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Potential energy curves and dipole transition moments to the ground state of the system Ar-*(3p(5)4s, P-3, P-1) plus Ne. / Petsalakis, ID; Buenker, RJ; Lieberman, HP; Alekseyev, AB; Devdariani, AZ; Theodorakopoulos, G.

In: Journal of Chemical Physics, Vol. 113, No. 14, 08.10.2000, p. 5812-5816.

Research output: Contribution to journal › Article › peer-review

Harvard

Petsalakis, ID, Buenker, RJ, Lieberman, HP, Alekseyev, AB, Devdariani, AZ & Theodorakopoulos, G 2000, 'Potential energy curves and dipole transition moments to the ground state of the system Ar-*(3p(5)4s, P-3, P-1) plus Ne', Journal of Chemical Physics, vol. 113, no. 14, pp. 5812-5816. https://doi.org/10.1063/1.1290007

APA

Petsalakis, ID., Buenker, RJ., Lieberman, HP., Alekseyev, AB., Devdariani, AZ., & Theodorakopoulos, G. (2000). Potential energy curves and dipole transition moments to the ground state of the system Ar-*(3p(5)4s, P-3, P-1) plus Ne. Journal of Chemical Physics, 113(14), 5812-5816. https://doi.org/10.1063/1.1290007

Vancouver

Petsalakis ID, Buenker RJ, Lieberman HP, Alekseyev AB, Devdariani AZ, Theodorakopoulos G. Potential energy curves and dipole transition moments to the ground state of the system Ar-*(3p(5)4s, P-3, P-1) plus Ne. Journal of Chemical Physics. 2000 Oct 8;113(14):5812-5816. https://doi.org/10.1063/1.1290007

Author

Petsalakis, ID ; Buenker, RJ ; Lieberman, HP ; Alekseyev, AB ; Devdariani, AZ ; Theodorakopoulos, G. / Potential energy curves and dipole transition moments to the ground state of the system Ar-*(3p(5)4s, P-3, P-1) plus Ne. In: Journal of Chemical Physics. 2000 ; Vol. 113, No. 14. pp. 5812-5816.

BibTeX

@article{167877d2920e43df90d4a53e8d5c7cc5,
title = "Potential energy curves and dipole transition moments to the ground state of the system Ar-*(3p(5)4s, P-3, P-1) plus Ne",
abstract = "Relativistic core-potential calculations have been carried out on Omega states resulting from the interaction of Ar*(3p(5)4s, P-3, P-1) with ground state Ne atoms. The results yield the correct asymptotic limits for the atomic states of Ar while shallow minima (700-800 cm(-1)) at large internuclear distances, 7-8 bohr, are obtained for the excited states. Dipole transition moments between pairs of states have been calculated and strong radiative transitions are predicted from excited states to the ground state. The 1(I) state, correlating with the metastable P-3(2) state of Ar is found to have a small dipole transition moment at short and intermediate nuclear distances leading to a radiative lifetime for this state of 8.3 mu s. (C) 2000 American Institute of Physics. [S0021- 9606(00)30737-1].",
keywords = "ORBIT CONFIGURATION-INTERACTION, MOLECULAR CALCULATIONS, EXCITED-STATES, BASIS SETS, ROW ATOMS, MODEL, COLLISIONS, AR",
author = "ID Petsalakis and RJ Buenker and HP Lieberman and AB Alekseyev and AZ Devdariani and G Theodorakopoulos",
year = "2000",
month = oct,
day = "8",
doi = "10.1063/1.1290007",
language = "Английский",
volume = "113",
pages = "5812--5816",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "14",

}

RIS

TY - JOUR

T1 - Potential energy curves and dipole transition moments to the ground state of the system Ar-*(3p(5)4s, P-3, P-1) plus Ne

AU - Petsalakis, ID

AU - Buenker, RJ

AU - Lieberman, HP

AU - Alekseyev, AB

AU - Devdariani, AZ

AU - Theodorakopoulos, G

PY - 2000/10/8

Y1 - 2000/10/8

N2 - Relativistic core-potential calculations have been carried out on Omega states resulting from the interaction of Ar*(3p(5)4s, P-3, P-1) with ground state Ne atoms. The results yield the correct asymptotic limits for the atomic states of Ar while shallow minima (700-800 cm(-1)) at large internuclear distances, 7-8 bohr, are obtained for the excited states. Dipole transition moments between pairs of states have been calculated and strong radiative transitions are predicted from excited states to the ground state. The 1(I) state, correlating with the metastable P-3(2) state of Ar is found to have a small dipole transition moment at short and intermediate nuclear distances leading to a radiative lifetime for this state of 8.3 mu s. (C) 2000 American Institute of Physics. [S0021- 9606(00)30737-1].

AB - Relativistic core-potential calculations have been carried out on Omega states resulting from the interaction of Ar*(3p(5)4s, P-3, P-1) with ground state Ne atoms. The results yield the correct asymptotic limits for the atomic states of Ar while shallow minima (700-800 cm(-1)) at large internuclear distances, 7-8 bohr, are obtained for the excited states. Dipole transition moments between pairs of states have been calculated and strong radiative transitions are predicted from excited states to the ground state. The 1(I) state, correlating with the metastable P-3(2) state of Ar is found to have a small dipole transition moment at short and intermediate nuclear distances leading to a radiative lifetime for this state of 8.3 mu s. (C) 2000 American Institute of Physics. [S0021- 9606(00)30737-1].

KW - ORBIT CONFIGURATION-INTERACTION

KW - MOLECULAR CALCULATIONS

KW - EXCITED-STATES

KW - BASIS SETS

KW - ROW ATOMS

KW - MODEL

KW - COLLISIONS

KW - AR

U2 - 10.1063/1.1290007

DO - 10.1063/1.1290007

M3 - статья

VL - 113

SP - 5812

EP - 5816

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 14

ER -

ID: 74051209