Research output: Contribution to journal › Letter › peer-review
Protolytic Properties of Water-Soluble Magnesium 5,10,15,20-Tetra(1-methylpyridin-1-ium-4-yl)porphyrinate Tetraperchlorate MgTMPyP4. / Ovsepyan, G.K.; Kudrev, A. G.; Shumilova, G. I.; Starikova, A. A.; Semeikin, A. S.; Pendin, A. A.
In: Russian Journal of General Chemistry, Vol. 87, No. 12, 01.12.2017, p. 2906-2908.Research output: Contribution to journal › Letter › peer-review
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TY - JOUR
T1 - Protolytic Properties of Water-Soluble Magnesium 5,10,15,20-Tetra(1-methylpyridin-1-ium-4-yl)porphyrinate Tetraperchlorate MgTMPyP4
AU - Ovsepyan, G.K.
AU - Kudrev, A. G.
AU - Shumilova, G. I.
AU - Starikova, A. A.
AU - Semeikin, A. S.
AU - Pendin, A. A.
PY - 2017/12/1
Y1 - 2017/12/1
N2 - Protolytic properties of porphyrin complexes with Mg, analogs of the natural porphyrin chlorophyll, were investigated by the UV spectroscopy method with simultaneous potentiometric determination of pH of the medium with the aim to detect metalloporphyrin forms arising in a solution with changing its acidity. To consider interconversions in solutions, MCR-ALS soft modelling based on the chemometric analysis of spectrometric data was applied.
AB - Protolytic properties of porphyrin complexes with Mg, analogs of the natural porphyrin chlorophyll, were investigated by the UV spectroscopy method with simultaneous potentiometric determination of pH of the medium with the aim to detect metalloporphyrin forms arising in a solution with changing its acidity. To consider interconversions in solutions, MCR-ALS soft modelling based on the chemometric analysis of spectrometric data was applied.
KW - chemometric analysis
KW - metalloporphyrins
KW - protonation
KW - spectrophotometry
UR - http://www.scopus.com/inward/record.url?scp=85042087978&partnerID=8YFLogxK
U2 - 10.1134/S1070363217120295
DO - 10.1134/S1070363217120295
M3 - Letter
AN - SCOPUS:85042087978
VL - 87
SP - 2906
EP - 2908
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 12
ER -
ID: 38689483