Research output: Contribution to journal › Article › peer-review
Promising membrane materials based on strontium titanate. / Murashkina, A. A.; Pikalova, E. Yu; Demin, A. K.
In: Russian Journal of Electrochemistry, Vol. 45, No. 5, 05.2009, p. 542-547.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Promising membrane materials based on strontium titanate
AU - Murashkina, A. A.
AU - Pikalova, E. Yu
AU - Demin, A. K.
PY - 2009/5
Y1 - 2009/5
N2 - Electroconductivity of SrTi1-x Fe x O 3-δ(x = 0-0.5) specimens was studied by four-probe method. An opportunity was studied to produce hydrogen by high-temperature electrochemical conversion using SrTi0.5Fe0.5O3-δ as the membrane material of the best conductivity. The effective ambipolar conductivity values calculated for SrTi0.5Fe0.5O3-δ from the leakage experiment were found different from the ambipolar conductivity values calculated by the four-probe data processing because ambipolar conductivity corresponds to bulk transfer of complex oxide particles, taking no surface phenomena into account.
AB - Electroconductivity of SrTi1-x Fe x O 3-δ(x = 0-0.5) specimens was studied by four-probe method. An opportunity was studied to produce hydrogen by high-temperature electrochemical conversion using SrTi0.5Fe0.5O3-δ as the membrane material of the best conductivity. The effective ambipolar conductivity values calculated for SrTi0.5Fe0.5O3-δ from the leakage experiment were found different from the ambipolar conductivity values calculated by the four-probe data processing because ambipolar conductivity corresponds to bulk transfer of complex oxide particles, taking no surface phenomena into account.
KW - Ambipolar onductivity
KW - Combined conductors
KW - Electrochemical converter
KW - Hydrogen production
KW - Oxygen permeability
UR - http://www.scopus.com/inward/record.url?scp=66149162975&partnerID=8YFLogxK
U2 - 10.1134/S1023193509050073
DO - 10.1134/S1023193509050073
M3 - Article
AN - SCOPUS:66149162975
VL - 45
SP - 542
EP - 547
JO - Russian Journal of Electrochemistry
JF - Russian Journal of Electrochemistry
SN - 1023-1935
IS - 5
ER -
ID: 85232361