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Preparation and characterization of methanol selective membranes based on polyheteroarylene − Cu(I) complexes for purification of methyl tertiary butyl ether. / Pulyalina, Alexandra; Polotskaya, Galina; Goikhman, Mikhail; Podeshvo, Irina; Gulii, Natalia; Shugurov, Sergey; Tataurov, Maksim; Toikka, Alexander.

In: Polymer International, Vol. 66, No. 12, 2017, p. 1873–1882 .

Research output: Contribution to journal › Article › peer-review

Harvard

Pulyalina, A, Polotskaya, G, Goikhman, M, Podeshvo, I, Gulii, N, Shugurov, S, Tataurov, M & Toikka, A 2017, 'Preparation and characterization of methanol selective membranes based on polyheteroarylene − Cu(I) complexes for purification of methyl tertiary butyl ether', Polymer International, vol. 66, no. 12, pp. 1873–1882 .

APA

Pulyalina, A., Polotskaya, G., Goikhman, M., Podeshvo, I., Gulii, N., Shugurov, S., Tataurov, M., & Toikka, A. (2017). Preparation and characterization of methanol selective membranes based on polyheteroarylene − Cu(I) complexes for purification of methyl tertiary butyl ether. Polymer International, 66(12), 1873–1882 .

Vancouver

Pulyalina A, Polotskaya G, Goikhman M, Podeshvo I, Gulii N, Shugurov S et al. Preparation and characterization of methanol selective membranes based on polyheteroarylene − Cu(I) complexes for purification of methyl tertiary butyl ether. Polymer International. 2017;66(12):1873–1882 .

Author

Pulyalina, Alexandra ; Polotskaya, Galina ; Goikhman, Mikhail ; Podeshvo, Irina ; Gulii, Natalia ; Shugurov, Sergey ; Tataurov, Maksim ; Toikka, Alexander. / Preparation and characterization of methanol selective membranes based on polyheteroarylene − Cu(I) complexes for purification of methyl tertiary butyl ether. In: Polymer International. 2017 ; Vol. 66, No. 12. pp. 1873–1882 .

BibTeX

@article{21d051dfdbdc4c2fb5b3f1bc3f6a6c0f,
title = "Preparation and characterization of methanol selective membranes based on polyheteroarylene − Cu(I) complexes for purification of methyl tertiary butyl ether",
abstract = "A comparative study of metal − polymer complexes of Cu(I) with polybenzoxazinoneimide (PBOI) and its prepolymer imide-containing polyamic acid (PAA) as novel membrane materials for methyl tertiary butyl ether (MTBE) purification was undertaken. The structure, physical parameters and transport properties were characterized in detail to analyse the separation performance of the membranes and obtain new knowledge on the interdependence of the chemical structure and physical data with transport parameters. Thermally initiated conversion of PAA − Cu(I) to PBOI − Cu(I) was studied by TGA and DSC. The thermal conversion increases the polymer glass transition temperature and membrane density. Both polymers were applied to pervaporation separation of MTBE from methanol impurities. Membranes based on PAA are highly effective in MTBE purification and preferably permeate methanol. The transport properties of PAA − Cu(I) membrane are compared with those of known membranes",
author = "Alexandra Pulyalina and Galina Polotskaya and Mikhail Goikhman and Irina Podeshvo and Natalia Gulii and Sergey Shugurov and Maksim Tataurov and Alexander Toikka",
year = "2017",
language = "English",
volume = "66",
pages = "1873–1882 ",
journal = "Polymer International",
issn = "0959-8103",
publisher = "Wiley-Blackwell",
number = "12",

}

RIS

TY - JOUR

T1 - Preparation and characterization of methanol selective membranes based on polyheteroarylene − Cu(I) complexes for purification of methyl tertiary butyl ether

AU - Pulyalina, Alexandra

AU - Polotskaya, Galina

AU - Goikhman, Mikhail

AU - Podeshvo, Irina

AU - Gulii, Natalia

AU - Shugurov, Sergey

AU - Tataurov, Maksim

AU - Toikka, Alexander

PY - 2017

Y1 - 2017

N2 - A comparative study of metal − polymer complexes of Cu(I) with polybenzoxazinoneimide (PBOI) and its prepolymer imide-containing polyamic acid (PAA) as novel membrane materials for methyl tertiary butyl ether (MTBE) purification was undertaken. The structure, physical parameters and transport properties were characterized in detail to analyse the separation performance of the membranes and obtain new knowledge on the interdependence of the chemical structure and physical data with transport parameters. Thermally initiated conversion of PAA − Cu(I) to PBOI − Cu(I) was studied by TGA and DSC. The thermal conversion increases the polymer glass transition temperature and membrane density. Both polymers were applied to pervaporation separation of MTBE from methanol impurities. Membranes based on PAA are highly effective in MTBE purification and preferably permeate methanol. The transport properties of PAA − Cu(I) membrane are compared with those of known membranes

AB - A comparative study of metal − polymer complexes of Cu(I) with polybenzoxazinoneimide (PBOI) and its prepolymer imide-containing polyamic acid (PAA) as novel membrane materials for methyl tertiary butyl ether (MTBE) purification was undertaken. The structure, physical parameters and transport properties were characterized in detail to analyse the separation performance of the membranes and obtain new knowledge on the interdependence of the chemical structure and physical data with transport parameters. Thermally initiated conversion of PAA − Cu(I) to PBOI − Cu(I) was studied by TGA and DSC. The thermal conversion increases the polymer glass transition temperature and membrane density. Both polymers were applied to pervaporation separation of MTBE from methanol impurities. Membranes based on PAA are highly effective in MTBE purification and preferably permeate methanol. The transport properties of PAA − Cu(I) membrane are compared with those of known membranes

M3 - Article

VL - 66

SP - 1873

EP - 1882

JO - Polymer International

JF - Polymer International

SN - 0959-8103

IS - 12

ER -

ID: 9431179