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Preparation and in situ use of unstable N-alkyl α-diazo-γ-butyrolactams in RhII-catalyzed X–H insertion reactions. / Eremeyeva, Maria; Zhukovsky, Daniil; Dar'in, Dmitrii; Krasavin, Mikhail.

In: Beilstein Journal of Organic Chemistry, Vol. 16, 02.04.2020, p. 607-610.

Research output: Contribution to journal › Article › peer-review

Harvard

Eremeyeva, M, Zhukovsky, D, Dar'in, D & Krasavin, M 2020, 'Preparation and in situ use of unstable N-alkyl α-diazo-γ-butyrolactams in RhII-catalyzed X–H insertion reactions', Beilstein Journal of Organic Chemistry, vol. 16, pp. 607-610. https://doi.org/10.3762/bjoc.16.55, https://doi.org/10.3762/bjoc.16.55

APA

Eremeyeva, M., Zhukovsky, D., Dar'in, D., & Krasavin, M. (2020). Preparation and in situ use of unstable N-alkyl α-diazo-γ-butyrolactams in RhII-catalyzed X–H insertion reactions. Beilstein Journal of Organic Chemistry, 16, 607-610. https://doi.org/10.3762/bjoc.16.55, https://doi.org/10.3762/bjoc.16.55

Vancouver

Eremeyeva M, Zhukovsky D, Dar'in D, Krasavin M. Preparation and in situ use of unstable N-alkyl α-diazo-γ-butyrolactams in RhII-catalyzed X–H insertion reactions. Beilstein Journal of Organic Chemistry. 2020 Apr 2;16:607-610. https://doi.org/10.3762/bjoc.16.55, https://doi.org/10.3762/bjoc.16.55

Author

Eremeyeva, Maria ; Zhukovsky, Daniil ; Dar'in, Dmitrii ; Krasavin, Mikhail. / Preparation and in situ use of unstable N-alkyl α-diazo-γ-butyrolactams in RhII-catalyzed X–H insertion reactions. In: Beilstein Journal of Organic Chemistry. 2020 ; Vol. 16. pp. 607-610.

BibTeX

@article{7148273ef358461e96521a95ce36d32d,
title = "Preparation and in situ use of unstable N-alkyl α-diazo-γ-butyrolactams in RhII-catalyzed X–H insertion reactions",
abstract = "N-Alkyl α-diazo-γ-butyrolactams, previously found to be unstable and to undergo unproductive dimerization to bishydrazones, were successfully converted immediately to various X–H insertion products with alcohols, aromatic amines and thiols via an in situ RhII-catalyzed reaction. With aliphatic amines or unreactive, sterically hindered anilines, the reactions tended to yield enamine adducts.",
keywords = "In situ reactions, N-alkyl 2-pyrrolidones, Rh -catalyzed insertion reactions, Stability of diazo compounds",
author = "Maria Eremeyeva and Daniil Zhukovsky and Dmitrii Dar'in and Mikhail Krasavin",
year = "2020",
month = apr,
day = "2",
doi = "10.3762/bjoc.16.55",
language = "English",
volume = "16",
pages = "607--610",
journal = "Beilstein Journal of Organic Chemistry",
issn = "1860-5397",
publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",

}

RIS

TY - JOUR

T1 - Preparation and in situ use of unstable N-alkyl α-diazo-γ-butyrolactams in RhII-catalyzed X–H insertion reactions

AU - Eremeyeva, Maria

AU - Zhukovsky, Daniil

AU - Dar'in, Dmitrii

AU - Krasavin, Mikhail

PY - 2020/4/2

Y1 - 2020/4/2

N2 - N-Alkyl α-diazo-γ-butyrolactams, previously found to be unstable and to undergo unproductive dimerization to bishydrazones, were successfully converted immediately to various X–H insertion products with alcohols, aromatic amines and thiols via an in situ RhII-catalyzed reaction. With aliphatic amines or unreactive, sterically hindered anilines, the reactions tended to yield enamine adducts.

AB - N-Alkyl α-diazo-γ-butyrolactams, previously found to be unstable and to undergo unproductive dimerization to bishydrazones, were successfully converted immediately to various X–H insertion products with alcohols, aromatic amines and thiols via an in situ RhII-catalyzed reaction. With aliphatic amines or unreactive, sterically hindered anilines, the reactions tended to yield enamine adducts.

KW - In situ reactions

KW - N-alkyl 2-pyrrolidones

KW - Rh -catalyzed insertion reactions

KW - Stability of diazo compounds

UR - http://www.scopus.com/inward/record.url?scp=85084381682&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/12486f6b-e0d0-356f-b9ef-7e8af114f031/

U2 - 10.3762/bjoc.16.55

DO - 10.3762/bjoc.16.55

M3 - Article

VL - 16

SP - 607

EP - 610

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 1860-5397

ER -

ID: 52907258