journal of Hydrogen Energy. 2014 ; Vol. 39, No. 30. pp. 17416-17421.

BibTeX

@article{cca8e41899fe40c89537575e15d27be3,
title = "Proton relaxation and hydrogen mobility in Ti–V–Cr alloys: Improved exchange model",
abstract = "Here we propose an improved exchange model of proton relaxation to describe hydrogen mobility in intermetallic hydrides. The model has been successfully applied to a number of hydrides of ternary Ti–V–Cr alloys of different composition, namely, TiV0.8Cr1.2, Ti0.5V1.9Cr0.6 and Ti0.5V1.9Cr0.6 + 4 wt.% Zr7Ni10. It has been found that (i) there are two non-equivalent states of hydrogen (with different mobility) and (ii) there is an exchange between these two states. By analyzing proton relaxation and Knight shift data it was possible to estimate the exchange time between these states: 0.02 ms",
keywords = "Ti–V–Cr hydrides, NMR, Proton relaxation",
author = "V.I. Chizhik and I.A. Rykov and M.G. Shelyapina and D. Fruchart",
year = "2014",
doi = "10.1016/j.ijhydene.2014.08.095",
language = "English",
volume = "39",
pages = "17416--17421",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier",
number = "30",

}

RIS

TY - JOUR

T1 - Proton relaxation and hydrogen mobility in Ti–V–Cr alloys: Improved exchange model

AU - Chizhik, V.I.

AU - Rykov, I.A.

AU - Shelyapina, M.G.

AU - Fruchart, D.

PY - 2014

Y1 - 2014

N2 - Here we propose an improved exchange model of proton relaxation to describe hydrogen mobility in intermetallic hydrides. The model has been successfully applied to a number of hydrides of ternary Ti–V–Cr alloys of different composition, namely, TiV0.8Cr1.2, Ti0.5V1.9Cr0.6 and Ti0.5V1.9Cr0.6 + 4 wt.% Zr7Ni10. It has been found that (i) there are two non-equivalent states of hydrogen (with different mobility) and (ii) there is an exchange between these two states. By analyzing proton relaxation and Knight shift data it was possible to estimate the exchange time between these states: 0.02 ms

AB - Here we propose an improved exchange model of proton relaxation to describe hydrogen mobility in intermetallic hydrides. The model has been successfully applied to a number of hydrides of ternary Ti–V–Cr alloys of different composition, namely, TiV0.8Cr1.2, Ti0.5V1.9Cr0.6 and Ti0.5V1.9Cr0.6 + 4 wt.% Zr7Ni10. It has been found that (i) there are two non-equivalent states of hydrogen (with different mobility) and (ii) there is an exchange between these two states. By analyzing proton relaxation and Knight shift data it was possible to estimate the exchange time between these states: 0.02 ms

KW - Ti–V–Cr hydrides

KW - NMR

KW - Proton relaxation

U2 - 10.1016/j.ijhydene.2014.08.095

DO - 10.1016/j.ijhydene.2014.08.095

M3 - Article

VL - 39

SP - 17416

EP - 17421

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 30

ER -

ID: 7018373