Pressure dependence of the solubility of light fullerenes in n-nonane

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Pressure dependence of the solubility of light fullerenes in n-nonane. / Semenov, Konstantin N.; Charykov, Nikolay A.; López, Enriqueta R.; Fernández, Josefa; Sharoyko, Vladimir V.; Murin, Igor V.

In: Journal of Chemical Thermodynamics, Vol. 112, 2017, p. 259-266.

Research output: Contribution to journal › Article › peer-review

Author

Semenov, Konstantin N. ; Charykov, Nikolay A. ; López, Enriqueta R. ; Fernández, Josefa ; Sharoyko, Vladimir V. ; Murin, Igor V. / Pressure dependence of the solubility of light fullerenes in n-nonane. In: Journal of Chemical Thermodynamics. 2017 ; Vol. 112. pp. 259-266.

BibTeX

@article{d46bf813e19c4bafa855cc7d3f140f83,

title = "Pressure dependence of the solubility of light fullerenes in n-nonane",

abstract = "Solubility of light fullerenes (C60 and C70) in n-nonane was investigated in the ranges of pressure form 0.1 MPa up to 100 MPa and temperature from 298.3 K to 353.3 K. Under isothermal conditions, the solubility, expressed as weight fraction of the fullerene in the solution, increases monotonously with increasing pressure. At ambient pressure, we have found that the temperature dependence of the solubility of C60 in n-nonane is non-monotonic: the solubility diagram consists of two branches corresponding to crystallization of different solid phases and one invariant point corresponding to simultaneous saturation of both phases. At 0.1 MPa, the solubility diagram of the binary system C70 – n-nonane in the analysed temperature range consists of only one branch corresponding to crystallization of non-solvated C70.",

keywords = "C, High pressure, Light fullerenes, n-Nonane, Solubility",

author = "Semenov, {Konstantin N.} and Charykov, {Nikolay A.} and L{\'o}pez, {Enriqueta R.} and Josefa Fern{\'a}ndez and Sharoyko, {Vladimir V.} and Murin, {Igor V.}",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2017",

doi = "10.1016/j.jct.2017.05.017",

language = "English",

volume = "112",

pages = "259--266",

journal = "Journal of Chemical Thermodynamics",

issn = "0021-9614",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Pressure dependence of the solubility of light fullerenes in n-nonane

AU - Semenov, Konstantin N.

AU - Charykov, Nikolay A.

AU - López, Enriqueta R.

AU - Fernández, Josefa

AU - Sharoyko, Vladimir V.

AU - Murin, Igor V.

PY - 2017

Y1 - 2017

N2 - Solubility of light fullerenes (C60 and C70) in n-nonane was investigated in the ranges of pressure form 0.1 MPa up to 100 MPa and temperature from 298.3 K to 353.3 K. Under isothermal conditions, the solubility, expressed as weight fraction of the fullerene in the solution, increases monotonously with increasing pressure. At ambient pressure, we have found that the temperature dependence of the solubility of C60 in n-nonane is non-monotonic: the solubility diagram consists of two branches corresponding to crystallization of different solid phases and one invariant point corresponding to simultaneous saturation of both phases. At 0.1 MPa, the solubility diagram of the binary system C70 – n-nonane in the analysed temperature range consists of only one branch corresponding to crystallization of non-solvated C70.

AB - Solubility of light fullerenes (C60 and C70) in n-nonane was investigated in the ranges of pressure form 0.1 MPa up to 100 MPa and temperature from 298.3 K to 353.3 K. Under isothermal conditions, the solubility, expressed as weight fraction of the fullerene in the solution, increases monotonously with increasing pressure. At ambient pressure, we have found that the temperature dependence of the solubility of C60 in n-nonane is non-monotonic: the solubility diagram consists of two branches corresponding to crystallization of different solid phases and one invariant point corresponding to simultaneous saturation of both phases. At 0.1 MPa, the solubility diagram of the binary system C70 – n-nonane in the analysed temperature range consists of only one branch corresponding to crystallization of non-solvated C70.

KW - C

KW - High pressure

KW - Light fullerenes

KW - n-Nonane

KW - Solubility

UR - http://www.scopus.com/inward/record.url?scp=85019362145&partnerID=8YFLogxK

U2 - 10.1016/j.jct.2017.05.017

DO - 10.1016/j.jct.2017.05.017

M3 - Article

VL - 112

SP - 259

EP - 266

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

ER -

ID: 7749443