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Pressure and temperature dependence of light fullerenes solubility in n-heptane. / Semenov, Konstantin N.; Charykov, Nikolay A.; López, Enriqueta R.; Fernández, Josefa; Parajó, Juan J.; Podolsky, Nikita E.; Murin, Igor V.

In: Journal of Molecular Liquids, Vol. 268, 15.10.2018, p. 569-577.

Research output: Contribution to journal › Article › peer-review

Harvard

Semenov, KN, Charykov, NA, López, ER, Fernández, J, Parajó, JJ, Podolsky, NE & Murin, IV 2018, 'Pressure and temperature dependence of light fullerenes solubility in n-heptane', Journal of Molecular Liquids, vol. 268, pp. 569-577. https://doi.org/10.1016/j.molliq.2018.06.099

APA

Semenov, K. N., Charykov, N. A., López, E. R., Fernández, J., Parajó, J. J., Podolsky, N. E., & Murin, I. V. (2018). Pressure and temperature dependence of light fullerenes solubility in n-heptane. Journal of Molecular Liquids, 268, 569-577. https://doi.org/10.1016/j.molliq.2018.06.099

Vancouver

Semenov KN, Charykov NA, López ER, Fernández J, Parajó JJ, Podolsky NE et al. Pressure and temperature dependence of light fullerenes solubility in n-heptane. Journal of Molecular Liquids. 2018 Oct 15;268:569-577. https://doi.org/10.1016/j.molliq.2018.06.099

Author

Semenov, Konstantin N. ; Charykov, Nikolay A. ; López, Enriqueta R. ; Fernández, Josefa ; Parajó, Juan J. ; Podolsky, Nikita E. ; Murin, Igor V. / Pressure and temperature dependence of light fullerenes solubility in n-heptane. In: Journal of Molecular Liquids. 2018 ; Vol. 268. pp. 569-577.

BibTeX

@article{7049547deec74229b1f29cdbbbd0017c,
title = "Pressure and temperature dependence of light fullerenes solubility in n-heptane",
abstract = "Solubility of individual light fullerenes (C60 and C70) in n-heptane was measured in the ranges of pressure from 0.1 up to 110 MPa and temperature from 298.3 to 358.3 K. At 0.1 MPa, the solubility diagrams of the C60 – n-heptane, C70 – n-heptane binary systems consist of only one branch corresponding to crystallization of mono-solvated fullerenes – C60·C7H16 and C70·C7H16. The compositions of the solid crystalline solvates were determined by thermogravimetric analysis. Thermodynamic description of the temperature and pressure dependences of solubility was performed using the van-der-Waals differential equation. As a result, the changes of the isothermal compressibility, molar volume, isobaric heat capacity and molar entropy in the process of the light fullerenes dissolution with formation of infinitely diluted solution were calculated.",
keywords = "C, High pressure, Light fullerenes, Solubility, n-heptane",
author = "Semenov, {Konstantin N.} and Charykov, {Nikolay A.} and L{\'o}pez, {Enriqueta R.} and Josefa Fern{\'a}ndez and Paraj{\'o}, {Juan J.} and Podolsky, {Nikita E.} and Murin, {Igor V.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = oct,
day = "15",
doi = "10.1016/j.molliq.2018.06.099",
language = "English",
volume = "268",
pages = "569--577",
journal = "Journal of Molecular Liquids",
issn = "0167-7322",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Pressure and temperature dependence of light fullerenes solubility in n-heptane

AU - Semenov, Konstantin N.

AU - Charykov, Nikolay A.

AU - López, Enriqueta R.

AU - Fernández, Josefa

AU - Parajó, Juan J.

AU - Podolsky, Nikita E.

AU - Murin, Igor V.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2018/10/15

Y1 - 2018/10/15

N2 - Solubility of individual light fullerenes (C60 and C70) in n-heptane was measured in the ranges of pressure from 0.1 up to 110 MPa and temperature from 298.3 to 358.3 K. At 0.1 MPa, the solubility diagrams of the C60 – n-heptane, C70 – n-heptane binary systems consist of only one branch corresponding to crystallization of mono-solvated fullerenes – C60·C7H16 and C70·C7H16. The compositions of the solid crystalline solvates were determined by thermogravimetric analysis. Thermodynamic description of the temperature and pressure dependences of solubility was performed using the van-der-Waals differential equation. As a result, the changes of the isothermal compressibility, molar volume, isobaric heat capacity and molar entropy in the process of the light fullerenes dissolution with formation of infinitely diluted solution were calculated.

AB - Solubility of individual light fullerenes (C60 and C70) in n-heptane was measured in the ranges of pressure from 0.1 up to 110 MPa and temperature from 298.3 to 358.3 K. At 0.1 MPa, the solubility diagrams of the C60 – n-heptane, C70 – n-heptane binary systems consist of only one branch corresponding to crystallization of mono-solvated fullerenes – C60·C7H16 and C70·C7H16. The compositions of the solid crystalline solvates were determined by thermogravimetric analysis. Thermodynamic description of the temperature and pressure dependences of solubility was performed using the van-der-Waals differential equation. As a result, the changes of the isothermal compressibility, molar volume, isobaric heat capacity and molar entropy in the process of the light fullerenes dissolution with formation of infinitely diluted solution were calculated.

KW - C

KW - High pressure

KW - Light fullerenes

KW - Solubility

KW - n-heptane

UR - http://www.scopus.com/inward/record.url?scp=85050456172&partnerID=8YFLogxK

U2 - 10.1016/j.molliq.2018.06.099

DO - 10.1016/j.molliq.2018.06.099

M3 - Article

AN - SCOPUS:85050456172

VL - 268

SP - 569

EP - 577

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

SN - 0167-7322

ER -

ID: 35260258